Improved interfacial li-ion transport in composite polymer electrolytes via surface modification of LLZO

Counihan, Michael J.; Lee, Jungkuk; Mirmira, Priyadarshini; Barai, Pallab; Burns, Meghan E.; Amanchukwu, Chibueze V.; Srinivasan, Venkat; Zhang, Yuepeng; Tepavcevic, Sanja

doi:10.20517/energymater.2024.195

Improved interfacial li-ion transport in composite polymer electrolytes via surface modification of LLZO

Journal Article · Wed Jan 22 00:00:00 EST 2025 · Energy Materials

DOI:https://doi.org/10.20517/energymater.2024.195· OSTI ID:2574955

Counihan, Michael J. ^[1]; Lee, Jungkuk ^[1]; Mirmira, Priyadarshini ^[2]; Barai, Pallab ^[1]; Burns, Meghan E. ^[3]; Amanchukwu, Chibueze V. ^[2]; Srinivasan, Venkat ^[1]; Zhang, Yuepeng ^[1]; ^[1]

Argonne National Laboratory (ANL), Argonne, IL (United States)
Univ. of Chicago, IL (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States); Univ. of Chicago, IL (United States)

Composite polymer electrolytes that incorporate ceramic fillers in a polymer matrix offer mechanical strength and flexibility as solid electrolytes for lithium metal batteries. However, fast Li⁺ transport between polymer and Li⁺-conductive filler phases is not a simple achievement due to high barriers for Li⁺ exchange across the interphase. This study demonstrates how modification of Li₇La₃Zr₂O₁₂ (LLZO) nanofiller surfaces with silane chemistries influences Li⁺ transport at local and global electrolyte scales. Anhydrous reactions covalently link amine-functionalized silanes [(3-aminopropyl)triethoxysilane (APTES)] to LLZO nanoparticles, which protects LLZO in air. APTES functionalization lowers the poly (ethylene oxide) (PEO)-LLZO interphase resistance to half that of unmodified LLZO and increases effective Li⁺ transference number, while insulating Al₂O₃ completely blocks ion exchange and lowers transference number and conductivity in PEO-lithium bis(trifluoromethanesulfonyl)imide (LiTFSI)-LLZO composites. Modeling an inner resistive interphase between LLZO and PEO surrounded by an outer conductive interphase explains non-linear conductivity trends. Solid-state ⁷Li & ⁶Li nuclear magnetic resonance shows Li⁺ only exchanges between PEO-LiTFSI and some LLZO interphase, with no appreciable Li⁺ transport through bulk LLZO. Surface functionalization is a promising path toward lowering the polymer-ceramic interphase resistance. This work demonstrates that local changes in Li⁺ transport affect macroscopic performance, highlighting the intricate relationships between all interfaces in inherently heterogeneous composite polymer electrolytes.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Vehicle Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Materials & Manufacturing Technologies Office (AMMTO); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2574955

Journal Information:: Energy Materials, Journal Name: Energy Materials Journal Issue: 3 Vol. 5; ISSN 2770-5900

Publisher:: OAECopyright Statement

Country of Publication:: United States

Language:: English

References (69)

Ionic Conduction in Polymer‐Based Solid Electrolytes Li, Zhuo; Fu, Jialong; Zhou, Xiaoyan Advanced Science, Vol. 10, Issue 10 https://doi.org/10.1002/advs.202201718	journal	January 2023
Polymer‐Based Solid‐State Electrolytes for High‐Energy‐Density Lithium‐Ion Batteries – Review Lu, Xiao; Wang, Yumei; Xu, Xiaoyu Advanced Energy Materials, Vol. 13, Issue 38 https://doi.org/10.1002/aenm.202301746	journal	August 2023
Evaluating the Use of Critical Current Density Tests of Symmetric Lithium Transference Cells with Solid Electrolytes Fuchs, Till; Haslam, Catherine G.; Richter, Felix H. Advanced Energy Materials, Vol. 13, Issue 45 https://doi.org/10.1002/aenm.202302383	journal	October 2023
Lithium Ion Pathway within Li ₇ La ₃ Zr ₂ O ₁₂ -Polyethylene Oxide Composite Electrolytes Zheng, Jin; Tang, Mingxue; Hu, Yan-Yan Angewandte Chemie International Edition, Vol. 55, Issue 40 https://doi.org/10.1002/anie.201607539	journal	September 2016
Enhanced Surface Interactions Enable Fast Li ⁺ Conduction in Oxide/Polymer Composite Electrolyte Wu, Nan; Chien, Po‐Hsiu; Qian, Yumin Angewandte Chemie International Edition, Vol. 59, Issue 10 https://doi.org/10.1002/anie.201914478	journal	January 2020
Electrochemical Impedance Spectroscopy for All‐Solid‐State Batteries: Theory, Methods and Future Outlook Vadhva, Pooja; Hu, Ji; Johnson, Michael J. ChemElectroChem, Vol. 8, Issue 11 https://doi.org/10.1002/celc.202100108	journal	May 2021
Functionalized Thiophosphate and Oxidic Filler Particles for Hybrid Solid Electrolytes Helmers, Laura; Frankenberg, Finn; Brokmann, Julian ChemElectroChem, Vol. 10, Issue 21 https://doi.org/10.1002/celc.202300310	journal	October 2023
The Transference Number Gao, Kevin W.; Fang, Chao; Halat, David M. ENERGY & ENVIRONMENTAL MATERIALS, Vol. 5, Issue 2 https://doi.org/10.1002/eem2.12359	journal	April 2022
A “Concentrated Ionogel‐in‐Ceramic” Silanization Composite Electrolyte with Superior Bulk Conductivity and Low Interfacial Resistance for Quasi‐Solid‐State Li Metal Batteries Hou, Wangshu; Chen, Zongyuan; Wang, Shengxian ENERGY & ENVIRONMENTAL MATERIALS, Vol. 7, Issue 5 https://doi.org/10.1002/eem2.12736	journal	April 2024
Transport and mechanical behavior in PEO-LLZO composite electrolytes Kim, Hong-Keun; Barai, Pallab; Chavan, Kanchan Journal of Solid State Electrochemistry, Vol. 26, Issue 9 https://doi.org/10.1007/s10008-022-05231-w	journal	July 2022
Electrochemical measurement of transference numbers in polymer electrolytes Evans, James; Vincent, Colin A.; Bruce, Peter G. Polymer, Vol. 28, Issue 13 https://doi.org/10.1016/0032-3861(87)90394-6	journal	December 1987
Designing composite polymer electrolytes for all-solid-state lithium batteries Grundish, Nicholas S.; Goodenough, John B.; Khani, Hadi Current Opinion in Electrochemistry, Vol. 30 https://doi.org/10.1016/j.coelec.2021.100828	journal	December 2021
Nanostructured Garnet-type Li7La3Zr2O12: Synthesis, Properties, and Opportunities as Electrolytes for Li-ion Batteries Chan, Candace K.; Yang, Ting; Mark Weller, J. Electrochimica Acta, Vol. 253 https://doi.org/10.1016/j.electacta.2017.08.130	journal	November 2017
Effects of nanoparticle addition to poly(ε-caprolactone) electrolytes: Crystallinity, conductivity and ambient temperature battery cycling Eriksson, Therese; Mindemark, Jonas; Yue, Ma Electrochimica Acta, Vol. 300 https://doi.org/10.1016/j.electacta.2019.01.117	journal	March 2019
Garnet-rich composite solid electrolytes for dendrite-free, high-rate, solid-state lithium-metal batteries Yan, Chaoyi; Zhu, Pei; Jia, Hao Energy Storage Materials, Vol. 26 https://doi.org/10.1016/j.ensm.2019.11.018	journal	April 2020
A review of composite polymer-ceramic electrolytes for lithium batteries Yu, Xingwen; Manthiram, Arumugam Energy Storage Materials, Vol. 34 https://doi.org/10.1016/j.ensm.2020.10.006	journal	January 2021
The phantom menace of dynamic soft-shorts in solid-state battery research Counihan, Michael J.; Chavan, Kanchan S.; Barai, Pallab Joule, Vol. 8, Issue 1 https://doi.org/10.1016/j.joule.2023.11.007	journal	January 2024
Low temperature sintering of fully inorganic all-solid-state batteries – Impact of interfaces on full cell performance Ihrig, Martin; Finsterbusch, Martin; Tsai, Chih-Long Journal of Power Sources, Vol. 482 https://doi.org/10.1016/j.jpowsour.2020.228905	journal	January 2021
In-situ formed Li2CO3-free garnet/Li interface by rapid acid treatment for dendrite-free solid-state batteries Huo, Hanyu; Chen, Yue; Zhao, Ning Nano Energy, Vol. 61 https://doi.org/10.1016/j.nanoen.2019.04.058	journal	July 2019
Particles in composite polymer electrolyte for solid-state lithium batteries: A review Meng, Nan; Zhu, Xiaogang; Lian, Fang Particuology, Vol. 60 https://doi.org/10.1016/j.partic.2021.04.002	journal	January 2022
Lowering the Interfacial Resistance in Li6.4La3Zr1.4Ta0.6O12\|Poly(Ethylene Oxide) Composite Electrolytes Kuhnert, Eveline; Ladenstein, Lukas; Jodlbauer, Anna Cell Reports Physical Science, Vol. 1, Issue 10 https://doi.org/10.1016/j.xcrp.2020.100214	journal	October 2020
Effect of nano-porous Al2O3 on thermal, dielectric and transport properties of the (PEO)9LiTFSI polymer electrolyte system Jayathilaka, P. A. R. D.; Dissanayake, M. A. K. L.; Albinsson, I. Electrochimica Acta, Vol. 47, Issue 20 https://doi.org/10.1016/s0013-4686(02)00243-8	journal	August 2002
Effect of concentration and grain size of alumina filler on the ionic conductivity enhancement of the (PEO)9LiCF3SO3:Al2O3 composite polymer electrolyte Dissanayake, M. A. K. L.; Jayathilaka, P. A. R. D.; Bokalawala, R. S. P. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/s0378-7753(03)00262-3	journal	June 2003
Influence of Li ⁺ and H ⁺ Distribution on the Crystal Structure of Li _{7– x} H _x La ₃ Zr ₂ O ₁₂ (0 ≤ x ≤ 5) Garnets Orera, Alodia; Larraz, Guillermo; Rodríguez-Velamazán, José Alberto Inorganic Chemistry, Vol. 55, Issue 3 https://doi.org/10.1021/acs.inorgchem.5b02708	journal	January 2016
Proton Bulk Diffusion in Cubic Li ₇ La ₃ Zr ₂ O ₁₂ Garnets as Probed by Single X-ray Diffraction Hiebl, C.; Young, D.; Wagner, R. The Journal of Physical Chemistry C, Vol. 123, Issue 2 https://doi.org/10.1021/acs.jpcc.8b10694	journal	December 2018
Limiting Current in Nanostructured Block Copolymer Electrolytes Maslyn, Jacqueline A.; Frenck, Louise; Veeraraghavan, Vijay D. Macromolecules, Vol. 54, Issue 9 https://doi.org/10.1021/acs.macromol.1c00425	journal	April 2021
Relationship between Conductivity, Ion Diffusion, and Transference Number in Perfluoropolyether Electrolytes Chintapalli, Mahati; Timachova, Ksenia; Olson, Kevin R. Macromolecules, Vol. 49, Issue 9 https://doi.org/10.1021/acs.macromol.6b00412	journal	April 2016
Li₂CO₃: Insights into Its Blocking Effect on Li-Ion Transfer in Garnet Composite Electrolytes Guo, Yixuan; Cheng, Jun; Zeng, Zhen ACS Applied Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1021/acsaem.1c03529	journal	February 2022
Nonconductive Polymers Enable Higher Ionic Conductivities and Suppress Reactivity in Hybrid Sulfide–Polymer Solid State Electrolytes Mirmira, Priyadarshini; Fuschi, Claire; Gillett, Walker ACS Applied Energy Materials, Vol. 5, Issue 7 https://doi.org/10.1021/acsaem.2c01388	journal	July 2022
Garnet Electrolyte Surface Degradation and Recovery Cheng, Lei; Liu, Miao; Mehta, Apurva ACS Applied Energy Materials, Vol. 1, Issue 12 https://doi.org/10.1021/acsaem.8b01723	journal	October 2018
Garnet–Polymer Composite Electrolytes: New Insights on Local Li-Ion Dynamics and Electrodeposition Stability with Li Metal Anodes Zagórski, Jakub; López del Amo, Juan Miguel; Cordill, Megan J. ACS Applied Energy Materials, Vol. 2, Issue 3 https://doi.org/10.1021/acsaem.8b01850	journal	January 2019
Effect of Liquid Electrolyte Soaking on the Interfacial Resistance of Li ₇ La ₃ Zr ₂ O ₁₂ for All-Solid-State Lithium Batteries Besli, Münir M.; Usubelli, Camille; Metzger, Michael ACS Applied Materials & Interfaces, Vol. 12, Issue 18 https://doi.org/10.1021/acsami.0c06194	journal	April 2020
Impact of Protonation on the Electrochemical Performance of Li₇La₃Zr₂O₁₂ Garnets Grissa, Rabeb; Payandeh, Seyedhosein; Heinz, Meike ACS Applied Materials & Interfaces, Vol. 13, Issue 12 https://doi.org/10.1021/acsami.0c23144	journal	March 2021
Unveiling Interfacial Li-Ion Dynamics in Li ₇ La ₃ Zr ₂ O ₁₂ /PEO(LiTFSI) Composite Polymer-Ceramic Solid Electrolytes for All-Solid-State Lithium Batteries Bonilla, Mauricio R.; García Daza, Fabián A.; Ranque, Pierre ACS Applied Materials & Interfaces, Vol. 13, Issue 26 https://doi.org/10.1021/acsami.1c07029	journal	June 2021
Electrochemical Impedance Spectroscopy of PEO-LATP Model Multilayers: Ionic Charge Transport and Transfer Isaac, James Alfred; Mangani, Léa Rose; Devaux, Didier ACS Applied Materials & Interfaces, Vol. 14, Issue 11 https://doi.org/10.1021/acsami.1c19235	journal	March 2022
Interplay of Dynamic Constriction and Interface Morphology between Reversible Metal Anode and Solid Electrolyte in Solid State Batteries Eckhardt, Janis K.; Klar, Peter J.; Janek, Jürgen ACS Applied Materials & Interfaces, Vol. 14, Issue 31 https://doi.org/10.1021/acsami.2c07077	journal	July 2022
3D Impedance Modeling of Metal Anodes in Solid-State Batteries–Incompatibility of Pore Formation and Constriction Effect in Physical-Based 1D Circuit Models Eckhardt, Janis K.; Fuchs, Till; Burkhardt, Simon ACS Applied Materials & Interfaces, Vol. 14, Issue 37 https://doi.org/10.1021/acsami.2c12991	journal	September 2022
Understanding the Influence of Li₇La₃Zr₂O₁₂ Nanofibers on Critical Current Density and Coulombic Efficiency in Composite Polymer Electrolytes Counihan, Michael J.; Powers, Devon J.; Barai, Pallab ACS Applied Materials & Interfaces, Vol. 15, Issue 21 https://doi.org/10.1021/acsami.3c04262	journal	May 2023
Influence of Microstructure on the Material Properties of LLZO Ceramics Derived by Impedance Spectroscopy and Brick Layer Model Analysis Eckhardt, Janis K.; Kremer, Sascha; Fuchs, Till ACS Applied Materials & Interfaces, Vol. 15, Issue 40 https://doi.org/10.1021/acsami.3c10060	journal	September 2023
External Pressure in Polymer-Based Lithium Metal Batteries: An Often-Neglected Criterion When Evaluating Cycling Performance? Roering, Philipp; Overhoff, Gerrit Michael; Liu, Kun Ling ACS Applied Materials & Interfaces, Vol. 16, Issue 17 https://doi.org/10.1021/acsami.4c02095	journal	April 2024
A Simple Method for the Study of Heteroionic Interface Impedances in Solid Electrolyte Multilayer Cells Containing LLZO Kremer, Sascha; Rekers, René; Sigar, Ujjawal ACS Applied Materials & Interfaces, Vol. 16, Issue 33 https://doi.org/10.1021/acsami.4c07845	journal	August 2024
Composite Polymer Electrolytes with Li ₇ La ₃ Zr ₂ O ₁₂ Garnet-Type Nanowires as Ceramic Fillers: Mechanism of Conductivity Enhancement and Role of Doping and Morphology Yang, Ting; Zheng, Jin; Cheng, Qian ACS Applied Materials & Interfaces, Vol. 9, Issue 26 https://doi.org/10.1021/acsami.7b03806	journal	June 2017
New Insights into the Compositional Dependence of Li-Ion Transport in Polymer–Ceramic Composite Electrolytes Zheng, Jin; Hu, Yan-Yan ACS Applied Materials & Interfaces, Vol. 10, Issue 4 https://doi.org/10.1021/acsami.7b17301	journal	January 2018
Ionic Conduction in Composite Polymer Electrolytes: Case of PEO:Ga-LLZO Composites Li, Zhuo; Huang, He-Ming; Zhu, Jia-Kun ACS Applied Materials & Interfaces, Vol. 11, Issue 1 https://doi.org/10.1021/acsami.8b17279	journal	December 2018
Space-Charge Effects at the Li ₇ La ₃ Zr ₂ O ₁₂ /Poly(ethylene oxide) Interface Brogioli, Doriano; Langer, Frederieke; Kun, Robert ACS Applied Materials & Interfaces, Vol. 11, Issue 12 https://doi.org/10.1021/acsami.8b19237	journal	March 2019
Polyoxyethylene (PEO)\|PEO–Perovskite\|PEO Composite Electrolyte for All-Solid-State Lithium Metal Batteries Liu, Ke; Zhang, Ruihan; Sun, Jing ACS Applied Materials & Interfaces, Vol. 11, Issue 50 https://doi.org/10.1021/acsami.9b16936	journal	November 2019
Experimental Platform for Determining the Maximum Limiting Current in a Polymer Electrolyte Lee, Jaeyong; Kim, Se Young; Hoffman, Zach J. ACS Energy Letters, Vol. 9, Issue 4 https://doi.org/10.1021/acsenergylett.4c00480	journal	March 2024
Lithium-Ion Transport and Exchange between Phases in a Concentrated Liquid Electrolyte Containing Lithium-Ion-Conducting Inorganic Particles Yu, Deyang; Tronstad, Zachary C.; McCloskey, Bryan D. ACS Energy Letters, Vol. 9, Issue 4 https://doi.org/10.1021/acsenergylett.4c00502	journal	March 2024
Determining and Minimizing Resistance for Ion Transport at the Polymer/Ceramic Electrolyte Interface Chen, X. Chelsea; Liu, Xiaoming; Samuthira Pandian, Amaresh ACS Energy Letters, Vol. 4, Issue 5 https://doi.org/10.1021/acsenergylett.9b00495	journal	April 2019
Detection of subsurface structures underneath dendrites formed on cycled lithium metal electrodes Harry, Katherine J.; Hallinan, Daniel T.; Parkinson, Dilworth Y. Nature Materials, Vol. 13, Issue 1 https://doi.org/10.1038/nmat3793	journal	November 2013
Reducing crystallinity in solid polymer electrolytes for lithium-metal batteries via statistical copolymerization St-Onge, Vincent; Cui, Mengyang; Rochon, Sylviane Communications Materials, Vol. 2, Issue 1 https://doi.org/10.1038/s43246-021-00187-2	journal	August 2021
Cubic phases of garnet-type Li7La3Zr2O12: the role of hydration Larraz, G.; Orera, A.; Sanjuán, M. L. Journal of Materials Chemistry A, Vol. 1, Issue 37 https://doi.org/10.1039/c3ta11996c	journal	January 2013
Li-ion transport in a representative ceramic–polymer–plasticizer composite electrolyte: Li ₇ La ₃ Zr ₂ O ₁₂ –polyethylene oxide–tetraethylene glycol dimethyl ether Zheng, Jin; Dang, Heather; Feng, Xuyong Journal of Materials Chemistry A, Vol. 5, Issue 35 https://doi.org/10.1039/c7ta05832b	journal	January 2017
Elucidating the mobility of H ⁺ and Li ⁺ ions in (Li _6.25−x H _x Al _0.25 )La ₃ Zr ₂ O ₁₂ via correlative neutron and electron spectroscopy Liu, Xiaoming; Chen, Yan; Hood, Zachary D. Energy & Environmental Science, Vol. 12, Issue 3 https://doi.org/10.1039/c8ee02981d	journal	January 2019
Nanothin film conductivity measurements reveal interfacial influence on ion transport in polymer electrolytes Dong, Ban Xuan; Bennington, Peter; Kambe, Yu Molecular Systems Design & Engineering, Vol. 4, Issue 3 https://doi.org/10.1039/c9me00011a	journal	January 2019
Acid induced conversion towards a robust and lithiophilic interface for Li–Li ₇ La ₃ Zr ₂ O ₁₂ solid-state batteries Ruan, Yadong; Lu, Yang; Huang, Xiao Journal of Materials Chemistry A, Vol. 7, Issue 24 https://doi.org/10.1039/c9ta01911a	journal	January 2019
Visualizing percolation and ion transport in hybrid solid electrolytes for Li–metal batteries Zaman, Wahid; Hortance, Nicholas; Dixit, Marm B. Journal of Materials Chemistry A, Vol. 7, Issue 41 https://doi.org/10.1039/c9ta05118j	journal	January 2019
Controlling the lithium proton exchange of LLZO to enable reproducible processing and performance optimization Rosen, Melanie; Ye, Ruijie; Mann, Markus Journal of Materials Chemistry A, Vol. 9, Issue 8 https://doi.org/10.1039/d0ta11096e	journal	January 2021
Characterization of the interfacial Li-ion exchange process in a ceramic–polymer composite by solid state NMR Ranque, Pierre; Zagórski, Jakub; Devaraj, Shanmukaraj Journal of Materials Chemistry A, Vol. 9, Issue 33 https://doi.org/10.1039/d1ta03720j	journal	January 2021
The quest for the holy grail of solid-state lithium batteries Bonnick, Patrick; Muldoon, John Energy & Environmental Science, Vol. 15, Issue 5 https://doi.org/10.1039/d2ee00842d	journal	January 2022
Lithium ion transport in solid polymer electrolyte filled with alumina nanoparticles Wang, Jiaqi; Fan, Linhao; Du, Qing Energy Advances, Vol. 1, Issue 5 https://doi.org/10.1039/d2ya00025c	journal	January 2022
A room temperature rechargeable Li ₂ O-based lithium-air battery enabled by a solid electrolyte Kondori, Alireza; Esmaeilirad, Mohammadreza; Harzandi, Ahmad Mosen Science, Vol. 379, Issue 6631 https://doi.org/10.1126/science.abq1347	journal	February 2023
Continuum Description of the Role of Negative Transference Numbers on Ion Motion in Polymer Electrolytes Kim, Hong-Keun; Balsara, Nitash P.; Srinivasan, Venkat Journal of The Electrochemical Society, Vol. 167, Issue 11 https://doi.org/10.1149/1945-7111/aba790	journal	July 2020
Bridging the Gap Between Pouch and Coin Cell Electrochemical Performance in Lithium Metal Batteries Soulen, Charles; Lam, Nicholas; Holoubek, John Journal of The Electrochemical Society, Vol. 171, Issue 2 https://doi.org/10.1149/1945-7111/ad2731	journal	February 2024
Comparing Experimental Measurements of Limiting Current in Polymer Electrolytes with Theoretical Predictions Gribble, Daniel A.; Frenck, Louise; Shah, Deep B. Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0391914jes	journal	January 2019
Impedance Characterization of Li Ion Transport at the Interface between Laminated Ceramic and Polymeric Electrolytes Tenhaeff, W. E.; Perry, K. A.; Dudney, N. J. Journal of The Electrochemical Society, Vol. 159, Issue 12 https://doi.org/10.1149/2.063212jes	journal	January 2012
Controlling Ionic Transport through the PEO-LiTFSI/LLZTO Interface Gupta, Arushi; Sakamoto, Jeff The Electrochemical Society Interface, Vol. 28, Issue 2 https://doi.org/10.1149/2.f06192if	journal	January 2019
Review on Polymer-Based Composite Electrolytes for Lithium Batteries Yao, Penghui; Yu, Haobin; Ding, Zhiyu Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00522	journal	August 2019
Role of Filler Content and Morphology in LLZO/PEO Membranes Din, Mir Mehraj Ud; Häusler, M.; Fischer, S. M. Frontiers in Energy Research, Vol. 9 https://doi.org/10.3389/fenrg.2021.711610	journal	October 2021

Similar Records

Nanoscale Ion Transport Enhances Conductivity in Solid Polymer-Ceramic Lithium Electrolytes

Journal Article · Wed Jan 03 19:00:00 EST 2024 · ACS Nano · OSTI ID:2283877

Transport and mechanical behavior in PEO-LLZO composite electrolytes

Journal Article · Sun Jul 24 20:00:00 EDT 2022 · Journal of Solid State Electrochemistry · OSTI ID:1877696

Related Subjects

Composite polymer electrolyte
LLZO
interface
interphase
ion transport
lithium vacancies
silane

Improved interfacial li-ion transport in composite polymer electrolytes via surface modification of LLZO

Citation Formats

References (69)

Similar Records

Related Subjects