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Title: Minimization of corrosion using activated sodium bromide in a medium-size cooling tower

Journal Article · · Materials Performance
OSTI ID:253724
; ;  [1]; ;  [2]
  1. Albemarle Corp., Baton Rouge, LA (United States)
  2. Puckorius and Associates, Evergreen, CO (United States)

The cooling tower at the Albermarle Process Development Center in Baton Rouge, Louisiana, historically used chlorine as a biocide in combination with phosphorus-based corrosion/scale inhibitors. Although this regimen provided biocontrol, sludge and iron buildup was a problem in low-velocity, small cross-sectional areas of piping. A general cleanup of the system was performed in April 1995. This cleanup was followed with a switch to a two-component corrosion inhibitor/dispersant package. Alternate biocides were evaluated at this time. Activated sodium bromide was found to be particularly effective in this tower, which operates at pH {approximately}8.4. Relative to chlorine, the use of activated sodium bromide led to a decrease in general and pitting corrosion on mild steel. The reduced corrosion appears to be due to a combination of both chemical (less attack on passivated metal surfaces) and biological factors (better control of heterotrophic and sessile bacteria). These conclusions are supported by chemical analyses, corrosion meter and coupon data, dip slides, biological activity reaction tests, and visual observations of the tower sump and heat exchanger surfaces.

OSTI ID:
253724
Journal Information:
Materials Performance, Vol. 35, Issue 7; Other Information: PBD: Jul 1996
Country of Publication:
United States
Language:
English