A novel polymeric lithicone coating for superior lithium metal anodes

Wang, Xin; Carballo, Kevin Velasquez; Shao, Aiying; Cai, Jiyu; Watanabe, Fumiya; Meng, Xiangbo

doi:10.1016/j.nanoen.2024.109840

A novel polymeric lithicone coating for superior lithium metal anodes

Journal Article · Thu Jun 06 00:00:00 EDT 2024 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2024.109840· OSTI ID:2569848

Wang, Xin ^[1]; Carballo, Kevin Velasquez ^[1]; Shao, Aiying ^[1]; Cai, Jiyu ^[2]; Watanabe, Fumiya ^[3]; Meng, Xiangbo ^[1]

Univ. of Arkansas, Fayetteville, AR (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Univ. of Arkansas, Little Rock, AR (United States)

Lithium metal (Li) is commonly regarded as the “holy grail” of rechargeable batteries and can serve as anodes for constituting various high-energy lithium metal batteries (LMBs). However, it suffers from two notorious issues: (1) continuous formation of inhomogeneous solid electrolyte interphase and (2) Li dendritic growth. Here, in this study, we developed a novel polymeric lithicone via a new molecular layer deposition (MLD) process, using lithium tert-butoxide (LTB) and hydroquinone (HQ) as precursors. We revealed that such an MLD process enabled the resultant LiHQ to grow linearly in a highly controllable and cyclic mode at a growth rate of 4 Å cycle⁻¹ . Furthermore, its low process deposition temperature of 150 °C made it possible to practice high-quality coatings over Li anodes directly. We demonstrated that, very compellingly, this LiHQ coating could protect Li anodes from corrosion and dendritic growth. As a consequence, this LiHQ coating has enabled Li||Li symmetric cells an extremely long cyclability up to 8000 Li-plating/stripping cycles without failure. More excitingly, we demonstrated that, coupled with LiNi_0.8Mn_0.1Co_0.1O₂ (NMC811) cathodes, the LiHQ-modified Li anodes could help the resultant Li||NMC811 realize a much better capacity retention and much longer cyclability. Thus, this study represents a strategic route for developing commercializeable LMBs.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-06CH11357; SC0023439

OSTI ID:: 2569848

Alternate ID(s):: OSTI ID: 2373244

Journal Information:: Nano Energy, Journal Name: Nano Energy Vol. 128; ISSN 2211-2855

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (46)

Solution-Processed Alkaline Lithium Oxide Dielectrics for Applications in n- and p-Type Thin-Film Transistors Liu, Ao; Liu, Guoxia; Zhu, Chundan Advanced Electronic Materials, Vol. 2, Issue 9 https://doi.org/10.1002/aelm.201600140	journal	July 2016
Highly Stable Operation of Lithium Metal Batteries Enabled by the Formation of a Transient High-Concentration Electrolyte Layer Zheng, Jianming; Yan, Pengfei; Mei, Donghai Advanced Energy Materials, Vol. 6, Issue 8 https://doi.org/10.1002/aenm.201502151	journal	February 2016
Lithium Batteries and the Solid Electrolyte Interphase (SEI)—Progress and Outlook Adenusi, Henry; Chass, Gregory A.; Passerini, Stefano Advanced Energy Materials, Vol. 13, Issue 10 https://doi.org/10.1002/aenm.202203307	journal	January 2023
Design and development of low cost polyurethane biopolymer based on castor oil and glycerol for biomedical applications Tan, A. C. W.; Polo-Cambronell, B. J.; Provaggi, E. Biopolymers, Vol. 109, Issue 2 https://doi.org/10.1002/bip.23078	journal	November 2017
Atomic Layer Deposition of Li _x Al _y S Solid-State Electrolytes for Stabilizing Lithium-Metal Anodes Cao, Yanqiang; Meng, Xiangbo; Elam, Jeffrey W. ChemElectroChem, Vol. 3, Issue 6 https://doi.org/10.1002/celc.201600139	journal	April 2016
A revisit to atomic layer deposition of zinc oxide using diethylzinc and water as precursors Cai, Jiyu; Ma, Zhiyuan; Wejinya, Uche Journal of Materials Science, Vol. 54, Issue 7 https://doi.org/10.1007/s10853-018-03260-3	journal	December 2018
Effect of stirring environment humidity on electrochemical performance of nickel-rich cathode materials as lithium ion batteries Wu, Xingyu; Ruan, Dingshan; Tan, Shenghe Ionics, Vol. 26, Issue 11 https://doi.org/10.1007/s11581-020-03708-0	journal	July 2020
Spontaneously formation of SEI layers on lithium metal from LiFSI/DME and LiTFSI/DME electrolytes Zhang, Haitao; Shen, Cai; Huang, Yunbo Applied Surface Science, Vol. 537 https://doi.org/10.1016/j.apsusc.2020.147983	journal	January 2021
Tackling issues of lithium metal anodes with a novel polymeric lithicone coating Wang, Xin; Cai, Jiyu; Velasquez Carballo, Kevin Chemical Engineering Journal, Vol. 475 https://doi.org/10.1016/j.cej.2023.146156	journal	November 2023
High-performance LiNi0.8Mn0.1Co0.1O2 cathode by nanoscale lithium sulfide coating via atomic layer deposition Wang, Xin; Cai, Jiyu; Ren, Yang Journal of Energy Chemistry, Vol. 69 https://doi.org/10.1016/j.jechem.2022.02.015	journal	June 2022
Advancing Lithium Metal Batteries Liu, Bin; Zhang, Ji-Guang; Xu, Wu Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.03.008	journal	May 2018
Protective coatings for lithium metal anodes: Recent progress and future perspectives Zhou, Hongyao; Yu, Sicen; Liu, Haodong Journal of Power Sources, Vol. 450 https://doi.org/10.1016/j.jpowsour.2019.227632	journal	February 2020
Effects of charged interfaces on electrolyte decomposition at the lithium metal anode Camacho-Forero, Luis E.; Balbuena, Perla B. Journal of Power Sources, Vol. 472 https://doi.org/10.1016/j.jpowsour.2020.228449	journal	October 2020
Construction of a dense and N-rich solid electrolyte interface for dendrite-free lithium metal batteries Zhang, Lei; Sun, Bing; Liu, Qinghua Journal of Power Sources, Vol. 580 https://doi.org/10.1016/j.jpowsour.2023.233391	journal	October 2023
Atomic Layer Deposition of Two-Dimensional Layered Materials: Processes, Growth Mechanisms, and Characteristics Cai, Jiyu; Han, Xiaoxiao; Wang, Xin Matter, Vol. 2, Issue 3 https://doi.org/10.1016/j.matt.2019.12.026	journal	March 2020
Advanced electrolyte design for stable lithium metal anode: From liquid to solid Wang, Qian; Wang, Hangchao; Wu, Jianyang Nano Energy, Vol. 80 https://doi.org/10.1016/j.nanoen.2020.105516	journal	February 2021
A gel polymer electrolyte based on Polyacrylonitrile/organic montmorillonite membrane exhibiting dense structure for lithium ion battery He, Chunfeng; Liu, Jiuqing; Cui, Jinqiang Solid State Ionics, Vol. 315 https://doi.org/10.1016/j.ssi.2017.12.014	journal	February 2018
Lithium Metal Anodes with Nonaqueous Electrolytes Zhang, Ji-Guang; Xu, Wu; Xiao, Jie Chemical Reviews, Vol. 120, Issue 24 https://doi.org/10.1021/acs.chemrev.0c00275	journal	November 2020
Li-Containing Organic Thin Film—Structure of Lithium Propane Dioxide via Molecular Layer Deposition Wang, Haotian; Gregorczyk, Keith E.; Lee, Sang Bok The Journal of Physical Chemistry C, Vol. 124, Issue 12 https://doi.org/10.1021/acs.jpcc.9b11868	journal	February 2020
XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction Wood, Kevin N.; Teeter, Glenn ACS Applied Energy Materials, Vol. 1, Issue 9 https://doi.org/10.1021/acsaem.8b00406	journal	August 2018
Interphase Formation of PEO ₂₀ :LiTFSI–Li ₆ PS ₅ Cl Composite Electrolytes with Lithium Metal Simon, Fabian J.; Hanauer, Matthias; Richter, Felix H. ACS Applied Materials & Interfaces, Vol. 12, Issue 10 https://doi.org/10.1021/acsami.9b22968	journal	February 2020
Rapid Interfacial Exchange of Li Ions Dictates High Coulombic Efficiency in Li Metal Anodes May, Richard; Fritzsching, Keith J.; Livitz, Dimitri ACS Energy Letters https://doi.org/10.1021/acsenergylett.1c00112	journal	March 2021
Degradation and Speciation of Li Salts during XPS Analysis for Battery Research Yu, Weilai; Yu, Zhiao; Cui, Yi ACS Energy Letters, Vol. 7, Issue 10 https://doi.org/10.1021/acsenergylett.2c01587	journal	September 2022
Suspended Aminosilanized Graphene Oxide Nanosheets for Selective Preconcentration of Lead Ions and Ultrasensitive Determination by Electrothermal Atomic Absorption Spectrometry Sitko, Rafal; Janik, Paulina; Feist, Barbara ACS Applied Materials & Interfaces, Vol. 6, Issue 22 https://doi.org/10.1021/am505740d	journal	October 2014
Exceptional Electrochemical Performance of Si-Nanowires in 1,3-Dioxolane Solutions: A Surface Chemical Investigation Etacheri, Vinodkumar; Geiger, Uzi; Gofer, Yossi Langmuir, Vol. 28, Issue 14 https://doi.org/10.1021/la300306v	journal	March 2012
Vapor-Phase Atomic-Controllable Growth of Amorphous Li ₂ S for High-Performance Lithium–Sulfur Batteries Meng, Xiangbo; Comstock, David J.; Fister, Timothy T. ACS Nano, Vol. 8, Issue 10 https://doi.org/10.1021/nn505480w	journal	October 2014
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
Pathways for practical high-energy long-cycling lithium metal batteries Liu, Jun; Bao, Zhenan; Cui, Yi Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0338-x	journal	February 2019
Ionic liquids modified graphene oxide composites: a high efficient adsorbent for phthalates from aqueous solution Zhou, Xinguang; Zhang, Yinglu; Huang, Zuteng Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep38417	journal	December 2016
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Novel 3D lightweight carbon foam as an effective adsorbent for arsenic(v) removal from contaminated water Agrawal, Pinki Rani; Kumar, Rajeev; Uppal, Himani RSC Advances, Vol. 6, Issue 36 https://doi.org/10.1039/C6RA02208A	journal	January 2016
An overview of molecular layer deposition for organic and organic–inorganic hybrid materials: mechanisms, growth characteristics, and promising applications Meng, Xiangbo Journal of Materials Chemistry A, Vol. 5, Issue 35 https://doi.org/10.1039/C7TA04449F	journal	January 2017
A fumed alumina induced gel-like electrolyte for great performance improvement of lithium–sulfur batteries Lei, Bin; Yang, Jun; Xu, Zhixin Chemical Communications, Vol. 54, Issue 96 https://doi.org/10.1039/C8CC07741J	journal	January 2018
A bidirectional growth mechanism for a stable lithium anode by a platinum nanolayer sputtered on a polypropylene separator Wen, Kaihua; Liu, Lili; Chen, Shimou RSC Advances, Vol. 8, Issue 23 https://doi.org/10.1039/C8RA02140F	journal	January 2018
Early-stage decomposition of solid polymer electrolytes in Li-metal batteries Andersson, Edvin K. W.; Sångeland, Christofer; Berggren, Elin Journal of Materials Chemistry A, Vol. 9, Issue 39 https://doi.org/10.1039/D1TA05015J	journal	January 2021
3D-hosted lithium metal anodes He, Xin; Zhang, Kai; Zhu, Zhiqiang Chemical Society Reviews, Vol. 53, Issue 1 https://doi.org/10.1039/D3CS00495C	journal	January 2024
Interface engineering of lithium metal anodes via atomic and molecular layer deposition Meng, Xiangbo Inorganic Chemistry Frontiers, Vol. 11, Issue 3 https://doi.org/10.1039/D3QI02241B	journal	January 2024
Controllable synthesis of graphene-based titanium dioxide nanocomposites by atomic layer deposition Meng, Xiangbo; Geng, Dongsheng; Liu, Jian Nanotechnology, Vol. 22, Issue 16 https://doi.org/10.1088/0957-4484/22/16/165602	journal	March 2011
Surface engineering toward stable lithium metal anodes Lu, Gongxun; Nai, Jianwei; Luan, Deyan Science Advances, Vol. 9, Issue 14 https://doi.org/10.1126/sciadv.adf1550	journal	April 2023
A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries Bar-Tow, D. Journal of The Electrochemical Society, Vol. 146, Issue 3 https://doi.org/10.1149/1.1391688	journal	January 1999
The Reactivity of Linear Alkyl Carbonates toward Metallic Lithium Rendek, Louis J.; Chottiner, Gary S.; Scherson, Daniel A. Journal of The Electrochemical Society, Vol. 149, Issue 10 https://doi.org/10.1149/1.1507595	journal	January 2002
Communication—Solvate Ionic Liquid Incorporating Lithium Nitrate as a Redox Mediator for Lithium-Oxygen Batteries Togasaki, Norihiro; Naruse, Takuya; Momma, Toshiyuki Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0731914jes	journal	January 2019
Role of 1,3-Dioxolane and LiNO ₃ Addition on the Long Term Stability of Nanostructured Silicon/Carbon Anodes for Rechargeable Lithium Batteries Jaumann, Tony; Balach, Juan; Klose, Markus Journal of The Electrochemical Society, Vol. 163, Issue 3 https://doi.org/10.1149/2.1011603jes	journal	January 2016
Atomic layer deposition of zirconium oxide thin films Wang, Xin; Ghosh, Sujan Kumar; Afshar-Mohajer, Mahyar Journal of Materials Research, Vol. 35, Issue 7 https://doi.org/10.1557/jmr.2019.338	journal	November 2019
Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes Meng, Xiangbo; Lau, Kah Chun; Zhou, Hua Energy Material Advances, Vol. 2021 https://doi.org/10.34133/2021/9786201	journal	January 2021

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