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Challenges and Prospects of All-Solid-State Electrodes for Solid-State Lithium Batteries

Journal Article · · Advanced Functional Materials
 [1];  [2];  [2];  [3];  [2];  [4];  [2];  [2]
  1. China University of Mining and Technology, Beijing (China); Tsinghua University, Beijing (China)
  2. Tsinghua University, Beijing (China)
  3. China University of Mining and Technology, Beijing (China)
  4. Argonne National Laboratory (ANL), Argonne, IL (United States)
+ Show Author Affiliations

In the development of all-solid-state lithium batteries (ASSLB), progress is made with solid-state electrolytes; however, challenges regarding compatibility and stability still exist with solid electrodes. These issues result in a low battery capacity and short cycle life, which limit the commercial application of ASSLBs. Here, this review summarizes the recent research progress on solid-state electrodes in ASSLBs including the solid–solid interface phenomena such as the interface between electrode materials and electrolytes. The mechanical stability problems in solid electrodes, including fracture, brittleness, and deformation of electrode materials, are also discussed, and corresponding methods to measure the solid electrode stress are provided. In addition, strategies for mitigating stress-related issues are examined. Finally, the fabrication process of solid electrodes is introduced and their future developments, including the exploration of new electrode materials and the design of more intelligent electrode structures, are proposed.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); Ministry of Science and Technology (MOST); National Natural Science Foundation of China (NSFC); China-Clean Energy Research Center (CERC)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
2564825
Journal Information:
Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 49 Vol. 33; ISSN 1616-301X
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

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Related Subjects

all solid electrodes
all-solid-state lithium battery
electrodes construction
mechanical stability
solid-solid interface