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Title: Pilot plant investigation of N{sub 2}O emissions including the effect of long term operation in circulating FBC

Book ·
OSTI ID:287968
; ;  [1];  [2]
  1. CANMET, Ottawa, Ontario (Canada)
  2. Nova Scotia Power Inc., Halifax, Nova Scotia (Canada)

A pilot plant test program was conducted at CANMET to study the emissions of nitrous oxide (N{sub 2}O) from circulating fluidized bed combustors using the same coal and similar limestones as those to be used with the 165 MWe CFBC boiler owned and operated by Nova Scotia Power Incorporated (NSPI). The feedstocks examined during this trial were Devco Prince coal and the Windsor Group and Calpo limestones, the fuel and potential sorbents for NSPI`s 165 MWe CFBC plant. Twelve tests were first carried out with the first test series (TS1) using CANMET`s 0.8 MWt pilot-scale CFBC. Later, three additional tests were conducted (test series TS2), to study the effect of long term operation on the emissions of N{sub 2}O from CFBC and generate ash for an ash utilization study under a separate program. The key parameters studied were: temperature, secondary air to primary air ratio and elevation of the secondary air injection level on N{sub 2}O emissions as well as sulfur capture, combustion efficiency and NO{sub x} and CO levels. The N{sub 2}O emissions ranged from 51 to 117 ppm (or 32 to 72 mg/MJ). As expected, temperature was the dominant influence on N{sub 2}O emissions. In addition, longer term operation (80 to 100 h) had no significant effect on N{sub 2}O emissions. Despite a change in limestones and a significant change in limestone utilization, the N{sub 2}O emissions were equivalent in the two test series. Neither was any significant correlation established by way of multilinear regression between N{sub 2}O and other emissions for the two test series (i.e., SO{sub 2}, NO{sub x}, CO or O{sub 2}).

OSTI ID:
287968
Report Number(s):
CONF-950522-; ISBN 0-7918-1305-3; TRN: IM9639%%588
Resource Relation:
Conference: 13. international conference on fluidized-bed combustion, Orlando, FL (United States), 7-10 May 1995; Other Information: PBD: 1995; Related Information: Is Part Of 13. international conference on fluidized bed combustion: Proceedings. Volume 2; Heinschel, K.J. [ed.] [Air Products and Chemicals, Inc., Allentown, PA (United States)]; PB: 823 p.
Country of Publication:
United States
Language:
English