Facile synthesis of co-doped Carbon nanofibers for supercapacitor applications

Ozcan, Mucahid

doi:10.1016/j.molstruc.2025.142894

Facile synthesis of co-doped Carbon nanofibers for supercapacitor applications

Journal Article · Sat Jun 07 00:00:00 EDT 2025 · Journal of Molecular Structure

DOI:https://doi.org/10.1016/j.molstruc.2025.142894· OSTI ID:2572175

^[1]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Here, in this study, the synthesis and electrochemical performance of carbon nanofibers (CNFs) co-doped with aluminum (Al) and nitrogen (N) and decorated with zinc oxide (ZnO) nanoparticles are investigated. After electrospinning polyacrylonitrile (PAN) nanofibers, the nanofiber mats are coated with Al and ZnO precursors by the dip coating method and converted into carbon nanofibers by thermal treatments at 850 °C. Co-doping and nanoparticle decoration affect the efficacy of carbon nanofibers as supercapacitors. With a maximal specific capacitance of 206.28 Fg^-1, it is believed that our produced carbon nanofibers, which can effectively store the renewable energy resources required to meet the rising energy demand, offer superior electrochemical properties compared to traditional supercapacitor materials. The effective incorporation of Al, N, and ZnO into the CNF structure, in conjunction with enhanced electrochemical performance, represents a significant advancement in the development of functional carbon nanofibers.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2572175

Journal Information:: Journal of Molecular Structure, Journal Name: Journal of Molecular Structure Vol. 1343; ISSN 0022-2860

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (22)

Fabrication of carbon papers using polyacrylonitrile fibers as a binder Kim, Hyunuk; Lee, Young-Ju; Lee, Sung-Jin Journal of Materials Science, Vol. 49, Issue 10 https://doi.org/10.1007/s10853-014-8096-4	journal	February 2014
Dechlorinating transformation of propachlor through nucleophilic substitution by dithionite on the surface of alumina Liu, Chengshuai; Shih, Kaimin; Gao, Yuanxue Journal of Soils and Sediments, Vol. 12, Issue 5 https://doi.org/10.1007/s11368-012-0506-0	journal	March 2012
Strong carbon nanofibers from electrospun polyacrylonitrile Arshad, Salman N.; Naraghi, Mohammad; Chasiotis, Ioannis Carbon, Vol. 49, Issue 5 https://doi.org/10.1016/j.carbon.2010.12.056	journal	April 2011
Phosphorus-doped 3D carbon nanofiber aerogels derived from bacterial-cellulose for highly-efficient capacitive deionization Li, Yanjiang; Liu, Yong; Wang, Miao Carbon, Vol. 130 https://doi.org/10.1016/j.carbon.2018.01.035	journal	April 2018
TiO2 nanoparticle decorated carbon nanofibers for removal of organic dyes Wang, Hao; Huang, Xuewu; Li, Wan Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 549 https://doi.org/10.1016/j.colsurfa.2018.04.017	journal	July 2018
A novel high power symmetric ZnO/carbon aerogel composite electrode for electrochemical supercapacitor Kalpana, D.; Omkumar, K. S.; Kumar, S. Suresh Electrochimica Acta, Vol. 52, Issue 3 https://doi.org/10.1016/j.electacta.2006.07.032	journal	November 2006
Supercapacitors as next generation energy storage devices: Properties and applications Olabi, Abdul Ghani; Abbas, Qaisar; Al Makky, Ahmed Energy, Vol. 248 https://doi.org/10.1016/j.energy.2022.123617	journal	June 2022
The role of renewable energy in the global energy transformation Gielen, Dolf; Boshell, Francisco; Saygin, Deger Energy Strategy Reviews, Vol. 24 https://doi.org/10.1016/j.esr.2019.01.006	journal	April 2019
A review of carbon materials for supercapacitors Zhai, Zuozhao; Zhang, Lihui; Du, Tianmin Materials & Design, Vol. 221 https://doi.org/10.1016/j.matdes.2022.111017	journal	September 2022
Electrospun carbon nanofibers and their hybrid composites as advanced materials for energy conversion and storage Peng, Shengjie; Li, Linlin; Kong Yoong Lee, Jeremy Nano Energy, Vol. 22 https://doi.org/10.1016/j.nanoen.2016.02.001	journal	April 2016
A review of heat treatment on polyacrylonitrile fiber Rahaman, M. S. A.; Ismail, A. F.; Mustafa, A. Polymer Degradation and Stability, Vol. 92, Issue 8 https://doi.org/10.1016/j.polymdegradstab.2007.03.023	journal	August 2007
Crosslinking and carbonization processes in PAN films and nanofibers Cipriani, E.; Zanetti, M.; Bracco, P. Polymer Degradation and Stability, Vol. 123 https://doi.org/10.1016/j.polymdegradstab.2015.11.008	journal	January 2016
Carbonization of polyacrylonitrile-based fibers under defined tensile load: Influence on shrinkage behavior, microstructure, and mechanical properties Gutmann, Patrick; Moosburger-Will, Judith; Kurt, Samet Polymer Degradation and Stability, Vol. 163 https://doi.org/10.1016/j.polymdegradstab.2019.03.007	journal	May 2019
Oxygen Vacancy-Induced Structural, Optical, and Enhanced Supercapacitive Performance of Zinc Oxide Anchored Graphitic Carbon Nanofiber Hybrid Electrodes Dillip, Gowra Raghupathy; Banerjee, Arghya Narayan; Anitha, Veettikkunnu Chandran ACS Applied Materials & Interfaces, Vol. 8, Issue 7 https://doi.org/10.1021/acsami.5b12322	journal	February 2016
High Photocatalytic Activity of ZnO−Carbon Nanofiber Heteroarchitectures Mu, Jingbo; Shao, Changlu; Guo, Zengcai ACS Applied Materials & Interfaces, Vol. 3, Issue 2 https://doi.org/10.1021/am101171a	journal	January 2011
Electrochemical Capacitances of Well-Defined Carbon Surfaces Kim, Taegon; Lim, Seongyop; Kwon, Kihyun Langmuir, Vol. 22, Issue 22 https://doi.org/10.1021/la061380q	journal	October 2006
Highly nitrogen doped carbon nanofibers with superior rate capability and cyclability for potassium ion batteries Xu, Yang; Zhang, Chenglin; Zhou, Min Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04190-z	journal	April 2018
ZnO quantum dot-decorated carbon nanofibers derived from electrospun ZIF-8/PVA nanofibers for high-performance energy storage electrodes Lee, Gyeongseop; Seo, Young Deok; Jang, Jyongsik Chem. Commun., Vol. 53, Issue 83 https://doi.org/10.1039/C7CC05206E	journal	January 2017
Boron and nitrogen co-doped porous carbon nanofibers as metal-free electrocatalysts for highly efficient ammonia electrosynthesis Kong, Yan; Li, Yan; Yang, Bin Journal of Materials Chemistry A, Vol. 7, Issue 46 https://doi.org/10.1039/C9TA06076F	journal	January 2019
Electrode Materials for Supercapacitors: A Review of Recent Advances Forouzandeh, Parnia; Kumaravel, Vignesh; Pillai, Suresh C. Catalysts, Vol. 10, Issue 9 https://doi.org/10.3390/catal10090969	journal	August 2020
Fabrication and Properties of Carbon Fibers Huang, Xiaosong Materials, Vol. 2, Issue 4 https://doi.org/10.3390/ma2042369	journal	December 2009
A Global Assessment: Can Renewable Energy Replace Fossil Fuels by 2050? Holechek, Jerry L.; Geli, Hatim M. E.; Sawalhah, Mohammed N. Sustainability, Vol. 14, Issue 8 https://doi.org/10.3390/su14084792	journal	April 2022

Similar Records

A comprehensive study on two types of supercapacitor composite electrodes comprising MnO₂ and activated carbon nanofibers: Self-supporting membrane and ground powder

Journal Article · Fri May 24 00:00:00 EDT 2024 · Journal of Energy Storage · OSTI ID:2428035

Carbon nanofibers based carbon–carbon composite fibers

Journal Article · Wed Dec 20 23:00:00 EST 2023 · Discover Nano · OSTI ID:2267622

Effect of doping on the performance of high-crystalline SrMnO₃ perovskite nanofibers as a supercapacitor electrode

Journal Article · Tue Aug 28 00:00:00 EDT 2018 · Ceramics International · OSTI ID:1572464

Related Subjects

Carbon nanofiber
Dip coating
Electrospinning
Polyacrylonitrile
Supercapacitor

Facile synthesis of co-doped Carbon nanofibers for supercapacitor applications

Citation Formats

References (22)

Similar Records

Related Subjects