Cyanide-bridged lanthanide-transition metal one-dimensional arrays [(DMF){sub 10}Yb{sub 2}[Ni(CN){sub 4}]{sub 3}]{infinity} and [(DMF){sub 10}Yb{sub 2}[Pt(CN){sub 4}]{sub 3}]{infinity}
- Ohio State Univ., Columbus, OH (United States)
The one-dimensional arrays [(DMF){sub 10}Yb{sub 2}[Ni(CN){sub 4}]{sub 3}]{infinity} (1) and [(DMF){sub 10}Yb{sub 2}[Pt-(CN){sub 4}]{sub 3}]{infinity} (2) were prepared from the metathesis reactions of YbCl{sub 3} and K{sub 2}Ni(CN){sub 4} or K{sub 2}Pt(CN){sub 4} in DMF (DMF = N,N-dimethylformamide). Unlike other one-dimensional structures adopted by complexes of M(CN){sub 4}{sup 2{minus}} anions, two unusual array structures were obtained.
- OSTI ID:
- 263740
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 7 Vol. 35; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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