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Title: Precipitate-hardened aluminum alloys formed using pulsed laser deposition

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.360910· OSTI ID:256758
; ;  [1]
  1. Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)

Very high-strength alloys of Al have been formed by pulsed laser deposition (PLD) from Al and Al{sub 2}O{sub 3} targets. The deposition is alternated between the two targets, with the ratio of pulses per target controlling the O content, and the amount of each element deposited in a cycle kept low enough that the final material is uniform in composition and has a highly refined microstructure. A fine, uniform dispersion of {approximately}1-nm-diam {gamma}-Al{sub 2}O{sub 3} precipitates is formed in fcc Al, with an overall composition of up to 33 at.{percent} oxygen. This microstructure is very similar to one that we previously synthesized by using ion implantation of O into Al, where nanoindentation testing revealed yield stresses of {approximately}1 GPa or more. Nanoindentation testing of these new PLD materials shows yield stresses as high as 5.1 GPa, greatly exceeding the strengths of aerospace Al alloys and even high-strength steels. The key to the properties of these materials is the dispersion of small, hard precipitates spaced only a few Burgers vectors apart; dislocations are apparently unable to cut through and must bow around them. While the nature of ion implantation limits both its cost effectiveness and the thickness of the layers that can be formed, PLD is a completely new approach with major advantages over implantation, including greater control of the composition versus depth, deposition on arbitrary substrates to any thickness, and scalability of the process to larger areas.

Research Organization:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
DOE Contract Number:
AC04-94AL85000
OSTI ID:
256758
Journal Information:
Journal of Applied Physics, Vol. 79, Issue 2; Other Information: PBD: Jan 1996
Country of Publication:
United States
Language:
English