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Evaluation of the gas response of ZnO/La{sub 2}CuO{sub 4} hetero-contacts with different electrode materials

Conference ·
OSTI ID:28852
This paper reports the sensitivity to CO and H{sub 2} of hetero-contacts between p-type La{sub 2}CuO{sub 4} and n-type ZnO semiconductors, with different electrode materials applied on ZnO pellets. Hetero-contacts were prepared by mechanically pressing sintered pellets of the two oxides. Three different electrode materials were used for ZnO pellets (Zn-containing Ag, In- and Ga-containing Ag, and Al pastes), and different resistivities were observed using different electrodes. For ZnO pellets and for hetero-contacts the gas-sensitivity was dependent on the electrode materials applied on the pellets. The greater the resistivity of the ZnO pellets, the larger the gas sensitivity of the hetero-contacts. Slight differences in the potential barrier height are induced by the different resistivities of the three ohmic contacts. The larger the band-bending at ZnO/La{sub 2}CuO{sub 4} interface, the larger the influence of adsorbates, resulting in increased sensitivity.
OSTI ID:
28852
Report Number(s):
CONF-931142--
Country of Publication:
United States
Language:
English

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