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Liquid viscosities of carbon dioxide + hydrocarbons from 310 K to 403 K

Journal Article · · Journal of Chemical and Engineering Data
DOI:https://doi.org/10.1021/je950256y· OSTI ID:256887
;  [1];  [2];  [3]
  1. Texas A and M Univ., College Station, TX (United States). Petroleum Engineering Dept.
  2. Suez-Canal Univ. (Egypt)
  3. Instituto Technologico de Celaya (Mexico). Dept. de Ingenieria Quimica

A knowledge of the effect of CO{sub 2} upon the properties of a hydrocarbon mixture is essential to evaluate how viscous fingering, gravity segregation, hydrodynamic dispersion, and interfacial tension phenomena affect the local displacement efficiency in a miscible gas flooding process. Kinematic viscosities of twelve mixtures made from pentane, hexane, heptane, octane, decane, and carbon dioxide were measured using a rolling ball viscometer. The temperatures ranged from 310 K to 403 K and the pressures from 0.8 MPa to 12 MPa. Kinematic viscosities were converted to absolute viscosities using mixture densities estimated from a modified Rackett equation. Calculated absolute viscosities for the decane + CO{sub 2} system were within 0.5% of the values by Cullick and Mathis. All viscosities of hydrocarbon mixtures and hydrocarbons with CO{sub 2} could be predicted from the Orbey and Sandler correlation with an average absolute deviation of 4.1%. The authors found that the Lohrenz, Bray, and Clark viscosity correlation cannot be used to estimate the viscosity of the mixtures containing CO{sub 2} with reasonable accuracy.

OSTI ID:
256887
Journal Information:
Journal of Chemical and Engineering Data, Journal Name: Journal of Chemical and Engineering Data Journal Issue: 3 Vol. 41; ISSN 0021-9568; ISSN JCEAAX
Country of Publication:
United States
Language:
English

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