Interface Design for High‐Performance All‐Solid‐State Lithium Batteries

Wan, Hongli; Zhang, Bao; Liu, Sufu; Wang, Zeyi; Xu, Jijian; Wang, Chunsheng

doi:10.1002/aenm.202303046

Interface Design for High‐Performance All‐Solid‐State Lithium Batteries (in EN)

Journal Article · Fri Dec 29 00:00:00 EST 2023 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.202303046· OSTI ID:2575806

^[1]; Zhang, Bao ^[2]; Liu, Sufu ^[1]; Wang, Zeyi ^[1]; Xu, Jijian ^[1]; ^[1]

Univ. of Maryland, College Park, MD (United States)
Nanyang Technological Univ. (Singapore)

All‐solid‐state batteries suffer from high interface resistance and lithium dendrite growth leading to low Li plating/stripping Coulombic efficiency (CE) of <90% and low critical current density at high capacity. Here, in this work, both challenges are simultaneously addressed and the Li plating/stripping CE is significantly increased to 99.6% at 0.2 mA cm⁻²/0.2 mAh cm⁻², and critical current density (CCD) of > 3.0 mA cm⁻²/3.0 mAh cm⁻² by inserting a mixed ionic‐electronic conductive (MIEC) and lithiophobic LiF‐C‐Li₃N‐Bi nanocomposite interlayer between Li₆PS₅Cl electrolyte and Li anode. The highly lithiophobic LiF‐C‐Li₃N‐Bi interlayer with high ionic conductivity (10⁻⁵ S cm⁻¹) and low electronic conductivity (3.4×10⁻⁷ S cm⁻¹) enables Li to plate on the current collector (CC) surface rather than on Li₆PS₅Cl surface avoiding Li₆PS₅Cl electrolyte reduction. During initial Li plating on CC, Li penetrates into porous LiF‐C‐Li₃N‐Bi interlayer and lithiates Bi nanoparticles into Li₃Bi. The lithiophilic Li₃Bi and Li₃N nanoparticles in LiF‐C‐Li₃N‐Li₃Bi sub‐interlayer will move to CC along with plated Li, forming LiF‐C/Li₃N‐Li₃Bi lithiophobic/lithiophilic sublayer during the following Li stripping. This interlayer enables Co_0.1Fe_0.9S₂/Li₆PS₅Cl/Li cell with an areal capacity of 1.4 mAh cm⁻² to achieve a cycle life of >850 cycles at 150 mA g⁻¹. The lithiophobic/lithiophilic interlayer enables solid‐state metal batteries to simultaneously achieve high energy and long cycle life.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, CA (United States); Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE; USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AR0000781; EE0008856

OSTI ID:: 2575806

Alternate ID(s):: OSTI ID: 2267595

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 19 Vol. 14; ISSN 1614-6840; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: EN

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