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Title: Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}

Abstract

The reaction of IrH{sub 5}(PPr{sup i}{sub 3}){sub 2} and indene at 60 {degree}C leads to the formation of ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2} and ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}). The molecular structures of these products have been determined by single crystal X-ray diffraction studies. The {eta}{sup +3}-indenyl complex is stable only in the solid state and converts to the {eta}{sup +5}-indenyl complex product upon dissolution. 8 refs., 4 figs.

Authors:
;  [1]
  1. Univ. of Hawaii, Honolulu, HI (United States)
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
28693
Resource Type:
Journal Article
Journal Name:
Organometallics
Additional Journal Information:
Journal Volume: 14; Journal Issue: 3; Other Information: PBD: Mar 1995
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; ORGANOMETALLIC COMPOUNDS; CHEMICAL PREPARATION; INDENE; CHEMICAL REACTIONS; IRIDIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; MOLECULAR STRUCTURE; X-RAY DIFFRACTION

Citation Formats

Husebo, T L, and Jensen, C M. Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}. United States: N. p., 1995. Web. doi:10.1021/om00003a004.
Husebo, T L, & Jensen, C M. Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}. United States. https://doi.org/10.1021/om00003a004
Husebo, T L, and Jensen, C M. 1995. "Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}". United States. https://doi.org/10.1021/om00003a004.
@article{osti_28693,
title = {Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}},
author = {Husebo, T L and Jensen, C M},
abstractNote = {The reaction of IrH{sub 5}(PPr{sup i}{sub 3}){sub 2} and indene at 60 {degree}C leads to the formation of ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2} and ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}). The molecular structures of these products have been determined by single crystal X-ray diffraction studies. The {eta}{sup +3}-indenyl complex is stable only in the solid state and converts to the {eta}{sup +5}-indenyl complex product upon dissolution. 8 refs., 4 figs.},
doi = {10.1021/om00003a004},
url = {https://www.osti.gov/biblio/28693}, journal = {Organometallics},
number = 3,
volume = 14,
place = {United States},
year = {Wed Mar 01 00:00:00 EST 1995},
month = {Wed Mar 01 00:00:00 EST 1995}
}