Circularly Polarized Light-Induced Microwave Conductivity Measurement: Rapid Screening Technique of Electronic Conductivity in Chiral Molecular Materials

Koo, Yun Hee; Tsutsui, Yusuke; Omoto, Mikito; Yomogida, Yohei; Yanagi, Kazuhiro; Kato, Yuichiro K.; Hermosilla-Palacios, M. Alejandra; Blackburn, Jeffrey L.; Seki, Shu

doi:10.1021/acs.jpclett.5c00370

Circularly Polarized Light-Induced Microwave Conductivity Measurement: Rapid Screening Technique of Electronic Conductivity in Chiral Molecular Materials

Journal Article · Thu Mar 20 20:00:00 EDT 2025 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.5c00370· OSTI ID:2558952

Koo, Yun Hee ^[1]; ^[2]; Omoto, Mikito ^[3]; Yomogida, Yohei ^[4]; ^[5]; ^[6]; ^[7]; ^[7]; ^[8]

Kyoto University (Japan)
Kyoto University (Japan); JST-PRESTO, Kawaguchi (Japan)
Tokyo Metropolitan University (Japan)
Hokkaido University, Sapporo (Japan)
Tokyo Metropolitan University (Japan); JST-PRESTO, Kawaguchi (Japan)
Inst. of Physical and Chemical Research (RIKEN), Wako (Japan)
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Kyoto University (Japan); JST-CREST, Kawaguchi (Japan)

Here, we developed circularly polarized light-time-resolved microwave conductivity (CPL-TRMC) for investigation of the CPL-dependent photoinduced charge carrier dynamics in chiral materials with chiroptical properties. Chiral R- or S-perylenediimide (PDI) molecular thin films were paired with handedness-sorted (6,5) and (11,-5) single-walled carbon nanotube (SWCNT) films to compose a donor (D)-acceptor (A) system for the spin-dependent charge separation process, and the D-A system was examined through linear and circular polarization-dependent steady-state and time-resolved measurements. The R-PDI-(6,5) film exhibited strong enhancement in circular dichroism (CD) and revealed a reversed transient conductivity signal, relative to the polarity of CD in CPL-TRMC measurement upon excitation of the E₁₁ state, which is interpreted as arising from a spin-dependent initial charge separation process. Through linear polarization-dependent flash photolysis TRMC and circular polarization-resolved femtosecond transient absorption, we could deduce that sub-picosecond intertubular charge separation upon E₁₁ excitation in SWCNT was responsible for the spin-dependent photoconductivity transients observed in CPL-TRMC measurements.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); Core Research for Evolutional Science and Technology; Precursory Research for Embryonic Science and Technology; Japan Society for the Promotion of Science (JSPS) KAKENHI; Japan Science and Technology Agency (JST); Fusion Oriented REsearch for disruptive Science and Technology

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 2558952

Report Number(s):: NREL/JA--5900-93170

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 13 Vol. 16; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Circularly Polarized Light-Induced Microwave Conductivity Measurement: Rapid Screening Technique of Electronic Conductivity in Chiral Molecular Materials

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