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Thrifting iridium for hydrogen

Journal Article · · Science
 [1];  [2]
  1. Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); University of California, Berkeley, CA (United States)
  2. Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); University of California, Berkeley, CA (United States); Univ. of Oregon, Eugene, OR (United States)

Using renewable electricity to produce hydrogen fuel reduces reliance on fossil fuels. Proton exchange membrane water electrolyzers (PEMWEs) are the highest-performing commercialized technology. These devices split water into oxygen gas and hydrogen ions (protons) at the anode. The protons then migrate through an ion-conducting polymer membrane (ionomer) to be reduced to hydrogen gas at the cathode. Further, the anode reaction’s harsh environment requires the use of precious-metal catalysts, such as iridium oxide (IrOx). Given the expense and scarcity, the design of electrodes that minimize the use of precious metals without compromising the requisite stability and activity is desired for large-scale hydrogen production. On page 791 of this issue, Shi et al. report that anchoring IrOx catalysts onto porous cerium-oxide (CeOx) supports maintains performance even with much reduced precious metal use.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
2538436
Journal Information:
Science, Journal Name: Science Journal Issue: 6735 Vol. 387; ISSN 0036-8075
Publisher:
AAASCopyright Statement
Country of Publication:
United States
Language:
English

References (13)

Recent Progress in Advanced Electrocatalyst Design for Acidic Oxygen Evolution Reaction journal March 2021
The Stability Challenges of Oxygen Evolving Catalysts: Towards a Common Fundamental Understanding and Mitigation of Catalyst Degradation journal May 2017
The Common Intermediates of Oxygen Evolution and Dissolution Reactions during Water Electrolysis on Iridium journal February 2018
Current Challenges in Catalyst Development for PEM Water Electrolyzers journal January 2020
Microscopic insights on the degradation of a PEM water electrolyzer with ultra-low catalyst loading journal January 2020
Quantification of Iridium Dissolution at Water Electrolysis Relevant Conditions Using a Gas Diffusion Electrode Half-Cell Setup journal July 2024
In Search of Lost Iridium: Quantification of Anode Catalyst Layer Dissolution in Proton Exchange Membrane Water Electrolyzers journal May 2023
Activity–Stability Trends for the Oxygen Evolution Reaction on Monometallic Oxides in Acidic Environments journal July 2014
On the limitations in assessing stability of oxygen evolution catalysts using aqueous model electrochemical cells journal April 2021
The stability number as a metric for electrocatalyst stability benchmarking journal June 2018
Towards a realistic prediction of catalyst durability from liquid half-cell tests journal January 2023
Ultrastable supported oxygen evolution electrocatalyst formed by ripening-induced embedding journal February 2025
Design of PEM water electrolysers with low iridium loading journal January 2024

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