Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

A Sulfide‐Based Solid Electrolyte With High Humid Air Tolerance for Long Lifespan All‐Solid‐State Sodium Batteries

Journal Article · · Advanced Energy Materials
 [1];  [1];  [2];  [1];  [1];  [3];  [1];  [1];  [4]
  1. School of Materials Science and Engineering Tianjin University of Technology Tianjin 300384 China
  2. Neutron Scattering Division Oak Ridge National Laboratory Oak Ridge TN 37830 USA
  3. Guilin Electrical Equipment Scientific Research Institute Co., Ltd Guilin 541004 China
  4. Chemical Sciences Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA, Department of Chemistry University of Tennessee Knoxville TN 37996 USA
+ Show Author Affiliations

Abstract

Sulfide‐based superionic conductors present great promise to achieve high energy density and safety for all‐solid‐state sodium batteries (ASSSBs). However, the poor electrolyte/electrode interface compatibility and humid air stability seriously hinder their deployment in ASSSBs. Herein, a series of high‐performance Na 3‐□ Sb 1‐4x (SnWCaTi) x S 4 sulfide‐based solid electrolytes (SSEs) are reported by coupling the vacancy effect with configurational entropy, which displays an excellent interface stability against sodium metal and an extraordinary tolerance toward the moist atmosphere, even for water. The optimized electrolyte effectively inhibits the detrimental mixed ion‐electron conducting interphase formation, achieving the ultra‐stable operation of Na–Na symmetric cell up to 1000 h. Furthermore, the Na + diffusion kinetics is obviously enhanced by increasing the Na sites local anisotropy and Na vacancies. Eventually, the assembled TiS 2 //Na 5 Sn ASSSBs deliver a remarkable reversible capacity of 211.6 mAh g −1 at 0.5C with a long‐term cycling performance of 450 cycles at room temperature. More importantly, it achieves a steady running up to 100 cycles at 1C even if this electrolyte is placed in the air with a dew temperature of 13.8 °C for 30 min, the highest values in the state‐of‐the‐art sulfide‐based ASSSBs. The well‐designed SSEs open a new avenue for realizing the advanced and powerful ASSSBs.

Sponsoring Organization:
USDOE
OSTI ID:
2555939
Journal Information:
Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 45 Vol. 14; ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

References (60)

Studies of Functional Defects for Fast Na-Ion Conduction in Na 3− y PS 4− x Cl x with a Combined Experimental and Computational Approach journal January 2019
Gradiently Sodiated Alucone as an Interfacial Stabilizing Strategy for Solid‐State Na Metal Batteries journal April 2020
O‐Tailored Microstructure‐Engineered Interface toward Advanced Room Temperature All‐Solid‐State Na Batteries journal May 2022
Solid‐State Electrolytes for Sodium Metal Batteries: Recent Status and Future Opportunities journal May 2023
A Series of Hybrid Multifunctional Interfaces as Artificial SEI Layer for Realizing Dendrite Free, and Long‐Life Sodium Metal Anodes journal June 2023
Configurational and Dynamical Heterogeneity in Superionic Li5.3PS4.3Cl1.7−xBrx journal August 2023
Lithium/Sulfide All‐Solid‐State Batteries using Sulfide Electrolytes journal August 2020
Inorganic Sodium Solid Electrolytes: Structure Design, Interface Engineering and Application journal January 2024
Vacancy-Contained Tetragonal Na 3 SbS 4 Superionic Conductor journal April 2016
TiS 2 as an Advanced Conversion Electrode for Sodium-Ion Batteries with Ultra-High Capacity and Long-Cycle Life journal September 2018
New Na-Ion Solid Electrolytes Na 4− x Sn 1− x Sb x S 4 (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries journal January 2018
Design Principles for Cation‐Mixed Sodium Solid Electrolytes journal January 2021
In Situ Constructed 3D Lithium Anodes for Long‐Cycling All‐Solid‐State Batteries journal May 2023
Heavily Tungsten‐Doped Sodium Thioantimonate Solid‐State Electrolytes with Exceptionally Low Activation Energy for Ionic Diffusion journal November 2021
Na 3 SbS 4 : A Solution Processable Sodium Superionic Conductor for All-Solid-State Sodium-Ion Batteries journal July 2016
Directed Dehydration as Synthetic Tool for Generation of a New Na4SnS4 Polymorph: Crystal Structure, Na+ Conductivity, and Influence of Sb‐Substitution journal July 2022
High‐Entropy Lithium Argyrodite Solid Electrolytes Enabling Stable All‐Solid‐State Batteries journal November 2023
Diffusion in Solids: Fundamentals, Methods, Materials, Diffusion-Controlled Processes book January 2007
Ionic conductivity of Na2S single crystals between 295 and 1350 K experimental setup and first results journal October 1997
A novel air-stable Li7Sb0.05P2.95S10.5I0.5 superionic conductor glass-ceramics electrolyte for all-solid-state lithium-sulfur batteries journal March 2021
Stabilize lithium metal anode through in-situ forming a multi-component composite protective layer journal October 2021
Synthesis of cubic Na3SbS4 solid electrolyte with enhanced ion transport for all-solid-state sodium-ion batteries journal January 2018
Enhanced ion conduction by enforcing structural disorder in Li-deficient argyrodites Li6−xPS5−xCl1+x journal September 2020
Na3.8[Sn0.67Si0.33]0.8Sb0.2S4: A quinary sodium fast ionic conductor for all-solid-state sodium battery journal September 2020
Reactivity-Guided Interface Design in Na Metal Solid-State Batteries journal April 2019
Na2S–NaI solid solution as positive electrode in all-solid-state Na/S batteries journal June 2022
Grain-boundary-resistance-less Na3SbS4-Se solid electrolytes for all-solid-state sodium batteries journal December 2019
First-Principles Calculation Study of Na + Superionic Conduction Mechanism in W- and Mo-Doped Na 3 SbS 4 Solid Electrolytes journal September 2020
Role of Na + Interstitials and Dopants in Enhancing the Na + Conductivity of the Cubic Na 3 PS 4 Superionic Conductor journal December 2015
Abnormally Low Activation Energy in Cubic Na 3 SbS 4 Superionic Conductors journal January 2020
Long-Range and Local Structure of SrxBa1–xNb2O6 (x = 0.33 and 0.67) across the Ferroelectric–Relaxor Transition journal February 2020
Liquid-Phase Synthesis of Nanosized Na11Sn2PS12 Solid Electrolytes for Room Temperature All-Solid-State Sodium Batteries journal January 2021
Artificial Solid Electrolyte Interphases for Lithium Metal Electrodes by Wet Processing: The Role of Metal Salt Concentration and Solvent Choice journal June 2020
New Insights into the Interphase between the Na Metal Anode and Sulfide Solid-State Electrolytes: A Joint Experimental and Computational Study journal March 2018
Stabilizing the Interface between Sodium Metal Anode and Sulfide-Based Solid-State Electrolyte with an Electron-Blocking Interlayer journal February 2019
Vacancy-Driven Na + Superionic Conduction in New Ca-Doped Na 3 PS 4 for All-Solid-State Na-Ion Batteries journal September 2018
Defect-Mediated Conductivity Enhancements in Na 3– x Pn 1– x W x S 4 (Pn = P, Sb) Using Aliovalent Substitutions journal November 2019
Anomalous High Ionic Conductivity of Nanoporous β-Li3PS4 journal January 2013
Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries journal January 2012
A sodium-ion sulfide solid electrolyte with unprecedented conductivity at room temperature journal November 2019
Realizing long-cycling all-solid-state Li-In||TiS2 batteries using Li6+xMxAs1-xS5I (M=Si, Sn) sulfide solid electrolytes journal July 2023
Promoting high-voltage stability through local lattice distortion of halide solid electrolytes journal February 2024
Benchmarking the performance of all-solid-state lithium batteries journal March 2020
Fundamentals of inorganic solid-state electrolytes for batteries journal August 2019
Na3SbSe4−xS x as Sodium Superionic Conductors journal June 2018
Sodium-ion batteries: present and future journal January 2017
Na-ion dynamics in tetragonal and cubic Na 3 PS 4 , a Na-ion conductor for solid state Na-ion batteries journal January 2016
Solution-derived glass-ceramic NaI·Na 3 SbS 4 superionic conductors for all-solid-state Na-ion batteries journal January 2018
Fast Na diffusion and anharmonic phonon dynamics in superionic Na 3 PS 4 journal January 2021
Nominally stoichiometric Na3(WxSixSb1−2x)S4 as a superionic solid electrolyte journal January 2022
Theoretical study on stability and ion transport property with halide doping of Na 3 SbS 4 electrolyte for all-solid-state batteries journal January 2022
Recent progress and strategic perspectives of inorganic solid electrolytes: fundamentals, modifications, and applications in sodium metal batteries journal January 2023
Vacancy-controlled quaternary sulfide Na3−xZn1−xGa1+xS4 with improved ionic conductivity and aqueous stability journal January 2022
Designed anion and cation co-doped Na3Sb(WM)xS4 (M = Cl, Br, I) sulfide electrolytes with an improved conductivity and stable interfacial qualities journal January 2023
High-areal-capacity and long-cycle-life all-solid-state battery enabled by freeze drying technology journal January 2023
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage journal January 2013
The emergent field of high entropy oxides: Design, prospects, challenges, and opportunities for tailoring material properties journal April 2020
TOPAS and TOPAS-Academic : an optimization program integrating computer algebra and crystallographic objects written in C++ journal February 2018
High-entropy mechanism to boost ionic conductivity journal December 2022
A lithium superionic conductor for millimeter-thick battery electrode journal July 2023

Similar Records

Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries
Journal Article · Wed Feb 07 23:00:00 EST 2018 · Angewandte Chemie · OSTI ID:1419899
Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries
Journal Article · Wed Feb 07 23:00:00 EST 2018 · Angewandte Chemie (International Edition) · OSTI ID:1419900
Phase-Transition Interlayer Enables High-Performance Solid-State Sodium Batteries with Sulfide Solid Electrolyte
Journal Article · Fri Apr 30 00:00:00 EDT 2021 · Advanced Functional Materials · OSTI ID:1785686

Related Subjects