Review of Carbon Support Coordination Environments for Single Metal Atom Electrocatalysts (SACS)

Song, Wanqing; Xiao, Caixia; Ding, Jia; Huang, Zechuan; Yang, Xinyi; Zhang, Tao; Mitlin, David; Hu, Wenbin

doi:10.1002/adma.202301477

Review of Carbon Support Coordination Environments for Single Metal Atom Electrocatalysts (SACS) (in EN)

Journal Article · Thu Apr 20 00:00:00 EDT 2023 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202301477· OSTI ID:2575754

Song, Wanqing ^[1]; Xiao, Caixia ^[1]; Ding, Jia ^[1]; Huang, Zechuan ^[1]; Yang, Xinyi ^[1]; Zhang, Tao ^[1]; ^[2]; Hu, Wenbin ^[1]

Tianjin Univ. (China)
Univ. of Texas, Austin, TX (United States)

This topical review focuses on the distinct role of carbon support coordination environment of single-atom catalysts (SACs) for electrocatalysis. The article begins with an overview of atomic coordination configurations in SACs, including a discussion of the advanced characterization techniques and simulation used for understanding the active sites. A summary of key electrocatalysis applications is then provided. These processes are oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), nitrogen reduction reaction (NRR), and carbon dioxide reduction reaction (CO₂RR). The review then shifts to modulation of the metal atom-carbon coordination environments, focusing on nitrogen and other non-metal coordination through modulation at the first coordination shell and modulation in the second and higher coordination shells. Representative case studies are provided, starting with the classic four-nitrogen-coordinated single metal atom (M$$-$$N₄) based SACs. Bimetallic coordination models including homo-paired and hetero-paired active sites are also discussed, being categorized as emerging approaches. The theme of the discussions is the correlation between synthesis methods for selective doping, the carbon structure–electron configuration changes associated with the doping, the analytical techniques used to ascertain these changes, and the resultant electrocatalysis performance. In conclusion, critical unanswered questions as well as promising underexplored research directions are identified.

View Accepted Manuscript (DOE)

Research Organization:: Purdue Univ., West Lafayette, IN (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: SC0023260

Other Award/Contract Number:: 52072257
2019YFE0118800

OSTI ID:: 2575754

Alternate ID(s):: OSTI ID: 2279219

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 1 Vol. 36; ISSN 1521-4095; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: EN

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