Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Low temperature sodium battery comprising an electrochemically active molten inorganic catholyte

Patent ·
OSTI ID:2542081
A high-performance electrochemically active sodium molten salt catholyte enables a dramatic reduction in molten sodium battery operating temperature from near 300° C. to less than 120° C. As an example, stable electrochemical cycling was demonstrated in a high voltage (3.65 V) sodium battery comprising a sodium iodide-gallium chloride (NaI—GaCl3) molten salt catholyte for over 8 months at 110° C. The combination of high voltage, stable cycling behavior, and practical current densities supported by a molten catholyte enables a new generation of transformative high performance, low temperature molten sodium batteries.
Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
DOE Contract Number:
NA0003525
Assignee:
National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
Patent Number(s):
11,962,009
Application Number:
17/505,413
OSTI ID:
2542081
Country of Publication:
United States
Language:
English

References (22)

Sodium-Metal Halide and Sodium-Air Batteries journal June 2014
Ambient Temperature Sodium-Sulfur Batteries journal January 2015
Improving the ionic conductivity of NASICON through aliovalent cation substitution of Na3Zr2Si2PO12 journal July 2015
The sodium/nickel chloride (ZEBRA) battery journal November 2001
Low temperature performance of sodium–nickel chloride batteries with NaSICON solid electrolyte journal December 2015
Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives journal May 2010
The effects of temperature on the electrochemical performance of sodium–nickel chloride batteries journal October 2012
P2-type Na 2/3 Mn 1-x Al x O 2 cathode material for sodium-ion batteries: Al-doped enhanced electrochemical properties and studies on the electrode kinetics journal July 2017
Next generation molten NaI batteries for grid scale energy storage journal August 2017
Nanoeffects promote the electrochemical properties of organic Na2C8H4O4 as anode material for sodium-ion batteries journal April 2015
Progress and prospects of sodium-sulfur batteries: A review journal December 2017
Low-Temperature Molten Sodium Batteries journal November 2020
An Ambient Temperature Molten Sodium–Vanadium Battery with Aqueous Flowing Catholyte journal January 2016
Electrochemical Energy Storage for Green Grid journal May 2011
High-performance rechargeable lithium-iodine batteries using triiodide/iodide redox couples in an aqueous cathode journal May 2013
Liquid-metal electrode to enable ultra-low temperature sodium–beta alumina batteries for renewable energy storage journal August 2014
Electrochemical energy storage in a sustainable modern society journal January 2014
Tin-based ionic chaperone phases to improve low temperature molten sodium–NaSICON interfaces journal January 2020
High temperature sodium batteries: status, challenges and future trends journal January 2013
Structural Investigation of Monoclinic‐Rhombohedral Phase Transition in Na 3 Zr 2 Si 2 PO 12 and Doped NASICON journal June 2015
Electrical Energy Storage for the Grid: A Battery of Choices journal November 2011
Electrochemistry of the NaI-AlCl 3 Molten Salt System for Use as Catholyte in Sodium Metal Batteries journal January 2018

Similar Records

Electrochemical Modeling of Iodide Oxidation in Metal-Halide Molten Salts
Journal Article · Thu Dec 09 19:00:00 EST 2021 · Journal of the Electrochemical Society · OSTI ID:1835155

Related Subjects