Intramolecular photoassociation and photoinduced charge transfer in bridged diaryl compounds. 3. Intramolecular triplet exciplex formation in fluid solutions of N-Phenyl-2-naphthylamine
Journal Article
·
· Journal of Physical Chemistry
- Univ. of Akron, OH (United States)
The time-resolved emission spectra of N-phenyl-2-naphthylamine reveal the formation of an intramolecular triplet exciplex in fluid solutions at room temperature. The exciplex formation involves transformation of the {open_quotes}noninteracting{close_quotes} conformation {sup 3}(M-X){sup *}-N, in which the excitation is largely localized on the naphthylamine (M-X) moiety, to the {open_quotes}interacting{close_quotes} conformation {sup 3}(M-X-N){sup *} with delocalized excitation. 6 refs., 8 figs.
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-89ER14024
- OSTI ID:
- 263595
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 21 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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