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Selective vapor-phase formation of dimethylformamide via oxidative coupling of methanol and dimethylamine over bimetallic catalysts (in EN)

Journal Article · · Catalysis Science and Technology
DOI:https://doi.org/10.1039/d3cy01655b· OSTI ID:2578216

Selective dimethylformamide formation occurs over PdAu; reactivity and selectivity are sensitive to Pd : Au ratio. Reaction kinetics suggest a crowded surface and that beneficial effects of surface hydroxyls are induced by co-feeding water.

Research Organization:
Krell Institute, Ames, IA (United States); Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE; USDOE Office of Science (SC)
Grant/Contract Number:
AC02-05CH11231; SC0023112
OSTI ID:
2578216
Alternate ID(s):
OSTI ID: 2301732
Journal Information:
Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 6 Vol. 14; ISSN CSTAGD; ISSN 2044-4753
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
EN

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