Stabilities and reactivities of solution phase organic radicals. Final report
Technical Report
·
OSTI ID:290870
Summaries of results are presented on the following five investigations: (a) Determination and analyses of the effects of substituents on the heterolytic and homolytic strengths of N-H bonds in variously substituted diphenylamines; (b) Comparisons of the effects of {alpha}- and {beta}-substituents on the heterolytic and homolytic C-H strengths of several 9-substituted fluorines; (c) Comparison of the sp{sup 3} C-H bond strengths in 1,3-cyclopentadiene and (all-cis)-1,3,5,7-cyclononatetraene: Effects of ring size and aromaticity on the stabilities of reactive intermediates; (d) Evaluation of the magnitude of dipole stabilization as it pertains to anion and radical stabilities; and (e) Evaluation of the effects of adjacent germanium and selenium substituents on heterolytic and homolytic sp{sup 3} C-H bond strengths.
- Research Organization:
- Southern Illinois Univ., Dept. of Chemistry and Biochemistry, Carbondale, IL (United States)
- Sponsoring Organization:
- USDOE Office of Energy Research, Washington, DC (United States)
- DOE Contract Number:
- FG02-91ER14186
- OSTI ID:
- 290870
- Report Number(s):
- DOE/ER/14186--T2; ON: DE99001050
- Country of Publication:
- United States
- Language:
- English
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