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A Rapid Decision Support Tool for Estimating Impacts of a Vadose Zone Volatile Organic Compound Source on Groundwater and Soil Gas

Journal Article · · Ground Water Monitoring and Remediation
DOI:https://doi.org/10.1111/gwmr.12468· OSTI ID:2574253
 [1];  [1];  [1];  [2];  [3];  [3];  [4]
  1. Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
  2. INTERA, Inc., Richland, WA (United States)
  3. US Army Corps of Engineers, Omaha, NE (United States). Environmental and Munitions Center of Expertise
  4. Naval Facilities Engineering and Expeditionary Warfare Center, Port Hueneme, CA (United States)
Diminishing rates of subsurface volatile contaminant removal by soil vapor extraction (SVE) oftentimes warrants an in‐depth performance assessment to guide remedy decision‐making processes. Such a performance assessment must include quantitative approaches to better understand the impact of remaining vadose zone contamination on soil gas and groundwater concentrations. The spreadsheet‐based Soil Vapor Extraction Endstate Tool (SVEET) software functionality has recently been expanded to facilitate quantitative performance assessments. The updated version, referred to as SVEET2, includes expansion of the input parameter ranges for describing a site (site geometry, source characteristics, etc.), an expanded list of contaminants, and incorporation of elements of the Vapor Intrusion Estimation Tool for Unsaturated‐zone Sources software to provide soil gas concentration estimates for use in vapor intrusion evaluation. As part of the update, SVEET2 was used to estimate the impact of a tetrachloroethene (PCE) vadose zone source on groundwater concentrations, comparing SVEET2 results to field‐observed values at an undisclosed site where SVE was recently terminated. PCE concentrations from three separate monitoring wells were estimated by SVEET2 to be within the range of 6.0–6.7 μg/L, as compared to actual field concentrations that ranged from 3 to 11 μg/L PCE. These data demonstrate that SVEET2 can rapidly provide representative quantitative estimates of impacts from a vadose zone contaminant source at field sites. Finally, in the context of the SVE performance assessment, such quantitative estimates provide a basis to support remedial and/or regulatory decisions regarding the continued need for vadose zone volatile organic compound remediation or technical justification for SVE termination, which can significantly reduce the cost to complete for a site.
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC05-76RL01830
OSTI ID:
2574253
Report Number(s):
PNNL-SA--161793
Journal Information:
Ground Water Monitoring and Remediation, Journal Name: Ground Water Monitoring and Remediation Journal Issue: 1 Vol. 42; ISSN 1069-3629; ISSN 1745-6592
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

References (6)

Assessing performance and closure for soil vapor extraction: Integrating vapor discharge and impact to groundwater quality journal February 2012
Estimating the Impact of Vadose Zone Sources on Groundwater to Support Performance Assessment of Soil Vapor Extraction journal March 2014
Estimating Persistent Mass Flux of Volatile Contaminants from the Vadose Zone to Ground Water journal May 2009
Three-Dimensional Simulation of Volatile Organic Compound Mass Flux from the Vadose Zone to Groundwater journal April 2010
Characterization and Remediation of Chlorinated Volatile Organic Contaminants in the Vadose Zone journal February 2013
STOMP Subsurface Transport Over Multiple Phases, Version 4.0, User?s Guide
  • White, Mark D.; Oostrom, Martinus
  • Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL) https://doi.org/10.2172/1012530
report June 2006

Figures / Tables (5)


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