The first peroxotitanoniobate cluster – [N(CH3)4]10 [Ti12Nb6O38(O$^{I}_{2}$)6]

The first peroxotitanoniobate cluster – [N(CH₃)₄]₁₀ [Ti₁₂Nb₆O₃₈(O$$^{I}_{2}$$)₆]

Journal Article · Fri Jun 25 00:00:00 UTC 2010 · Inorganica Chimica Acta

DOI:https://doi.org/10.1016/j.ica.2010.06.033· OSTI ID:2544387

Ohlin, C. André ^[1]; Villa, Eric M. ^[1]; Fettinger, James C. ^[1]; Casey, William H. ^[1]

Here, the synthesis and structure of the first discrete peroxotitanoniobate cluster, [N(CH₃)₄]₁₀ [Ti₁₂Nb₆O₃₈(O$$^{I}_{2}$$)₆], is described.

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Journal Information:: Inorganica Chimica Acta, Journal Name: Inorganica Chimica Acta Journal Issue: 15 Vol. 363; ISSN 0020-1693

The [Ti₁₂Nb₆O₄₄]¹⁰⁻ Ion—A New Type of Polyoxometalate Structure Ohlin, C. André; Villa, Eric M.; Fettinger, James C. Angewandte Chemie International Edition, Vol. 47, Issue 30 https://doi.org/10.1002/anie.200801883	journal	July 2008
Distinctly Different Reactivities of Two Similar Polyoxoniobates with Hydrogen Peroxide Ohlin, C. André; Villa, Eric M.; Fettinger, James C. Angewandte Chemie International Edition, Vol. 47, Issue 43 https://doi.org/10.1002/anie.200803688	journal	October 2008
Inorganic Materials as Catalysts for Photochemical Splitting of Water Osterloh, Frank E. Chemistry of Materials, Vol. 20, Issue 1 https://doi.org/10.1021/cm7024203	journal	January 2008
Ion-Exchange Behavior of One-Dimensional Linked Dodecaniobate Keggin Ion Materials Nyman, May; Powers, Craig R.; Bonhomme, Francois Chemistry of Materials, Vol. 20, Issue 7 https://doi.org/10.1021/cm800158u	journal	March 2008

The [Ti₁₂Nb₆O₄₄]^10– Ion—A New Type of Polyoxometalate Structure

Journal Article · Wed Jul 09 04:00:00 UTC 2008 · Angewandte Chemie (International Edition) · OSTI ID:2507320

The [Ti₁₂Nb₆O₄₄]^10– Ion—A New Type of Polyoxometalate Structure

Journal Article · Wed Jul 09 00:00:00 UTC 2008 · Angewandte Chemie (International Edition) · OSTI ID:2543077

Journal Article · Wed Jul 28 04:00:00 UTC 1999 · Journal of the American Chemical Society · OSTI ID:20000039

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Crystal structure
Niobate
Niobium compounds
Polyoxometalates
Synthesis