Metal–Organic Frameworks for Per- and Polyfluoroalkyl Substances Treatment in Contaminated Water

Liang, Rong-Ran; Liu, Zhaoyi; Rushlow, Joshua; Huo, Jiatong; Han, Zongsu; Yang, Yihao; Lin, Hengyu; Zhou, Hong-Cai

doi:10.1021/acsmaterialslett.5c00902

Metal–Organic Frameworks for Per- and Polyfluoroalkyl Substances Treatment in Contaminated Water

Journal Article · Thu Aug 28 00:00:00 EDT 2025 · ACS Materials Letters

DOI:https://doi.org/10.1021/acsmaterialslett.5c00902· OSTI ID:2999009

Liang, Rong-Ran ^[1]; Liu, Zhaoyi ^[1]; Rushlow, Joshua ^[1]; Huo, Jiatong ^[1]; Han, Zongsu ^[1]; ^[1]; Lin, Hengyu ^[1]; ^[1]

Texas A&M University, College Station, TX (United States)

Per- and polyfluoroalkyl substances (PFAS) are synthetic pollutants known for their chemical stability, environmental persistence, and toxicological risks. Their widespread use has led to extensive contamination, particularly in aquatic systems. Conventional treatment methods often face challenges such as high energy consumption and the production of secondary pollutants. Metal− organic frameworks (MOFs), with their high surface areas and tunable structures, have emerged as promising materials for PFAS remediation. This review summarizes recent progress in MOF-based PFAS adsorption and degradation, highlighting key frameworks such as MIL, UiO, and ZIF. Mechanistic insights into adsorption behavior and regeneration capabilities are discussed, along with the catalytic performance of MOF composites and postmodified systems in degradation pathways. The review concludes with design strategies for next-generation MOF materials aimed at efficient, sustainable PFAS removal under realistic conditions.

View Accepted Manuscript (DOE)

Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy and Carbon Management (FECM)

Grant/Contract Number:: FE0032108

OSTI ID:: 2999009

Journal Information:: ACS Materials Letters, Journal Name: ACS Materials Letters Journal Issue: 10 Vol. 7; ISSN 2639-4979

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Efficient Removal of Per- and Polyfluoroalkyl Substances from Water with Zirconium-Based Metal–Organic Frameworks

Journal Article · Mon Apr 19 00:00:00 EDT 2021 · Chemistry of Materials · OSTI ID:1786325

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Adsorption
Chemical structure
Composites
Degradation
Metal organic frameworks
Molecular mechanics
Oxides
Stability

Metal–Organic Frameworks for Per- and Polyfluoroalkyl Substances Treatment in Contaminated Water

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