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Highly dense atomic Fe–Ni dual metal sites for efficient CO 2 to CO electrolyzers at industrial current densities

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/D5EE01081K· OSTI ID:2566005
 [1];  [2];  [3];  [1];  [4];  [5];  [6];  [7];  [3];  [7];  [6];  [3];  [8];  [9]
  1. Department of Chemical and Biological Engineering University at Buffalo, The State University of New York, Buffalo, NY 14260, USA
  2. Centre for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA
  3. School of Chemical Sciences, The University of Auckland, Auckland 1010, New Zealand
  4. Centre for Functional Nanomaterials Brookhaven National Laboratory Upton, Upton, NY 11973, USA
  5. Department of Energy, Environmental & Chemical Engineering, Washington University in St. Louis, St. Louis, MO 63130, USA
  6. School of Chemical, Biological, and Environmental Engineering Oregon State University, Corvallis, OR 97331, USA
  7. Pacific Northwest National Laboratory, Richland, WA 99354, USA
  8. Commonwealth Scientific and Industrial Research Organization (CSIRO) Energy Centre, 10 Murray Dwyer Circuit, Mayfield West, NSW 2304, Australia
  9. Department of Energy, Environmental & Chemical Engineering, Washington University in St. Louis, St. Louis, MO 63130, USA, Department of Chemical and Biological Engineering University at Buffalo, The State University of New York, Buffalo, NY 14260, USA

Integrating metal–organic frameworks and gaseous deposition for high-density atomically dispersed Fe–Ni dual metal sites for highly efficient CO 2 to CO conversion.

Sponsoring Organization:
USDOE
OSTI ID:
2566005
Alternate ID(s):
OSTI ID: 2569452
OSTI ID: 2572185
OSTI ID: 2575503
Journal Information:
Energy & Environmental Science, Journal Name: Energy & Environmental Science; ISSN 1754-5692; ISSN EESNBY
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (54)

Heterogeneous Single‐Atom Catalysts for Electrochemical CO 2 Reduction Reaction journal July 2020
Engineering the NiNC Catalyst Microenvironment Enabling CO2 Electroreduction with Nearly 100% CO Selectivity in Acid journal August 2022
Inter‐Metal Interaction with a Threshold Effect in NiCu Dual‐Atom Catalysts for CO2 Electroreduction journal February 2023
Facile Synthesis of Atomic Fe‐N‐C Materials and Dual Roles Investigation of Fe‐N 4 Sites in Fenton‐Like Reactions journal October 2021
Electrochemical Reduction of CO2 to CO over Transition Metal/N‐Doped Carbon Catalysts: The Active Sites and Reaction Mechanism journal October 2021
Isolated Diatomic Ni-Fe Metal-Nitrogen Sites for Synergistic Electroreduction of CO 2 journal April 2019
Size‐Dependent Nickel‐Based Electrocatalysts for Selective CO 2 Reduction journal August 2020
Engineering Atomically Dispersed FeN 4 Active Sites for CO 2 Electroreduction journal November 2020
Advances and Challenges for the Electrochemical Reduction of CO 2 to CO: From Fundamentals to Industrialization journal May 2021
Low‐Valence Znδ+ (0<δ<2) Single‐Atom Material as Highly Efficient Electrocatalyst for CO2 Reduction journal September 2021
Atomically Dispersed Dual‐Metal Site Catalysts for Enhanced CO 2 Reduction: Mechanistic Insight into Active Site Structures journal May 2022
Designing and Engineering Atomically Dispersed Metal Catalysts for CO2 to CO Conversion: From Single to Dual Metal Sites journal January 2024
Binary Atomically Dispersed Metal‐Site Catalysts with Core−Shell Nanostructures for O 2 and CO 2 Reduction Reactions journal August 2021
Atomically dispersed dual‐metal‐site PGM‐free electrocatalysts for oxygen reduction reaction: Opportunities and challenges journal June 2022
In-situ growth of Ni nanoparticle-encapsulated N-doped carbon nanotubes on carbon nanorods for efficient hydrogen evolution electrocatalysis journal March 2020
In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts journal June 2019
Synthetic tuning produces multi-junctions of copper for efficient electroreduction of carbon dioxide journal May 2025
Surface engineering of Cu catalysts for electrochemical reduction of CO2 to value-added multi-carbon products journal July 2022
Boosting CO2 reduction on Fe-N-C with sulfur incorporation: Synergistic electronic and structural engineering journal February 2020
The effect of carbon supports on the electrocatalytic performance of Ni-N-C catalysts for CO2 reduction to CO journal January 2025
Advanced Electrocatalysts with Single-Metal-Atom Active Sites journal November 2020
Kinetics of ZIF-8 Thermal Decomposition in Inert, Oxidizing, and Reducing Environments journal June 2016
Unveiling Active Sites of CO 2 Reduction on Nitrogen-Coordinated and Atomically Dispersed Iron and Cobalt Catalysts journal March 2018
Precisely Constructing Orbital Coupling-Modulated Dual-Atom Fe Pair Sites for Synergistic CO 2 Electroreduction journal January 2022
Close to 90% Single-Pass Conversion Efficiency for CO2 Electroreduction in an Acid-Fed Membrane Electrode Assembly journal October 2022
Introductory Guide to Assembling and Operating Gas Diffusion Electrodes for Electrochemical CO 2 Reduction journal February 2019
Non-Bonding Interaction of Neighboring Fe and Ni Single-Atom Pairs on MOF-Derived N-Doped Carbon for Enhanced CO 2 Electroreduction journal November 2021
Sabatier Phenomenon in Hydrogenation Reactions Induced by Single-Atom Density journal May 2023
N and OH-Immobilized Cu3 Clusters In Situ Reconstructed from Single-Metal Sites for Efficient CO2 Electromethanation in Bicontinuous Mesochannels journal January 2024
Unveiling the Active Structure of Single Nickel Atom Catalysis: Critical Roles of Charge Capacity and Hydrogen Bonding journal March 2020
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode journal November 2004
Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2 journal October 2017
Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts journal March 2019
Asymmetric dinitrogen-coordinated nickel single-atomic sites for efficient CO2 electroreduction journal June 2023
General synthesis of single-atom catalysts with high metal loading using graphene quantum dots journal June 2021
Molecular engineering of dispersed nickel phthalocyanines on carbon nanotubes for selective CO2 reduction journal August 2020
Atomically dispersed iron sites with a nitrogen–carbon coating as highly active and durable oxygen reduction catalysts for fuel cells journal July 2022
Chemical vapour deposition of Fe–N–C oxygen reduction catalysts with full utilization of dense Fe–N4 sites journal June 2021
A single-atom library for guided monometallic and concentration-complex multimetallic designs journal May 2022
Scalable two-step annealing method for preparing ultra-high-density single-atom catalyst libraries journal November 2021
Activity versus stability of atomically dispersed transition-metal electrocatalysts journal July 2024
Recovering carbon losses in CO2 electrolysis using a solid electrolyte reactor journal April 2022
Tuning the thermal activation atmosphere breaks the activity–stability trade-off of Fe–N–C oxygen reduction fuel cell catalysts journal December 2023
Nickel dual-atom sites for electrochemical carbon dioxide reduction journal August 2022
Coordinatively unsaturated nickel–nitrogen sites towards selective and high-rate CO 2 electroreduction journal January 2018
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products journal January 2021
Gas diffusion electrode design for electrochemical carbon dioxide reduction journal January 2020
Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments journal January 2022
Atomically dispersed single Ni site catalysts for high-efficiency CO2 electroreduction at industrial-level current densities journal January 2022
Tailoring acidic microenvironments for carbon-efficient CO2electrolysis over a Ni–N–C catalyst in a membrane electrode assembly electrolyzer journal January 2023
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal June 2006
Precursor-mediated in situ growth of hierarchical N-doped graphene nanofibers confining nickel single atoms for CO 2 electroreduction journal March 2023
What would it take for renewably powered electrosynthesis to displace petrochemical processes? journal April 2019
Atomically dispersed Fe 3+ sites catalyze efficient CO 2 electroreduction to CO journal June 2019

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