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Title: Absorption process for producing oxygen and nitrogen and solution therefor

Patent ·
OSTI ID:27738

Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible. 1 figure

Research Organization:
Bend Research Inc
DOE Contract Number:
AC06-79ER10337
Assignee:
Bend Research, Inc., OR (United States)
Patent Number(s):
US RE 33,352/E/
Application Number:
PAN: 6-848,032
OSTI ID:
27738
Resource Relation:
Other Information: DN: Reissue of US Pat. No. 4,451,270, which was issued May 29, 1984; PBD: 25 Sep 1990
Country of Publication:
United States
Language:
English