Ultrafast photochemistry of gas-phase transition metal carbonyls

Ramasesha, Krupa; Carlson, Daniel Ryan; Bandaranayake, Savini Sandunika

doi:10.1063/5.0266408

Ultrafast photochemistry of gas-phase transition metal carbonyls

Journal Article · Tue Jun 03 00:00:00 EDT 2025 · Chemical Physics Reviews

DOI:https://doi.org/10.1063/5.0266408· OSTI ID:2584049

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Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Organometallic photochemistry lies at the heart of photochemical energy conversions in applications such as photocatalysis, photovoltaic cells, and luminescent materials. Thus, understanding how metal and ligand interactions in organometallic complexes modify electronic excited-state properties and reactivity has been the subject of intense studies for decades. Transition metal carbonyls [M_n(CO)_m] have long served as prototypical organometallic complexes for understanding metal–ligand bonding and photochemistry and have been studied extensively in solution, matrices, and the gas phase on time scales ranging from femtoseconds to microseconds and longer. This review chronicles the past two and a half decades of efforts in understanding the ultrafast (sub-nanosecond) dynamics of transition metal carbonyls in the gas phase, where complicating solvent influences are absent and multiple experimental probes and high-level electronic structure theory can come together to yield rich information on the intricate interplay of electronic and structural dynamics. This review first lays the groundwork by briefly describing the electronic structure of transition metal carbonyls and introducing the various ultrafast techniques that have been applied to study their unimolecular dynamics. We then provide a detailed historical account on the ultrafast photochemistry of iron pentacarbonyl, nickel tetracarbonyl, and transition metal hexacarbonyls and decacarbonyls, putting the more recent ultrafast studies in the context of prior investigations. In conclusion, we end this review with an outlook on open questions and future possibilities.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: NA0003525

OSTI ID:: 2584049

Alternate ID(s):: OSTI ID: 2585629

Report Number(s):: SAND--2025-06833J; 1770346

Journal Information:: Chemical Physics Reviews, Journal Name: Chemical Physics Reviews Journal Issue: 2 Vol. 6; ISSN 2688-4070

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (168)

Termaufspaltung in Kristallen Bethe, H. Annalen der Physik, Vol. 395, Issue 2 https://doi.org/10.1002/andp.19293950202	journal	January 1929
Homogeneous Photocatalytic Reactions with Organometallic and Coordination Compounds-Perspectives for Sustainable Chemistry Hoffmann, Norbert ChemSusChem, Vol. 5, Issue 2 https://doi.org/10.1002/cssc.201100286	journal	January 2012
Ultrafast Electron Diffraction (UED): A New Development for the 4D Determination of Transient Molecular Structures Srinivasan, Ramesh; Lobastov, Vladimir A.; Ruan, Chong-Yu Helvetica Chimica Acta, Vol. 86, Issue 6 https://doi.org/10.1002/hlca.200390147	journal	June 2003
Recent advances of organometallic complexes in emerging photovoltaics Gao, Huaizhi; Yu, Runnan; Ma, Zongwen Journal of Polymer Science, Vol. 60, Issue 6 https://doi.org/10.1002/pol.20210592	journal	September 2021
Transition metals compounds: Outstanding challenges for multiconfigurational methods Pierloot, K. International Journal of Quantum Chemistry, Vol. 111, Issue 13 https://doi.org/10.1002/qua.23029	journal	March 2011
X-Ray Interactions: Photoabsorption, Scattering, Transmission, and Reflection at E = 50-30,000 eV, Z = 1-92 Henke, B. L.; Gullikson, E. M.; Davis, J. C. Atomic Data and Nuclear Data Tables, Vol. 54, Issue 2, p. 181-342 https://doi.org/10.1006/adnd.1993.1013	journal	July 1993
X-ray Free Electron Lasers Boutet, Sébastien; Fromme, Petra; Hunter, Mark S. Springer Cham https://doi.org/10.1007/978-3-030-00551-1	book	January 2018
A stroboscopical gas-electron diffraction method for the investigation of short-lived molecular species Ischenko, A. A.; Golubkov, V. V.; Spiridonov, V. P. Applied Physics B Photophysics and Laser Chemistry, Vol. 32, Issue 3 https://doi.org/10.1007/BF00688823	journal	November 1983
State correlation diagrams for the photochemical reactions of organometallics Veillard, Alain; Dedieu, Alain Theoretica Chimica Acta, Vol. 63, Issue 4 https://doi.org/10.1007/BF01151611	journal	January 1983
Population relaxation of CO(v = 1 ) vibrations in solution phase metal carbonyl complexes Heilweil, E. J.; Cavanagh, R. R.; Stephenson, J. C. Chemical Physics Letters, Vol. 134, Issue 2 https://doi.org/10.1016/0009-2614(87)87118-X	journal	February 1987
Luminescence spectra after excimer laser photolysis of Ni(CO)4 Reiner, H.; Wittenzellner, Ch.; Schröder, H. Chemical Physics Letters, Vol. 195, Issue 2-3 https://doi.org/10.1016/0009-2614(92)86130-A	journal	July 1992
Ultrafast transient infrared absorption studies of M(CO)6 (M  Cr, Mo or W) photoproducts in n-hexane solution Dougherty, T. P.; Heilweil, E. J. Chemical Physics Letters, Vol. 227, Issue 1-2 https://doi.org/10.1016/0009-2614(94)00812-4	journal	September 1994
Coherent photochemistry in solution Waldman, Amir; Ruhman, Sanford; Shaik, Sason Chemical Physics Letters, Vol. 230, Issue 1-2 https://doi.org/10.1016/0009-2614(94)01123-0	journal	November 1994
Femtochemistry of organometallics: dynamics of metal-metal and metal-ligand bond cleavage in M2(CO)10 Kyu Kim, Sang; Pedersen, Soren; Zewail, Ahmed H. Chemical Physics Letters, Vol. 233, Issue 5-6 https://doi.org/10.1016/0009-2614(95)00050-E	journal	February 1995
Femtosecond photodissociation dynamics of Fe(CO)5 in the gas phase Bañares, L.; Baumert, T.; Bergt, M. Chemical Physics Letters, Vol. 267, Issue 1-2 https://doi.org/10.1016/S0009-2614(97)00067-5	journal	March 1997
Ultrafast electron diffraction: structures in dissociation dynamics of Fe(CO)5 Ihee, H.; Cao, J.; Zewail, A. H. Chemical Physics Letters, Vol. 281, Issue 1-3 https://doi.org/10.1016/S0009-2614(97)01167-6	journal	December 1997
A CASSCF/MR-CCI study of the excited states of Fe(CO)5 Rubner, O.; Engel, V.; Hachey, M. R. Chemical Physics Letters, Vol. 302, Issue 5-6 https://doi.org/10.1016/S0009-2614(99)00149-9	journal	March 1999
Theoretical analysis of femtosecond excitation and fragmentation dynamics of Fe(CO)5 Rubner, O.; Baumert, T.; Bergt, M. Chemical Physics Letters, Vol. 316, Issue 5-6 https://doi.org/10.1016/S0009-2614(99)01352-4	journal	January 2000
Conical intersections, pseudorotation and coherent oscillations in ultrafast photodissociation of group-6 metal hexacarbonyls Trushin, S. A.; Fuß, W.; Schmid, W. E. Chemical Physics, Vol. 259, Issue 2-3 https://doi.org/10.1016/S0301-0104(00)00198-1	journal	September 2000
Relativistic effects in spectroscopy and photophysics of heavy-metal complexes illustrated by spin–orbit calculations of [Re(imidazole)(CO)3(phen)]+ Baková, Radka; Chergui, Majed; Daniel, Chantal Coordination Chemistry Reviews, Vol. 255, Issue 7-8 https://doi.org/10.1016/j.ccr.2010.12.027	journal	April 2011
Integration of organometallic complexes with semiconductors and other nanomaterials for photocatalytic H2 production Wang, Mei; Han, Kai; Zhang, Shuai Coordination Chemistry Reviews, Vol. 287 https://doi.org/10.1016/j.ccr.2014.12.005	journal	March 2015
Time-resolved photoelectron spectroscopy of polyatomic molecules using 42-nm vacuum ultraviolet laser based on high harmonics generation Nishitani, Junichi; West, Christopher W.; Higashimura, Chika Chemical Physics Letters, Vol. 684 https://doi.org/10.1016/j.cplett.2017.07.025	journal	September 2017
Primary photochemical dynamics of metal carbonyl dimers and clusters in solution: Insights into the results of metal–metal bond cleavage from ultrafast spectroscopic studies Lomont, Justin P.; Harris, Charles B. Inorganica Chimica Acta, Vol. 424 https://doi.org/10.1016/j.ica.2014.07.064	journal	January 2015
Organometallic photochemistry at the end of its first century Bitterwolf, Thomas E. Journal of Organometallic Chemistry, Vol. 689, Issue 24 https://doi.org/10.1016/j.jorganchem.2004.06.023	journal	November 2004
Heavy main group element containing organometallic phosphorescent materials Arunkumar, S.; Ghosh, Debashis; Kumar, George Rajendra Results in Chemistry, Vol. 4 https://doi.org/10.1016/j.rechem.2022.100399	journal	January 2022
Light and Molecular Ions: The Emergence of Vacuum UV Single-Photon Ionization in MS Hanley, Luke; Zimmermann, Ralf Analytical Chemistry, Vol. 81, Issue 11 https://doi.org/10.1021/ac8013675	journal	June 2009
Inorganometallic Photocatalyst for CO₂ Reduction Son, Ho-Jin; Pac, Chyongjin; Kang, Sang Ook Accounts of Chemical Research, Vol. 54, Issue 24 https://doi.org/10.1021/acs.accounts.1c00579	journal	December 2021
Element-Specific Characterization of Transient Electronic Structure of Solvated Fe(II) Complexes with Time-Resolved Soft X-ray Absorption Spectroscopy Hong, Kiryong; Cho, Hana; Schoenlein, Robert W. Accounts of Chemical Research, Vol. 48, Issue 11 https://doi.org/10.1021/acs.accounts.5b00154	journal	October 2015
Ultrafast Excited-State Processes in Inorganic Systems McCusker, James K.; Vlček, Antonín Accounts of Chemical Research, Vol. 48, Issue 5 https://doi.org/10.1021/acs.accounts.5b00235	journal	May 2015
Advanced Functional Luminescent Metallomesogens: The Key Role of the Metal Center Cuerva, Cristián; Cano, Mercedes; Lodeiro, Carlos Chemical Reviews, Vol. 121, Issue 20 https://doi.org/10.1021/acs.chemrev.1c00011	journal	August 2021
Uncovering the 3d and 4d Electronic Interactions in Solvated Ru Complexes with 2p3d Resonant Inelastic X-ray Scattering Poulter, Benjamin I.; Biasin, Elisa; Nowak, Stanisław H. Inorganic Chemistry, Vol. 62, Issue 25 https://doi.org/10.1021/acs.inorgchem.3c00919	journal	June 2023
Time-Domain Vibrational Action Spectroscopy of Cryogenically Cooled, Messenger-Tagged Ions Using Ultrafast IR Pulses Chen, Liangyi; Dean, Jessika L. S.; Fournier, Joseph A. The Journal of Physical Chemistry A, Vol. 125, Issue 47 https://doi.org/10.1021/acs.jpca.1c01996	journal	November 2021
Generation and Implementation of Continuum Infrared Pulses for Broadband Detection in 2D IR Spectroscopy Hack, John H.; Lewis, Nicholas H. C.; Knight, Samuel The Journal of Physical Chemistry A, Vol. 128, Issue 24 https://doi.org/10.1021/acs.jpca.4c01746	journal	June 2024
Excited States of the Nickel Carbonyls Ni(CO) and Ni(CO) ₄ : Challenging Molecules for Electronic Structure Theory McKinlay, Russell G.; Almeida, Nuno M. S.; Coe, Jeremy P. The Journal of Physical Chemistry A, Vol. 119, Issue 39 https://doi.org/10.1021/acs.jpca.5b04844	journal	September 2015
Vibrational Dynamics of the Intramolecular H-Bond in Acetylacetone Investigated with Transient and 2D IR Spectroscopy Dean, Jessika L. S.; Fournier, Joseph A. The Journal of Physical Chemistry B, Vol. 126, Issue 19 https://doi.org/10.1021/acs.jpcb.2c00793	journal	May 2022
Electron-Affinity Time-Dependent Density Functional Theory: Formalism and Applications to Core-Excited States Carter-Fenk, Kevin; Cunha, Leonardo A.; Arias-Martinez, Juan E. The Journal of Physical Chemistry Letters, Vol. 13, Issue 41 https://doi.org/10.1021/acs.jpclett.2c02564	journal	October 2022
Different Photodissociation Mechanisms in Fe(CO)₅ and Cr(CO)₆ Evidenced with Femtosecond Valence Photoelectron Spectroscopy and Excited-State Molecular Dynamics Simulations Schröder, Henning; Coates, Michael R.; Jay, Raphael M. The Journal of Physical Chemistry Letters, Vol. 15, Issue 47 https://doi.org/10.1021/acs.jpclett.4c02025	journal	November 2024
Femtosecond Soft-X-ray Absorption Spectroscopy of Liquids with a Water-Window High-Harmonic Source Smith, Adam D.; Balčiu̅nas, Tadas; Chang, Yi-Ping The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.9b03559	journal	February 2020
Ultrafast Production of NiCO and Ni Following 197 nm Photodissociation of Nickel Tetracarbonyl Cole-Filipiak, Neil C.; Troß, Jan; Schrader, Paul ACS Physical Chemistry Au, Vol. 4, Issue 6 https://doi.org/10.1021/acsphyschemau.4c00033	journal	August 2024
Shedding light on organometallic reactions: the characterization of tetracarbonyliron (Fe(CO)4), a prototypical reaction intermediate Poliakoff, Martyn; Weitz, Eric Accounts of Chemical Research, Vol. 20, Issue 11 https://doi.org/10.1021/ar00143a004	journal	November 1987
Ultrafast Infrared Studies of the Role of Spin States in Organometallic Reaction Dynamics Lomont, Justin P.; Nguyen, Son C.; Harris, Charles B. Accounts of Chemical Research, Vol. 47, Issue 5 https://doi.org/10.1021/ar500032d	journal	April 2014
Ultrafast Photophysics of Transition Metal Complexes Chergui, Majed Accounts of Chemical Research, Vol. 48, Issue 3 https://doi.org/10.1021/ar500358q	journal	February 2015
Ultrafast Infrared Studies of Bond Activation in Organometallic Complexes Yang, Haw; Kotz, Kenneth T.; Asplund, Matthew C. Accounts of Chemical Research, Vol. 32, Issue 7 https://doi.org/10.1021/ar970133y	journal	February 1999
Photochemistry of metal-metal bonds Meyer, Thomas J.; Caspar, Jonathan V. Chemical Reviews, Vol. 85, Issue 3 https://doi.org/10.1021/cr00067a002	journal	June 1985
Femtosecond Time-Resolved Photoelectron Spectroscopy Stolow, Albert; Bragg, Arthur E.; Neumark, Daniel M. Chemical Reviews, Vol. 104, Issue 4 https://doi.org/10.1021/cr020683w	journal	April 2004
Photochemistry of metal carbonyls Wrighton, Mark Chemical Reviews, Vol. 74, Issue 4 https://doi.org/10.1021/cr60290a001	journal	August 1974
Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products Corey, Joyce Y. Chemical Reviews, Vol. 111, Issue 2 https://doi.org/10.1021/cr900359c	journal	February 2011
I - Ligand field theory Cotton, F. Albert Journal of Chemical Education, Vol. 41, Issue 9 https://doi.org/10.1021/ed041p466	journal	September 1964
Structures and kinetics of pentacarbonylchromium and pentacarbonylchromium monohydrate Church, Stephen P.; Grevels, Friedrich Wilhelm; Hermann, Horst Inorganic Chemistry, Vol. 24, Issue 3 https://doi.org/10.1021/ic00197a033	journal	January 1985
Electronic spectra of the d6 binary carbonyl complexes hexacarbonylmanganese(1+), hexacarbonylchromium and hexacarbonylvanadate(1-): an ab initio analysis Pierloot, K.; Verhulst, J.; Verbeke, P. Inorganic Chemistry, Vol. 28, Issue 15 https://doi.org/10.1021/ic00314a039	journal	July 1989
Photolysis and spectroscopy with polarized light: key to the photochemistry of pentacarbonylchromium and related species Burdett, Jeremy K.; Grzybowski, Joseph M.; Perutz, Robin N. Inorganic Chemistry, Vol. 17, Issue 1 https://doi.org/10.1021/ic50179a028	journal	January 1978
Transient Infrared Spectroscopy as a Probe of Coordinatively Unsaturated Metal Carbonyls in the Gas Phase Weitz, Eric The Journal of Physical Chemistry, Vol. 98, Issue 44 https://doi.org/10.1021/j100095a005	journal	November 1994
Femtosecond infrared spectroscopy: ultrafast photochemistry of iron carbonyls in solution Anfinrud, Philip A.; Han, Chul Hee; Lian, Tianquan The Journal of Physical Chemistry, Vol. 95, Issue 2 https://doi.org/10.1021/j100155a017	journal	January 1991
Reaction kinetics of coordinatively unsaturated iron carbonyls formed on gas-phase excimer laser photolysis of iron pentacarbonyl Ryther, Robert J.; Weitz, Eric The Journal of Physical Chemistry, Vol. 95, Issue 24 https://doi.org/10.1021/j100177a043	journal	November 1991
Diode laser probes of the product distribution of coordinatively unsaturated iron carbonyls produced following excimer laser photolysis of iron pentacarbonyl in the gas phase Ryther, Robert J.; Weitz, Eric The Journal of Physical Chemistry, Vol. 96, Issue 6 https://doi.org/10.1021/j100185a031	journal	March 1992
Studies of coordinatively unsaturated metal carbonyls in the gas phase by transient infrared spectroscopy Weitz, Eric. The Journal of Physical Chemistry, Vol. 91, Issue 15 https://doi.org/10.1021/j100299a007	journal	July 1987
Multiple luminescence spectra from continuous wave excitation of room temperature gas-phase nickel tetracarbonyl Preston, D. M.; Zink, Jeffrey I. The Journal of Physical Chemistry, Vol. 91, Issue 19 https://doi.org/10.1021/j100303a022	journal	September 1987
Theoretical aspects of the photochemistry of organometallics. 3. Potential energy curves for the photodissociation of pentacarbonyliron (Fe(CO)5) Daniel, Chantal; Benard, Marc; Dedieu, Alain The Journal of Physical Chemistry, Vol. 88, Issue 21 https://doi.org/10.1021/j150665a004	journal	October 1984
A transient infrared spectroscopy study of coordinatively unsaturated ruthenium carbonyls Bogdan, Paula L.; Weitz, Eric Journal of the American Chemical Society, Vol. 111, Issue 9 https://doi.org/10.1021/ja00191a009	journal	April 1989
Picosecond infrared probing of metal carbonyl photodissociation products Moore, John N.; Hansen, Patricia A.; Hochstrasser, Robin M. Journal of the American Chemical Society, Vol. 111, Issue 13 https://doi.org/10.1021/ja00195a005	journal	June 1989
Ultrafast studies of transition metal carbonyl reactions in the condensed phase. Solvation of coordinatively unsaturated pentacarbonyls Lee, M.; Harris, Charles B. Journal of the American Chemical Society, Vol. 111, Issue 24 https://doi.org/10.1021/ja00206a054	journal	November 1989
Triplet Organometallic Reactivity under Ambient Conditions: An Ultrafast UV Pump/IR Probe Study Snee, Preston T.; Payne, Christine K.; Kotz, Kenneth T. Journal of the American Chemical Society, Vol. 123, Issue 10 https://doi.org/10.1021/ja002350r	journal	March 2001
Visible transients in gas phase UV photolysis of transition metal compounds: experimental and theoretical results for nickel carbonyl (Ni(CO)4) Roesch, Notker.; Kotzian, Manfred.; Joerg, Harald. Journal of the American Chemical Society, Vol. 108, Issue 14 https://doi.org/10.1021/ja00274a073	journal	July 1986
Wavelength dependence of excimer laser photolysis of Cr(CO)6 in the gas phase. A study of the infrared spectroscopy and reactions of the Cr(CO)x (x = 5, 4, 3, 2) fragments Seder, T. A.; Church, Stephen P.; Weitz, Eric. Journal of the American Chemical Society, Vol. 108, Issue 16 https://doi.org/10.1021/ja00276a007	journal	August 1986
Photochemistry of gas-phase decacarbonyldimanganese (Mn2(CO)10) and decacarbonyldirhenium (Re2(CO)10): mass spectrometric evidence for a dinuclear primary photoproduct Leopold, D. G.; Vaida, V. Journal of the American Chemical Society, Vol. 106, Issue 13 https://doi.org/10.1021/ja00325a002	journal	June 1984
Organometallic bond dissociation energies: laser pyrolysis of iron pentacarbonyl, chromium hexacarbonyl, molybdenum hexacarbonyl, and tungsten hexacarbonyl Lewis, Karan E.; Golden, David M.; Smith, Gregory P. Journal of the American Chemical Society, Vol. 106, Issue 14 https://doi.org/10.1021/ja00326a004	journal	July 1984
Relative importance of metal-metal bond scission and loss of carbon monoxide from photoexcited dimanganese decacarbonyl: spectroscopic detection of a coordinatively unsaturated, carbonyl-bridged dinuclear species in low-temperature alkane matrices Hepp, Aloysius F.; Wrighton, Mark S. Journal of the American Chemical Society, Vol. 105, Issue 18 https://doi.org/10.1021/ja00356a047	journal	September 1983
Laser photolysis study of the photosubstitution in dimanganese decacarbonyl Yesaka, Hiroshi; Kobayashi, Takayoshi; Yasufuku, Katsutoshi Journal of the American Chemical Society, Vol. 105, Issue 20 https://doi.org/10.1021/ja00358a010	journal	September 1983
Picosecond dynamics of solution-phase photofragmentation of dimanganese decacarbonyl [Mn2(CO)10] Rothberg, Lewis J.; Cooper, N. John; Peters, Kevin S. Journal of the American Chemical Society, Vol. 104, Issue 12 https://doi.org/10.1021/ja00376a063	journal	June 1982
Laser photoelectron spectrometry of Ni(CO)n-, n = 1-3 Stevens, Amy E.; Feigerle, C. S.; Lineberger, W. C. Journal of the American Chemical Society, Vol. 104, Issue 19 https://doi.org/10.1021/ja00383a004	journal	September 1982
Photodissociation of molecular beams. Cleavage of metal-metal bonds in rhenium and manganese decacarbonyl Freedman, Andrew; Bersohn, Richard Journal of the American Chemical Society, Vol. 100, Issue 13 https://doi.org/10.1021/ja00481a021	journal	June 1978
Laser photoelectron spectrometry of the negative ions of iron and iron carbonyls. Electron affinity determination for the series Fe(CO)n, n = 0,1,2,3,4 Engelking, P. C.; Lineberger, W. C. Journal of the American Chemical Society, Vol. 101, Issue 19 https://doi.org/10.1021/ja00513a019	journal	September 1979
Electronic structure of compounds containing metal-metal bonds. Decacarbonyldimetal and related complexes Levenson, Robert A.; Gray, Harry B. Journal of the American Chemical Society, Vol. 97, Issue 21 https://doi.org/10.1021/ja00854a015	journal	October 1975
Electronic structures of metal hexacarbonyls Beach, Nancy A.; Gray, Harry B. Journal of the American Chemical Society, Vol. 90, Issue 21 https://doi.org/10.1021/ja01023a011	journal	October 1968
Dynamics of Photosubstitution Reactions of Fe(CO) ₅ : An Ultrafast Infrared Study of High Spin Reactivity Snee, Preston T.; Payne, Christine K.; Mebane, Sheryl D. Journal of the American Chemical Society, Vol. 123, Issue 28 https://doi.org/10.1021/ja010648r	journal	July 2001
Unraveling the Photochemistry of Fe(CO) ₅ in Solution: Observation of Fe(CO) ₃ and the Conversion between ³ Fe(CO) ₄ and ¹ Fe(CO) ₄ (Solvent) Portius, Peter; Yang, Jixin; Sun, Xue-Zhong Journal of the American Chemical Society, Vol. 126, Issue 34 https://doi.org/10.1021/ja048411t	journal	September 2004
Ultrafast Structural Dynamics in BLUF Domains: Transient Infrared Spectroscopy of AppA and Its Mutants Stelling, Allison L.; Ronayne, Kate L.; Nappa, Jérôme Journal of the American Chemical Society, Vol. 129, Issue 50 https://doi.org/10.1021/ja074074n	journal	November 2007
Ultrafast Observation of a Solvent Dependent Spin State Equilibrium in CpCo(CO) Lomont, Justin P.; Nguyen, Son C.; Schlegel, Jacob P. Journal of the American Chemical Society, Vol. 134, Issue 6 https://doi.org/10.1021/ja2098468	journal	January 2012
Electronic Spectra of M(CO) ₆ (M = Cr, Mo, W) Revisited by a Relativistic TDDFT Approach Rosa, Angela; Baerends, Evert Jan; van Gisbergen, Stan J. A. Journal of the American Chemical Society, Vol. 121, Issue 44 https://doi.org/10.1021/ja990747t	journal	November 1999
Femtosecond Core-Level Spectroscopy Reveals Involvement of Triplet States in the Gas-Phase Photodissociation of Fe(CO)₅ Troß, Jan; Arias-Martinez, Juan E.; Carter-Fenk, Kevin Journal of the American Chemical Society, Vol. 146, Issue 32 https://doi.org/10.1021/jacs.4c07523	journal	August 2024
Ultrafast Photodissociation Dynamics of Ni(CO) ₄ Fuss, W.; Schmid, W. E.; Trushin, S. A. The Journal of Physical Chemistry A, Vol. 105, Issue 2 https://doi.org/10.1021/jp002276z	journal	December 2000
Non-Adiabatic Direct Dynamics Study of Chromium Hexacarbonyl Photodissociation Paterson, Martin J.; Hunt, Patricia A.; Robb, Michael A. The Journal of Physical Chemistry A, Vol. 106, Issue 44 https://doi.org/10.1021/jp026394t	journal	November 2002
Vibrational Dynamics of Terminal Acetylenes: I. Comparison of the Intramolecular Vibrational Energy Redistribution Rate of Gases and the Total Relaxation Rate of Dilute Solutions at Room Temperature Yoo, Hyun S.; DeWitt, Merrick J.; Pate, Brooks H. The Journal of Physical Chemistry A, Vol. 108, Issue 8 https://doi.org/10.1021/jp027543a	journal	January 2004
The Influence of the Metal Spin State in the Iron-Catalyzed Alkene Isomerization Reaction Studied with Ultrafast Infrared Spectroscopy ^† Glascoe, Elizabeth A.; Sawyer, Karma R.; Shanoski, Jennifer E. The Journal of Physical Chemistry C, Vol. 111, Issue 25 https://doi.org/10.1021/jp068576j	journal	June 2007
Primary Reactions of Bacteriophytochrome Observed with Ultrafast Mid-Infrared Spectroscopy Toh, K. C.; Stojković, Emina A.; Rupenyan, Alisa B. The Journal of Physical Chemistry A, Vol. 115, Issue 16 https://doi.org/10.1021/jp106891x	journal	April 2011
UV Photochemistry of [CpFe(CO)₂]₂ (Cp = η⁵-C₅H₅) Studied by Picosecond Time-Resolved Infrared Spectroscopy George, Michael W.; Dougherty, Thomas P.; Heilweil, Edwin J. The Journal of Physical Chemistry, Vol. 100, Issue 1 https://doi.org/10.1021/jp952027o	journal	January 1996
Femtosecond Infrared Studies of the Dissociation and Dynamics of Transition Metal Carbonyls in Solution Lian, Tianquan; Bromberg, Steven E.; Asplund, Matthew C. The Journal of Physical Chemistry, Vol. 100, Issue 29 https://doi.org/10.1021/jp9618035	journal	January 1996
Femtosecond Dynamics and Vibrational Coherence in Gas-Phase Ultraviolet Photodecomposition of Cr(CO) ₆ Trushin, S. A.; Fuss, W.; Schmid, W. E. The Journal of Physical Chemistry A, Vol. 102, Issue 23 https://doi.org/10.1021/jp973133o	journal	June 1998
Ultrafast Dynamics of Transition Metal Carbonyls: Photodissociation of Cr(CO)₆ and Cr(CO)₆·(CH₃OH)_n Heteroclusters at 280 nm Gutmann, Michael; Janello, Jörg M.; Dickebohm, Markus S. The Journal of Physical Chemistry A, Vol. 102, Issue 23 https://doi.org/10.1021/jp9803081	journal	April 1998
Femtosecond Dynamics of Fe(CO) ₅ Photodissociation at 267 nm Studied by Transient Ionization Trushin, S. A.; Fuss, W.; Kompa, K. L. The Journal of Physical Chemistry A, Vol. 104, Issue 10 https://doi.org/10.1021/jp992474u	journal	March 2000
Ultrafast Infrared Mechanistic Studies of the Interaction of 1-Hexyne with Group 6 Hexacarbonyl Complexes Shanoski, Jennifer E.; Payne, Christine K.; Kling, Matthias F. Organometallics, Vol. 24, Issue 8 https://doi.org/10.1021/om049101m	journal	March 2005
Mechanism for Iron-Catalyzed Alkene Isomerization in Solution Sawyer, Karma R.; Glascoe, Elizabeth A.; Cahoon, James F. Organometallics, Vol. 27, Issue 17 https://doi.org/10.1021/om800481r	journal	August 2008
Clocking transient chemical changes by ultrafast electron diffraction Williamson, J. Charles; Cao, Jianming; Ihee, Hyotcherl Nature, Vol. 386, Issue 6621 https://doi.org/10.1038/386159a0	journal	March 1997
Switching on elusive organometallic mechanisms with photoredox catalysis Terrett, Jack A.; Cuthbertson, James D.; Shurtleff, Valerie W. Nature, Vol. 524, Issue 7565 https://doi.org/10.1038/nature14875	journal	August 2015
Attosecond science Corkum, P. B.; Krausz, Ferenc Nature Physics, Vol. 3, Issue 6 https://doi.org/10.1038/nphys620	journal	June 2007
Photoinduced bond oscillations in ironpentacarbonyl give delayed synchronous bursts of carbonmonoxide release Banerjee, Ambar; Coates, Michael R.; Kowalewski, Markus Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-28997-z	journal	March 2022
The photochemical ring-opening of 1,3-cyclohexadiene imaged by ultrafast electron diffraction Wolf, T. J. A.; Sanchez, D. M.; Yang, J. Nature Chemistry, Vol. 11, Issue 6 https://doi.org/10.1038/s41557-019-0252-7	journal	April 2019
Ultrafast X-ray scattering reveals vibrational coherence following Rydberg excitation Stankus, Brian; Yong, Haiwang; Zotev, Nikola Nature Chemistry, Vol. 11, Issue 8 https://doi.org/10.1038/s41557-019-0291-0	journal	July 2019
The merger of transition metal and photocatalysis Twilton, Jack; Le, Chi; Zhang, Patricia Nature Reviews Chemistry, Vol. 1, Issue 7 https://doi.org/10.1038/s41570-017-0052	journal	July 2017
Bright continuously tunable vacuum ultraviolet source for ultrafast spectroscopy Jurkovičová, Lucie; Ben Ltaief, Ltaief; Hult Roos, Andreas Communications Physics, Vol. 7, Issue 1 https://doi.org/10.1038/s42005-023-01513-5	journal	January 2024
Estimating the (CO)5Cr–(η2-benzene) bond dissociation enthalpy: reaction of the (CO)5Cr(η2-benzene) complex with a series of (CH3)nTHF (n = 0, 1, 2, and 4) ligands Bengali, Ashfaq A.; Stumbaugh, Trent F. Dalton Transactions, Issue 3 https://doi.org/10.1039/B210575F	journal	January 2003
Ultrafast infrared spectroscopy reveals water-mediated coherent dynamics in an enzyme active site Adamczyk, Katrin; Simpson, Niall; Greetham, Gregory M. Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02752C	journal	January 2015
Ultrafast vibrational and structural dynamics of dimeric cyclopentadienyliron dicarbonyl examined by infrared spectroscopy Yang, Fan; Yu, Pengyun; Zhao, Juan Physical Chemistry Chemical Physics, Vol. 17, Issue 22 https://doi.org/10.1039/C5CP00965K	journal	January 2015
Femtosecond gas phase electron diffraction with MeV electrons Yang, Jie; Guehr, Markus; Vecchione, Theodore Faraday Discussions, Vol. 194 https://doi.org/10.1039/C6FD00071A	journal	January 2016
Photochemistry of transition metal carbonyls Turner, James J.; George, Michael W.; Poliakoff, Martyn Chemical Society Reviews, Vol. 51, Issue 13 https://doi.org/10.1039/D1CS00826A	journal	January 2022
Observation of parallel intersystem crossing and charge transfer-state dynamics in [Fe(bpy)₃]²⁺ from ultrafast 2D electronic spectroscopy Lee, Angela; Son, Minjung; Deegbey, Mawuli Chemical Science, Vol. 14, Issue 45 https://doi.org/10.1039/D3SC02613B	journal	January 2023
Structure and reactions of matrix-isolated tetracarbonyliron(0) Poliakoff, Martyn; Turner, James J. Journal of the Chemical Society, Dalton Transactions, Issue 20 https://doi.org/10.1039/DT9740002276	journal	January 1974
Ligand-field theory Griffith, J. S.; Orgel, L. E. Quarterly Reviews, Chemical Society, Vol. 11, Issue 4 https://doi.org/10.1039/qr9571100381	journal	January 1957
Velocity map imaging of ions and electrons using electrostatic lenses: Application in photoelectron and photofragment ion imaging of molecular oxygen Eppink, André T. J. B.; Parker, David H. Review of Scientific Instruments, Vol. 68, Issue 9 https://doi.org/10.1063/1.1148310	journal	September 1997
A laser-based instrument for the study of ultrafast chemical dynamics by soft x-ray-probe photoelectron spectroscopy Nugent-Glandorf, Lora; Scheer, Michael; Samuels, David A. Review of Scientific Instruments, Vol. 73, Issue 4 https://doi.org/10.1063/1.1459094	journal	April 2002
A tabletop femtosecond time-resolved soft x-ray transient absorption spectrometer Loh, Zhi-Heng; Khalil, Munira; Correa, Raoul E. Review of Scientific Instruments, Vol. 79, Issue 7 https://doi.org/10.1063/1.2947737	journal	July 2008
Femtosecond time-resolved photoelectron spectroscopy with a vacuum-ultraviolet photon source based on laser high-order harmonic generation Wernet, Philippe; Gaudin, Jérôme; Godehusen, Kai Review of Scientific Instruments, Vol. 82, Issue 6 https://doi.org/10.1063/1.3600901	journal	June 2011
Fragmentation and molecular dynamics in the laser photodissociation of iron pentacarbonyl Yardley, James T.; Gitlin, Barbara; Nathanson, Gilbert The Journal of Chemical Physics, Vol. 74, Issue 1 https://doi.org/10.1063/1.440843	journal	January 1981
The metal–carbonyl bond in Ni(CO) ₄ and Fe(CO) ₅ : A clear‐cut analysis Bauschlicher, Charles W.; Bagus, Paul S. The Journal of Chemical Physics, Vol. 81, Issue 12 https://doi.org/10.1063/1.447589	journal	December 1984
The wavelength dependence of excimer laser photolysis of Fe(CO) ₅ in the gas phase. Transient infrared spectroscopy and kinetics of the Fe(CO) _x ( x =4,3,2) photofragments Seder, T. A.; Ouderkirk, A. J.; Weitz, Eric The Journal of Chemical Physics, Vol. 85, Issue 4 https://doi.org/10.1063/1.451141	journal	August 1986
CO(v=1) population lifetimes of metal–carbonyl cluster compounds in dilute CHCl3 solution Heilweil, E. J.; Cavanagh, R. R.; Stephenson, J. C. The Journal of Chemical Physics, Vol. 89, Issue 1 https://doi.org/10.1063/1.455510	journal	July 1988
State resolved photofragmentation of Ni(CO) ₄ at 193, 248, and 308 nm: A detailed study of the photodissociation dynamics Schlenker, F. J.; Bouchard, F.; Waller, I. M. The Journal of Chemical Physics, Vol. 93, Issue 10 https://doi.org/10.1063/1.459434	journal	November 1990
Branching ratios and bond dissociation energies from the excimer laser photolysis of group 6 metal carbonyls Rayner, D. M.; Ishikawa, Y.; Brown, C. E. The Journal of Chemical Physics, Vol. 94, Issue 8 https://doi.org/10.1063/1.460482	journal	April 1991
Photodissociation dynamics of Mn2(CO)1 in solution on ultrafast time scales Zhang, J. Z.; Harris, C. B. The Journal of Chemical Physics, Vol. 95, Issue 6 https://doi.org/10.1063/1.460757	journal	September 1991
Transient infrared spectroscopy of (η5−C5 H5)Co(CO)2 photoproduct reactions in hydrocarbon solutions Dougherty, T. P.; Heilweil, E. J. The Journal of Chemical Physics, Vol. 100, Issue 5 https://doi.org/10.1063/1.466334	journal	March 1994
Theoretical study of the vibrational spectra of the transition metal carbonyls M(CO) ₆ [M=Cr, Mo, W], M(CO) ₅ [M=Fe, Ru, Os], and M(CO) ₄ [M=Ni, Pd, Pt] Jonas, Volker; Thiel, Walter The Journal of Chemical Physics, Vol. 102, Issue 21 https://doi.org/10.1063/1.468839	journal	June 1995
Theoretical study on the excitation spectrum and the photofragmentation reaction of Ni(CO) ₄ Hada, M.; Imai, Y.; Hidaka, M. The Journal of Chemical Physics, Vol. 103, Issue 16 https://doi.org/10.1063/1.470325	journal	October 1995
Photoelectron and photofragment velocity map imaging of state-selected molecular oxygen dissociation/ionization dynamics Parker, D. H.; Eppink, A. T. J. B. The Journal of Chemical Physics, Vol. 107, Issue 7 https://doi.org/10.1063/1.474624	journal	August 1997
The ultrafast photodissociation of Fe(CO)5 in the gas phase Bañares, L.; Baumert, T.; Bergt, M. The Journal of Chemical Physics, Vol. 108, Issue 14 https://doi.org/10.1063/1.475991	journal	April 1998
Time-resolved dissociative intense-laser field ionization for probing dynamics: Femtosecond photochemical ring opening of 1,3-cyclohexadiene Fuß, W.; Schmid, W. E.; Trushin, S. A. The Journal of Chemical Physics, Vol. 112, Issue 19 https://doi.org/10.1063/1.481478	journal	May 2000
Resonant photoemission at the iron M-edge of Fe(CO) ₅ Sistrunk, E.; Grilj, J.; McFarland, B. K. The Journal of Chemical Physics, Vol. 139, Issue 16 https://doi.org/10.1063/1.4827093	journal	October 2013
Mega-electron-volt ultrafast electron diffraction at SLAC National Accelerator Laboratory Weathersby, S. P.; Brown, G.; Centurion, M. Review of Scientific Instruments, Vol. 86, Issue 7 https://doi.org/10.1063/1.4926994	journal	July 2015
Identification of the dominant photochemical pathways and mechanistic insights to the ultrafast ligand exchange of Fe(CO)5 to Fe(CO)4EtOH Kunnus, K.; Josefsson, I.; Rajkovic, I. Structural Dynamics, Vol. 3, Issue 4 https://doi.org/10.1063/1.4941602	journal	February 2016
Communication: Direct evidence for sequential dissociation of gas-phase Fe(CO)5 via a singlet pathway upon excitation at 266 nm Wernet, Ph.; Leitner, T.; Josefsson, I. The Journal of Chemical Physics, Vol. 146, Issue 21 https://doi.org/10.1063/1.4984774	journal	June 2017
Time-resolved electron spectroscopy for chemical analysis of photodissociation: Photoelectron spectra of Fe(CO) ₅ , Fe(CO) ₄ , and Fe(CO) ₃ Leitner, T.; Josefsson, I.; Mazza, T. The Journal of Chemical Physics, Vol. 149, Issue 4 https://doi.org/10.1063/1.5035149	journal	July 2018
Femtosecond gas-phase mega-electron-volt ultrafast electron diffraction Shen, X.; Nunes, J. P. F.; Yang, J. Structural Dynamics, Vol. 6, Issue 5 https://doi.org/10.1063/1.5120864	journal	September 2019
Ultrafast x-ray and electron scattering of free molecules: A comparative evaluation Ma, Lingyu; Yong, Haiwang; Geiser, Joseph D. Structural Dynamics, Vol. 7, Issue 3 https://doi.org/10.1063/4.0000010	journal	May 2020
Ultraviolet photodissociation of gas-phase iron pentacarbonyl probed with ultrafast infrared spectroscopy Cole-Filipiak, Neil C.; Troß, Jan; Schrader, Paul The Journal of Chemical Physics, Vol. 154, Issue 13 https://doi.org/10.1063/5.0041074	journal	April 2021
Using a multistate mapping approach to surface hopping to predict the ultrafast electron diffraction signal of gas-phase cyclobutanone Hutton, Lewis; Moreno Carrascosa, Andrés; Prentice, Andrew W. The Journal of Chemical Physics, Vol. 160, Issue 20 https://doi.org/10.1063/5.0203667	journal	May 2024
Non-adiabatic dynamics of photoexcited cyclobutanone: Predicting structural measurements from trajectory surface hopping with XMS-CASPT2 simulations Vindel-Zandbergen, Patricia; González-Vázquez, Jesús The Journal of Chemical Physics, Vol. 161, Issue 2 https://doi.org/10.1063/5.0203722	journal	July 2024
Prediction of photodynamics of 200 nm excited cyclobutanone with linear response electronic structure and ab initio multiple spawning Hait, Diptarka; Lahana, Dean; Fajen, O. Jonathan The Journal of Chemical Physics, Vol. 160, Issue 24 https://doi.org/10.1063/5.0203800	journal	June 2024
Brighter, faster, stronger: ultrafast scattering of free molecules Odate, Asami; Kirrander, Adam; Weber, Peter M. Advances in Physics: X, Vol. 8, Issue 1 https://doi.org/10.1080/23746149.2022.2126796	journal	December 2022
Time-resolved experiments on gas-phase atoms and molecules with XUV and X-ray free-electron lasers Rolles, Daniel Advances in Physics: X, Vol. 8, Issue 1 https://doi.org/10.1080/23746149.2022.2132182	journal	October 2022
Ultrafast imaging of isolated molecules with electron diffraction Centurion, Martin Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 49, Issue 6 https://doi.org/10.1088/0953-4075/49/6/062002	journal	February 2016
Advances in ultrafast gas-phase x-ray scattering Stankus, Brian; Yong, Haiwang; Ruddock, Jennifer Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 53, Issue 23 https://doi.org/10.1088/1361-6455/abbfea	journal	November 2020
Time-resolved x-ray photoelectron spectroscopy at FLASH Hellmann, S.; Sohrt, C.; Beye, M. New Journal of Physics, Vol. 14, Issue 1 https://doi.org/10.1088/1367-2630/14/1/013062	journal	January 2012
Stability of polyatomic molecules in degenerate electronic states - I—Orbital degeneracy Jahn, H. A.; Teller, E. Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences, Vol. 161, Issue 905, p. 220-235 https://doi.org/10.1098/rspa.1937.0142	journal	July 1937
Theory of the Variations in Paramagnetic Anisotropy Among Different Salts of the Iron Group Van Vleck, J. H. Physical Review, Vol. 41, Issue 2 https://doi.org/10.1103/PhysRev.41.208	journal	July 1932
Theory of high-harmonic generation by low-frequency laser fields Lewenstein, M.; Balcou, Ph.; Ivanov, M. Yu. Physical Review A, Vol. 49, Issue 3 https://doi.org/10.1103/PhysRevA.49.2117	journal	March 1994
Time-Resolved Electron Diffraction from Selectively Aligned Molecules Reckenthaeler, Peter; Centurion, Martin; Fuß, Werner Physical Review Letters, Vol. 102, Issue 21 https://doi.org/10.1103/PhysRevLett.102.213001	journal	May 2009
Imaging of Isolated Molecules with Ultrafast Electron Pulses Hensley, Christopher J.; Yang, Jie; Centurion, Martin Physical Review Letters, Vol. 109, Issue 13 https://doi.org/10.1103/PhysRevLett.109.133202	journal	September 2012
Plasma perspective on strong field multiphoton ionization Corkum, P. B. Physical Review Letters, Vol. 71, Issue 13 https://doi.org/10.1103/PhysRevLett.71.1994	journal	September 1993
High-resolution movies of molecular rotational dynamics captured with ultrafast electron diffraction Xiong, Yanwei; Wilkin, Kyle J.; Centurion, Martin Physical Review Research, Vol. 2, Issue 4 https://doi.org/10.1103/PhysRevResearch.2.043064	journal	October 2020
The Coherent X-ray Imaging instrument at the Linac Coherent Light Source Liang, Mengning; Williams, Garth J.; Messerschmidt, Marc Journal of Synchrotron Radiation, Vol. 22, Issue 3 https://doi.org/10.1107/S160057751500449X	journal	April 2015
Introduction to x-ray photoelectron spectroscopy Stevie, Fred A.; Donley, Carrie L. Journal of Vacuum Science & Technology A, Vol. 38, Issue 6 https://doi.org/10.1116/6.0000412	journal	December 2020
Time-resolved x-ray absorption spectroscopy with a water window high-harmonic source Pertot, Yoann; Schmidt, Cédric; Matthews, Mary Science, Vol. 355, Issue 6322 https://doi.org/10.1126/science.aah6114	journal	January 2017
Electronic structure in the transition metal block and its implications for light harvesting McCusker, James K. Science, Vol. 363, Issue 6426 https://doi.org/10.1126/science.aav9104	journal	January 2019
Simultaneous observation of nuclear and electronic dynamics by ultrafast electron diffraction Yang, Jie; Zhu, Xiaolei; F. Nunes, J. Pedro Science, Vol. 368, Issue 6493 https://doi.org/10.1126/science.abb2235	journal	May 2020
Vacuum Ultraviolet Photoionization of Complex Chemical Systems Kostko, Oleg; Bandyopadhyay, Biswajit; Ahmed, Musahid Annual Review of Physical Chemistry, Vol. 67, Issue 1 https://doi.org/10.1146/annurev-physchem-040215-112553	journal	May 2016
State-to-State Spectroscopy and Dynamics of Ions and Neutrals by Photoionization and Photoelectron Methods Ng, Cheuk-Yiu Annual Review of Physical Chemistry, Vol. 65, Issue 1 https://doi.org/10.1146/annurev-physchem-040412-110002	journal	April 2014
Femtosecond Extreme Ultraviolet Absorption Spectroscopy of Transition Metal Complexes Vura-Weis, Josh Annual Review of Physical Chemistry, Vol. 76, Issue 1 https://doi.org/10.1146/annurev-physchem-082720-031657	journal	April 2025
T IME -R ESOLVED P HOTOELECTRON S PECTROSCOPY OF M OLECULES AND C LUSTERS Neumark, Daniel M. Annual Review of Physical Chemistry, Vol. 52, Issue 1 https://doi.org/10.1146/annurev.physchem.52.1.255	journal	October 2001
F EMTOSECOND T IME -R ESOLVED P HOTOELECTRON S PECTROSCOPY OF P OLYATOMIC M OLECULES Stolow, Albert Annual Review of Physical Chemistry, Vol. 54, Issue 1 https://doi.org/10.1146/annurev.physchem.54.011002.103809	journal	October 2003
Ultrafast photochemistry of metal carbonyls Fuß, W.; Trushin, S. A.; Schmid, W. E. Research on Chemical Intermediates, Vol. 27, Issue 4-5 https://doi.org/10.1163/156856701104202093	journal	July 2001
Generation, shaping, and characterization of intense femtosecond pulses tunable from 3 to 20 μm Kaindl, Robert A.; Wurm, Matthias; Reimann, Klaus Journal of the Optical Society of America B, Vol. 17, Issue 12, p. 2086-2094 https://doi.org/10.1364/JOSAB.17.002086	journal	January 2000
Intense terahertz pulses by four-wave rectification in air Cook, D. J.; Hochstrasser, R. M. Optics Letters, Vol. 25, Issue 16 https://doi.org/10.1364/OL.25.001210	journal	January 2000
Generation of sub-two-cycle mid-infrared pulses by four-wave mixing through filamentation in air Fuji, Takao; Suzuki, Toshinori Optics Letters, Vol. 32, Issue 22 https://doi.org/10.1364/OL.32.003330	journal	January 2007
Source for ultrafast continuum infrared and terahertz radiation Petersen, Poul B.; Tokmakoff, Andrei Optics Letters, Vol. 35, Issue 12 https://doi.org/10.1364/OL.35.001962	journal	January 2010
Ultrafast continuum mid-infrared spectroscopy: probing the entire vibrational spectrum in a single laser shot with femtosecond time resolution Calabrese, Carmella; Stingel, Ashley M.; Shen, Lei Optics Letters, Vol. 37, Issue 12 https://doi.org/10.1364/OL.37.002265	journal	January 2012
Mid-infrared frequency comb generation via cascaded quadratic nonlinearities in quasi-phase-matched waveguides Kowligy, Abijith S.; Lind, Alex; Hickstein, Daniel D. Optics Letters, Vol. 43, Issue 8 https://doi.org/10.1364/OL.43.001678	journal	January 2018
Second-harmonic generation and self-phase modulation of few-cycle mid-infrared pulses Chen, Bo-Han; Hofer, Christina; Pupeza, Ioachim Optics Letters, Vol. 44, Issue 16 https://doi.org/10.1364/OL.44.004079	journal	January 2019
Ultrafast 1 MHz vacuum-ultraviolet source via highly cascaded harmonic generation in negative-curvature hollow-core fibers Couch, David E.; Hickstein, Daniel D.; Winters, David G. Optica, Vol. 7, Issue 7 https://doi.org/10.1364/OPTICA.395688	journal	January 2020
Two-Photon Ionization of Polyatomic Molecules in a Mass Spectrometer Boesl, U.; Neusser, H. J.; Schlag, E. W. Zeitschrift für Naturforschung A, Vol. 33, Issue 12 https://doi.org/10.1515/zna-1978-1218	journal	December 1978

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