Influence of TiO{sub 2} surface on 1,2-chlorine shift in {Beta}-chlorine substituted radicals as studied by radiation chemistry and photocatalysis
Journal Article
·
· Journal of Physical Chemistry
- Hahn-Meitner Institut Berlin GmbH (Germany)
The influence of surface-specific parameters on the photocatalytically induced oxidative degradation of halogenated hydrocarbon in aqueous TiO{sub 2} suspensions has been evaluated by comparing the results obtained in this heterogeneous system with those from {gamma}-irradiated homogeneous aqueous solutions. A 1,2-chlorine shift known to occur in {Beta}-chlorinated alkyl radicals and the products obtained upon degradation of these radicals (particulary various chloracetic acids) have been used as markers in these investigations. 83 refs., 4 figs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 263610
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 21 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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