NaSICON-type materials for lithium-ion battery applications: Progress and challenges

Xiao, Jingwen; Zhang, Bao; Liu, Junxiang; He, Xinyou; Xiao, Zhiming; Qin, Haozhe; Liu, Tongchao; Amine, Khalil; Ou, Xing

doi:10.1016/j.nanoen.2024.109730

NaSICON-type materials for lithium-ion battery applications: Progress and challenges

Journal Article · Tue May 14 00:00:00 EDT 2024 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2024.109730· OSTI ID:2563541

Xiao, Jingwen ^[1]; Zhang, Bao ^[1]; Liu, Junxiang ^[2]; He, Xinyou ^[1]; Xiao, Zhiming ^[1]; Qin, Haozhe ^[1]; Liu, Tongchao ^[2]; Amine, Khalil ^[2]; Ou, Xing ^[1]

Central South University, Changsha (China)
Argonne National Laboratory (ANL), Argonne, IL (United States)

Lithium-ion batteries (LIBs) are widely used in electric vehicles, energy storage, smart grids, and portable devices due to their high average output voltage and energy density. NaSICON-type materials have been identified as potential candidates for electrode and solid electrolyte materials for LIBs due to their 3D framework, which contains Li⁺ ions, excellent ionic conductivity, and thermal stability. NaSICON-type materials have a 3D framework and a fast Li⁺ diffusion pathway, making them suitable for use in LIBs. However, their application as solid electrolytes is limited due to poorer ionic conductivity and interfacial stability compared to commercialized liquid electrolytes. Furthermore, their use as electrode materials is restricted by their low electronic conductivity. Here, this review provides an overview of NaSICON-type materials, including their common structure, Li⁺ diffusion mechanism, and preparation strategies. The article also discusses the application and modification strategies of NaSICON-type materials for LIBs, classifying them as anode materials, cathode materials, and solid electrolyte materials. Additionally, the potential use of NaSICON-type materials as modification materials for cathode materials for LIBs is briefly mentioned. Building on previous work on NaSICON-type materials, we propose potential areas for further development and wider applications of these materials in LIBs.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); National Natural Science Foundation of China (NSFC); U.S.-China Clean Energy Research Center (CERC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2563541

Journal Information:: Nano Energy, Journal Name: Nano Energy Vol. 127; ISSN 2211-2855

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Alkali metal ion induced lattice regulation for all climate NASICON-type cathode with superior Na-storage performance Shen, Xing; Han, Miao; Su, Yuefeng Nano Energy, Vol. 114 https://doi.org/10.1016/j.nanoen.2023.108640	journal	September 2023
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Effect of simultaneous addition of aluminum and chromium on the lithium ionic conductivity of LiGe2(PO4)3 NASICON-type glass–ceramics Illbeigi, Mohammad; Fazlali, Alireza; Kazazi, Mahdi Solid State Ionics, Vol. 289 https://doi.org/10.1016/j.ssi.2016.03.012	journal	June 2016
A promising PEO/LAGP hybrid electrolyte prepared by a simple method for all-solid-state lithium batteries Zhao, Yanran; Huang, Zhen; Chen, Shaojie Solid State Ionics, Vol. 295 https://doi.org/10.1016/j.ssi.2016.07.013	journal	November 2016
Improved ionic conductivity in NASICON-type Sr2+ doped LiZr2(PO4)3 Kumar, Sunil; Balaya, Palani Solid State Ionics, Vol. 296 https://doi.org/10.1016/j.ssi.2016.08.012	journal	November 2016
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Sol-gel synthesis and electrochemical properties extracted by phase inflection detection method of NASICON-type solid electrolytes LiZr 2 (PO 4 ) 3 and Li 1.2 Zr 1.9 Ca 0.1 (PO 4 ) 3 Cassel, A.; Fleutot, B.; Courty, M. Solid State Ionics, Vol. 309 https://doi.org/10.1016/j.ssi.2017.07.009	journal	October 2017
Preparation and chemical compatibility of lithium aluminum germanium phosphate solid electrolyte Liu, Yingjia; Chen, Jian; Gao, Jing Solid State Ionics, Vol. 318 https://doi.org/10.1016/j.ssi.2017.10.016	journal	May 2018
Lithium-stable NASICON-type lithium-ion conducting solid electrolyte film coated with a polymer electrolyte Koizumi, Yuta; Mori, Daisuke; Taminato, Sou Solid State Ionics, Vol. 337 https://doi.org/10.1016/j.ssi.2019.04.016	journal	September 2019
Hydrothermal-assisted solid-state reaction synthesis of high ionic conductivity Li1+xAlxTi2−x(PO4)3 ceramic solid electrolytes: The effect of Al3+ doping content He, Shengnan; Xu, Youlong Solid State Ionics, Vol. 343 https://doi.org/10.1016/j.ssi.2019.115078	journal	December 2019
Novel NASICON-type structural Li1.3Al0.3Ti1.7SixP5(3-0.8x)O12 solid electrolytes with improved ionic conductivity for lithium ion batteries Kou, Zhiyan; Miao, Chang; Wang, Zhiyan Solid State Ionics, Vol. 343 https://doi.org/10.1016/j.ssi.2019.115090	journal	December 2019
Cold-pressing PEO/LAGP composite electrolyte for integrated all-solid-state lithium metal battery Cheng, Jun; Hou, Guangmei; Sun, Qing Solid State Ionics, Vol. 345 https://doi.org/10.1016/j.ssi.2019.115156	journal	February 2020
Electromechanical Failure of NASICON-Type Solid-State Electrolyte-Based All-Solid-State Li-Ion Batteries He, Linchun; Oh, Jin An Sam; Watarai, Kenta Chemistry of Materials, Vol. 33, Issue 17 https://doi.org/10.1021/acs.chemmater.1c01564	journal	August 2021
Lithium Ion Conduction in LiTi ₂ (PO ₄ ) ₃ and Related Compounds Based on the NASICON Structure: A First-Principles Study Lang, Britta; Ziebarth, Benedikt; Elsässer, Christian Chemistry of Materials, Vol. 27, Issue 14 https://doi.org/10.1021/acs.chemmater.5b01582	journal	July 2015
NASICON-Structured NaSn₂(PO₄)₃ with Excellent High-Rate Properties as Anode Material for Lithium Ion Batteries Hu, Pu; Ma, Jun; Wang, Tianshi Chemistry of Materials, Vol. 27, Issue 19 https://doi.org/10.1021/acs.chemmater.5b02471	journal	September 2015
Y-Doped NASICON-type LiZr ₂ (PO ₄ ) ₃ Solid Electrolytes for Lithium-Metal Batteries Xu, Henghui; Wang, Shaofei; Wilson, Hope Chemistry of Materials, Vol. 29, Issue 17 https://doi.org/10.1021/acs.chemmater.7b01463	journal	August 2017
Computational and Experimental Investigation of the Electrochemical Stability and Li-Ion Conduction Mechanism of LiZr ₂ (PO ₄ ) ₃ Noda, Yusuke; Nakano, Koki; Takeda, Hayami Chemistry of Materials, Vol. 29, Issue 21 https://doi.org/10.1021/acs.chemmater.7b01703	journal	October 2017
Electrochemical Performance and Mechanisms of NaSn₂(PO₄)₃/C Composites as Anode Materials for Li-Ion Batteries Difi, Siham; Nassiri, Abdelhaq; Saadoune, Ismael The Journal of Physical Chemistry C, Vol. 122, Issue 21 https://doi.org/10.1021/acs.jpcc.7b12770	journal	April 2018
All-Solid-State Li-Ion Battery Using Li _1.5 Al _0.5 Ge _1.5 (PO ₄ ) ₃ As Electrolyte Without Polymer Interfacial Adhesion Meesala, Yedukondalu; Chen, Chen-Yu; Jena, Anirudha The Journal of Physical Chemistry C, Vol. 122, Issue 26 https://doi.org/10.1021/acs.jpcc.8b03971	journal	May 2018
Interface-Controlled Rhombohedral Li ₃ V ₂ (PO ₄ ) ₃ Embedded in Carbon Nanofibers with Ultrafast Kinetics for Li-Ion Batteries Yang, Junghoon; Zhang, Jiliang; Lau, Vincent Wing-hei The Journal of Physical Chemistry Letters, Vol. 11, Issue 10 https://doi.org/10.1021/acs.jpclett.0c01035	journal	April 2020
Hybrid Li Ion Conducting Membrane as Protection for the Li Anode in an Aqueous Li–Air Battery: Coupling Sol–Gel Chemistry and Electrospinning Lancel, Gilles; Stevens, Philippe; Toussaint, Gwenaëlle Langmuir, Vol. 33, Issue 37 https://doi.org/10.1021/acs.langmuir.7b00675	journal	May 2017
Evaluation of Amorphous Oxide Coatings for High-Voltage Li-Ion Battery Applications Using a First-Principles Framework Cheng, Jianli; Sivonxay, Eric; Persson, Kristin A. ACS Applied Materials & Interfaces, Vol. 12, Issue 31 https://doi.org/10.1021/acsami.0c10000	journal	July 2020
Matchmaker of Marriage between a Li Metal Anode and NASICON-Structured Solid-State Electrolyte: Plastic Crystal Electrolyte and Three-Dimensional Host Structure Tong, Zizheng; Wang, Shu-Bo; Jena, Anirudha ACS Applied Materials & Interfaces, Vol. 12, Issue 40 https://doi.org/10.1021/acsami.0c12962	journal	September 2020
Enhancing the Thermal Stability of NASICON Solid Electrolyte Pellets against Metallic Lithium by Defect Modification Chen, Rusong; Yao, Chunxia; Yang, Qi ACS Applied Materials & Interfaces, Vol. 13, Issue 16 https://doi.org/10.1021/acsami.1c01246	journal	April 2021
High Performance Single-Crystal Ni-Rich Cathode Modification via Crystalline LLTO Nanocoating for All-Solid-State Lithium Batteries Fan, Zhaoze; Xiang, Jiayuan; Yu, Qiong ACS Applied Materials & Interfaces, Vol. 14, Issue 1 https://doi.org/10.1021/acsami.1c18264	journal	December 2021
NASICON-Structured LiZr₂(PO₄)₃ Surface Modification Improves Ionic Conductivity and Structural Stability of LiCoO₂ for a Stable 4.6 V Cathode Zhang, Xiaolei; Peng, Bo; Zhao, Liping ACS Applied Materials & Interfaces, Vol. 14, Issue 14 https://doi.org/10.1021/acsami.2c00533	journal	April 2022
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Characterization of Sputter-Deposited LiCoO ₂ Thin Film Grown on NASICON-type Electrolyte for Application in All-Solid-State Rechargeable Lithium Battery Kim, Hee-Soo; Oh, Yoong; Kang, Ki Hoon ACS Applied Materials & Interfaces, Vol. 9, Issue 19 https://doi.org/10.1021/acsami.6b15305	journal	May 2017
Facile Synthesis of Nanosized Lithium-Ion-Conducting Solid Electrolyte Li _1.4 Al _0.4 Ti _1.6 (PO ₄ ) ₃ and Its Mechanical Nanocomposites with LiMn ₂ O ₄ for Enhanced Cyclic Performance in Lithium Ion Batteries Liu, Xingang; Tan, Jiang; Fu, Ju ACS Applied Materials & Interfaces, Vol. 9, Issue 13 https://doi.org/10.1021/acsami.6b16233	journal	March 2017
Nasicon-Type Surface Functional Modification in Core–Shell LiNi _0.5 Mn _0.3 Co _0.2 O ₂ @NaTi ₂ (PO ₄ ) ₃ Cathode Enhances Its High-Voltage Cycling Stability and Rate Capacity toward Li-Ion Batteries Liang, Longwei; Sun, Xuan; Wu, Chen ACS Applied Materials & Interfaces, Vol. 10, Issue 6 https://doi.org/10.1021/acsami.7b15808	journal	January 2018
Enhanced Electrochemical Performance of Fast Ionic Conductor LiTi₂(PO₄)₃-Coated LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Material Zhang, Lu-Lu; Wang, Ji-Qing; Yang, Xue-Lin ACS Applied Materials & Interfaces, Vol. 10, Issue 14 https://doi.org/10.1021/acsami.7b19692	journal	March 2018
Stabilizing the Interface of NASICON Solid Electrolyte against Li Metal with Atomic Layer Deposition Liu, Yulong; Sun, Qian; Zhao, Yang ACS Applied Materials & Interfaces, Vol. 10, Issue 37 https://doi.org/10.1021/acsami.8b06366	journal	August 2018
Enhancing High-Voltage Performance of Ni-Rich Cathode by Surface Modification of Self-Assembled NASICON Fast Ionic Conductor LiZr ₂ (PO ₄ ) ₃ Zhang, Jiafeng; Zhang, Jianyong; Ou, Xing ACS Applied Materials & Interfaces, Vol. 11, Issue 17 https://doi.org/10.1021/acsami.9b00389	journal	April 2019
Insight into the Microstructure and Ionic Conductivity of Cold Sintered NASICON Solid Electrolyte for Solid-State Batteries Liu, Yulong; Liu, Jingru; Sun, Qian ACS Applied Materials & Interfaces, Vol. 11, Issue 31 https://doi.org/10.1021/acsami.9b08132	journal	July 2019
Self-Healing Janus Interfaces for High-Performance LAGP-Based Lithium Metal Batteries Liu, Qi; Zhou, Dong; Shanmukaraj, Devaraj ACS Energy Letters, Vol. 5, Issue 5 https://doi.org/10.1021/acsenergylett.0c00542	journal	April 2020
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Unveiling the Cation Exchange Reaction between the NASICON Li_1.5Al_0.5Ge_1.5(PO₄)₃ Solid Electrolyte and the pyr13TFSI Ionic Liquid Paolella, Andrea; Bertoni, Giovanni; Zhu, Wen Journal of the American Chemical Society, Vol. 144, Issue 8 https://doi.org/10.1021/jacs.1c11466	journal	February 2022
Modeling Ti/Ge Distribution in LiTi _{2– x} Ge _x (PO ₄ ) ₃ NASICON Series by ³¹ P MAS NMR and First-Principles DFT Calculations Diez-Gómez, Virginia; Arbi, Kamel; Sanz, Jesús Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b03583	journal	July 2016
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LiTi₂(PO₄)₃/reduced graphene oxide nanocomposite with enhanced electrochemical performance for lithium-ion batteries Roh, Ha-Kyung; Kim, Hyun-Kyung; Roh, Kwang Chul RSC Adv., Vol. 4, Issue 60 https://doi.org/10.1039/C4RA04943H	journal	January 2014
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β-Cyclodextrin coated lithium vanadium phosphate as novel cathode material for lithium ion batteries Chen, Renjie; Lai, Jingning; Li, Yuejiao RSC Advances, Vol. 6, Issue 105 https://doi.org/10.1039/C6RA22400H	journal	January 2016
Enhancing lithium-ion conductivity in NASICON glass-ceramics by adding yttria Vizgalov, Victor A.; Nestler, Tina; Trusov, Lev A. CrystEngComm, Vol. 20, Issue 10 https://doi.org/10.1039/C7CE01910F	journal	January 2018
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Li ₃ Cr(MoO ₄ ) ₃ : a NASICON-type high specific capacity cathode material for lithium ion batteries Feng, Kai; Wang, Fuxiang; Zhang, Hongzhang Journal of Materials Chemistry A, Vol. 6, Issue 39 https://doi.org/10.1039/C8TA07782G	journal	January 2018
NMR studies of Li mobility in NASICON-type glass-ceramic ionic conductors with optimized microstructure Vyalikh, Anastasia; Schikora, Marc; Seipel, Kaspar P. Journal of Materials Chemistry A, Vol. 7, Issue 23 https://doi.org/10.1039/C8TA11686E	journal	January 2019
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Bayesian-optimization-guided experimental search of NASICON-type solid electrolytes for all-solid-state Li-ion batteries Harada, Maho; Takeda, Hayami; Suzuki, Shinya Journal of Materials Chemistry A, Vol. 8, Issue 30 https://doi.org/10.1039/D0TA04441E	journal	January 2020
Competition between activation energy and migration entropy in lithium ion conduction in superionic NASICON-type Li_1−3xGa_xZr₂(PO₄)₃ Duan, Shanshan; Huang, Can; Liu, Min Journal of Materials Chemistry A, Vol. 9, Issue 12 https://doi.org/10.1039/D0TA11192A	journal	January 2021
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Effect of pressure on the properties of a NASICON Li_1.3Al_0.3Ti_1.7(PO₄)₃ nanofiber solid electrolyte La Monaca, Andrea; Girard, Gabriel; Savoie, Sylvio Journal of Materials Chemistry A, Vol. 9, Issue 23 https://doi.org/10.1039/D1TA01143J	journal	January 2021
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Electrochemical performance of NASICON type carbon coated LiTi2(PO4)3 with a spinel LiMn2O4 cathode Aravindan, V.; Chuiling, W.; Madhavi, S. RSC Advances, Vol. 2, Issue 19 https://doi.org/10.1039/c2ra20826a	journal	January 2012
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Preparation of NASICON-Type Nanosized Solid Electrolyte Li1.4Al0.4Ti1.6(PO4)3 by Evaporation-Induced Self-Assembly for Lithium-Ion Battery Liu, Xingang; Fu, Ju; Zhang, Chuhong Nanoscale Research Letters, Vol. 11, Issue 1 https://doi.org/10.1186/s11671-016-1768-z	journal	December 2016
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electrode materials
lithium-ion battery
modification strategies
solid-state electrolyte materials

NaSICON-type materials for lithium-ion battery applications: Progress and challenges

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