Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}
Abstract
The reaction of IrH{sub 5}(PPr{sup i}{sub 3}){sub 2} and indene at 60 {degree}C leads to the formation of ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2} and ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}). The molecular structures of these products have been determined by single crystal X-ray diffraction studies. The {eta}{sup +3}-indenyl complex is stable only in the solid state and converts to the {eta}{sup +5}-indenyl complex product upon dissolution. 8 refs., 4 figs.
- Authors:
-
- Univ. of Hawaii, Honolulu, HI (United States)
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 28693
- Resource Type:
- Journal Article
- Journal Name:
- Organometallics
- Additional Journal Information:
- Journal Volume: 14; Journal Issue: 3; Other Information: PBD: Mar 1995
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 40 CHEMISTRY; ORGANOMETALLIC COMPOUNDS; CHEMICAL PREPARATION; INDENE; CHEMICAL REACTIONS; IRIDIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; MOLECULAR STRUCTURE; X-RAY DIFFRACTION
Citation Formats
Husebo, T L, and Jensen, C M. Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}. United States: N. p., 1995.
Web. doi:10.1021/om00003a004.
Husebo, T L, & Jensen, C M. Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}. United States. https://doi.org/10.1021/om00003a004
Husebo, T L, and Jensen, C M. 1995.
"Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}". United States. https://doi.org/10.1021/om00003a004.
@article{osti_28693,
title = {Formation of indenyl dihydride complexes from an iridium polyhydride complex. Molecular structures of ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}) and the {eta}{sup +3}-indenyl intermediate ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2}},
author = {Husebo, T L and Jensen, C M},
abstractNote = {The reaction of IrH{sub 5}(PPr{sup i}{sub 3}){sub 2} and indene at 60 {degree}C leads to the formation of ({eta}{sup +3}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}){sub 2} and ({eta}{sup +5}-C{sub 9}H{sub 7})IrH{sub 2}(PPr{sup i}{sub 3}). The molecular structures of these products have been determined by single crystal X-ray diffraction studies. The {eta}{sup +3}-indenyl complex is stable only in the solid state and converts to the {eta}{sup +5}-indenyl complex product upon dissolution. 8 refs., 4 figs.},
doi = {10.1021/om00003a004},
url = {https://www.osti.gov/biblio/28693},
journal = {Organometallics},
number = 3,
volume = 14,
place = {United States},
year = {Wed Mar 01 00:00:00 EST 1995},
month = {Wed Mar 01 00:00:00 EST 1995}
}
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