Crystal and molecular structure of the ethylenediamine complex [Tc(CO){sub 3}Br{center_dot}en]
Journal Article
·
· Radiochemistry
OSTI ID:28600
An X-ray structure analysis is completed for the ethylenediamine complex [Tc(CO){sub 3}Br{center_dot}en]. The crystals belong to the monoclinic system, a = 7.013(1), b = 13.177(8), c = 10.736(5) {angstrom}, {beta} = 101.73(3){degrees}, space group P2{sub 1}/n, Z = 4, d{sub calc} = 2.19 g/cm{sup 3}. The crystal lattice is constructed of isolated [Tc(CO){sub 3}Br{center_dot}en] molecules with the facial configuration. The total energy and bond multiplicities are calculated by the extended Hueckel method for this complex, its chloride analog, and their hypothetical meridional isomers.
- OSTI ID:
- 28600
- Journal Information:
- Radiochemistry, Journal Name: Radiochemistry Journal Issue: 3 Vol. 36; ISSN RDIOEO; ISSN 1066-3622
- Country of Publication:
- United States
- Language:
- English
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