Fluorinated polythiophenes with ester side chains for boosting the V_OC and efficiency in non-fullerene polymer solar cells

Journal Article · Mon Mar 31 00:00:00 EDT 2025 · Polymer

DOI:https://doi.org/10.1016/j.polymer.2025.128336· OSTI ID:2556793

Su, Li-Yun ^[1]; Zhou, Yi-Ling ^[2]; Chen, Yu-Ting ^[2]; Chen, Guan-Lin ^[2]; Tseng, Kai-Wei ^[2]; Tukachev, Nikita ^[3]; Zhugayevych, Andriy ^[4]; Tretiak, Sergei ^[5]; Wang, Leeyih ^[2]

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1. Southern Taiwan University Science and Technology, Tainan (Taiwan); National Taiwan University, Taipei (Taiwan)
2. National Taiwan University, Taipei (Taiwan)
3. University of Glasgow, Scotland (United Kingdom)
4. Max Planck Institute for Polymer Research, Mainz (Germany)
5. Los Alamos National Laboratory (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies (CINT)

As the power conversion efficiency (PCE) of organic photovoltaics (OPVs) approximates the 19 % threshold, wide bandgap (WBG) polythiophenes (PTs) have gained increasing attention due to their simple chemical structures and ease of synthesis, making them promising candidates for large-scale production. However, the benchmark polymer poly(3-hexylthiophene) (P3HT) is limited by its high-lying HOMO energy level, which restricts the open-circuit voltage (V_OC) in solar cells. Here, in this study, we introduce a novel series of PT derivatives (PDC8-T, PDC8-3T, PDC16-3T, and PDC16-3T-2F) featuring ester side chains designed to fine-tune electronic properties through a streamlined three-step synthesis. Additionally, we incorporated a π-spacer to reduce steric hindrance and elongated alkyl side chains to improve solubility and processability. Compared to P3HT, these PT derivatives demonstrate a significant reduction in HOMO energy levels, lowering by approximately 0.3–0.4 eV. Among them, PDC16-3T-2F—with fluorine atom substitution—achieves the lowest HOMO energy level, induces a coplanar molecular conformation, and enhances polymer aggregation behavior. We evaluated these PT derivatives in inverted non-fullerene bulk-heterojunction (NFA BHJ) OPVs. The PDC8-3T device showed a relatively low PCE of 0.69 %, with a V_OC of 0.76 V, a short-circuit current density (J_SC) of 3.32 mA/cm², and a fill factor (FF) of 27.3 %. In contrast, the PDC16-3T-2F device achieved an impressive PCE of 7.21 %, with a V_OC of 0.85 V, a J_SC of 14.60 mA/cm², and an FF of 58.4 %. This remarkable improvement is attributed to the fluorine substitution, which not only enhances molecular orientation but also downshifts the HOMO energy level and further boosts the V_OC. Hence, these molecular design strategies have led to a fibrillar bicontinuous interpenetrating network with optimal nanoscale phase separation within the active layer.

• Research Organization: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); USDOE National Nuclear Security Administration (NNSA); National Science and Technology Council (NSTC); Ministry of Science and Technology (MOST); Academia Sinica
• Grant/Contract Number: 89233218CNA000001
• OSTI ID: 2556793
• Report Number(s): LA-UR--24-31039
• Journal Information: Polymer, Journal Name: Polymer Vol. 326; ISSN 0032-3861
• Publisher: Elsevier
• Country of Publication: United States
• Language: English

Related Subjects

14 SOLAR ENERGY
Ester side group-based polythiophene
Fluorination
Material Science
Non-fullerene polymer solar cells