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Title: Long-term thermal stability of alloy 825 as a high-level nuclear waste container material

Book ·
OSTI ID:264463
; ; ;  [1]
  1. Southwest Research Inst., San Antonio, TX (United States). Center for Nuclear Waste Regulatory Analyses

The thermal exposure of Fe-Cr-Ni-Mo materials to certain temperature regimes often results in the formation of grain boundary carbides and the associated depletion of alloying elements. This phenomenon, termed sensitization, is frequently the result of welding processes or in service exposure to elevated temperatures. In this investigation, alloy 825, a candidate high-level nuclear waste (HLW) container material, was thermally exposed to temperatures in the range of 550 to 800 C for periods of up to 1,000 hr. Sensitization of the material was evaluated by corrosion tests and grain boundary analyses using an analytical electron microscope. The sensitized microstructure was found to contain M{sub 23}C{sub 6}-type carbides as well as a Cr-depleted region in the vicinity of the grain boundaries. The degree of sensitization was correlated to the extent of Cr depletion in the grain boundary region.

OSTI ID:
264463
Report Number(s):
CONF-951155-; ISBN 1-55899-315-0; TRN: 96:016608
Resource Relation:
Conference: Fall meeting of the Materials Research Society (MRS), Boston, MA (United States), 27 Nov - 1 Dec 1995; Other Information: PBD: 1996; Related Information: Is Part Of Scientific basis for nuclear waste management 19; Murphy, W.M. [ed.] [Southwest Research Inst., San Antonio, TX (United States)]; Knecht, D.A. [ed.] [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States)]; PB: 957 p.; Materials Research Society symposium proceedings, Volume 412
Country of Publication:
United States
Language:
English