Evaluate Compatibility of Alloy 244 in NaCl-MgCl2
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Alloy 244 is a potential material of interest for molten salt reactor (MSR) developers employing molten chloride as fuel and coolant salts because of its improved mechanical properties compared to the austenitic stainless steel 316H and the Ni-base alloy Hastelloy-N. However, data are limited on the corrosion behavior of alloy 244 in molten chloride salts. Experimental data on the corrosion behavior of 244 in chloride salts will provide valuable data to MSR developers while simultaneously aiding in improving mechanistic understanding of the role of salt chemistry, alloying constituents and microstructure of 244. This task evaluated the compatibility of alloy 244 in two different eutectic NaCl–MgCl2 salt mixtures. Similar corrosion behavior in terms of depths of attack and compositional changes in the alloy subsurface was observed after exposure in both salts for 500 h at 750°C. However, severe corrosion attack was observed after 500 h at 850°C in one of the chloride salt mixture. This was most likely due to the combined effects of the differences in the two salt chemistries, distinct microstructure of 244 at 850°C compared to 750°C, and the temperature dependence of the chemical interactions (thermodynamic and kinetic) between the alloying constituents.
- Research Organization:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE Office of Nuclear Energy (NE), Nuclear Fuel Cycle and Supply Chain. Fuel Cycle Research and Development Program; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Materials & Manufacturing Technologies Office (AMMTO)
- DOE Contract Number:
- AC05-00OR22725
- OSTI ID:
- 3002287
- Report Number(s):
- ORNL/TM--2025/4038
- Country of Publication:
- United States
- Language:
- English
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