Thermodynamic properties and superconductivity of natural carrollite (CuCo2S4)

Gibson, Alexis; Lilova, Kristina; Subramani, Tamilarasan; von der Heyden, Bjorn; Gilbert, Dustin A.; Navrotsky, Alexandra; Woodfield, Brian F.

doi:10.1016/j.jct.2023.107096

Thermodynamic properties and superconductivity of natural carrollite (CuCo₂S₄)

Journal Article · Tue May 30 00:00:00 EDT 2023 · Journal of Chemical Thermodynamics

DOI:https://doi.org/10.1016/j.jct.2023.107096· OSTI ID:3013120

Gibson, Alexis ^[1]; Lilova, Kristina ^[2]; Subramani, Tamilarasan ^[2]; von der Heyden, Bjorn ^[3]; Gilbert, Dustin A. ^[4]; Navrotsky, Alexandra ^[2]; Woodfield, Brian F. ^[1]

Brigham Young University, Provo, UT (United States)
Arizona State University, Tempe, AZ (United States)
Stellenbosch University, Matieland (South Africa)
University of Tennessee, Knoxville, TN (United States)

The thermodynamic properties of natural carrollite with a formula Cu_0.92Co_2.07S₄ are studied using low temperature heat capacity and high temperature oxidative solution calorimetry. The standard thermodynamic functions at 298.15 K are: C_p,m°, S_m°, H_m°, and Φ_m° are 158.48 J∙K⁻¹∙mol⁻¹, 176.33 J∙K⁻¹∙mol⁻¹, 28.40 kJ∙mol⁻¹, and 81.07 kJ∙mol⁻¹ with an estimated error of 1%. The enthalpies (Δ_fH), entropies (Δ_fS), and Gibbs energies of formation (Δ_fG) from elements at 298.15 K are: −344.46 ± 12.87 kJ∙mol⁻¹, −45.22 ± 1.81 J∙K⁻¹∙mol⁻¹, and −331.14 ± 1.89 J∙K⁻¹∙mol⁻¹. The stability of carrollite relative to the elements is demonstrated with a negative Gibbs energy (ΔG_r°) of formation for several temperatures between 0 and 300 K. Furthermore, a superconductivity transition, which has been observed previously for synthetic carrollite, is confirmed by both the low temperature heat capacity and magnetization measurements.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Davis, CA (United States); Univ. of Tennessee, Knoxville, TN (United States); University of Tennessee, Knoxville, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-97ER14749; SC0021344

OSTI ID:: 3013120

Alternate ID(s):: OSTI ID: 2576771

Journal Information:: Journal of Chemical Thermodynamics, Journal Name: Journal of Chemical Thermodynamics Vol. 185; ISSN 0021-9614

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

Chemistry
CuCo2S4
Thermodynamics
carrollite
enthalpy of formation
heat capacity
superconductivity

Thermodynamic properties and superconductivity of natural carrollite (CuCo2S4)

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References (26)

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Thermodynamic properties and superconductivity of natural carrollite (CuCo₂S₄)