Molecular Polaritonics: Chemical Dynamics Under Strong Light–Matter Coupling

Li, Tao E.; Cui, Bingyu; Subotnik, Joseph E.; Nitzan, Abraham

doi:10.1146/annurev-physchem-090519-042621

Molecular Polaritonics: Chemical Dynamics Under Strong Light–Matter Coupling

Journal Article · Mon Dec 06 00:00:00 EST 2021 · Annual Review of Physical Chemistry

DOI:https://doi.org/10.1146/annurev-physchem-090519-042621· OSTI ID:2516691

Li, Tao E. ^[1]; Cui, Bingyu ^[2]; Subotnik, Joseph E. ^[1]; Nitzan, Abraham ^[2]

University of Pennsylvania, Philadelphia, PA (United States)
University of Pennsylvania, Philadelphia, PA (United States); Tel Aviv University (Israel)

Chemical manifestations of strong light–matter coupling have recently been a subject of intense experimental and theoretical studies. Here we review the present status of this field. Section 1 is an introduction to molecular polaritonics and to collective response aspects of light–matter interactions. Section 2 provides an overview of the key experimental observations of these effects, while Section 3 describes our current theoretical understanding of the effect of strong light–matter coupling on chemical dynamics. A brief outline of applications to energy conversion processes is given in Section 4. Pending technical issues in the construction of theoretical approaches are briefly described in Section 5. As a result, the summary in Section 6 outlines the paths ahead in this exciting endeavor.

View Accepted Manuscript (DOE)

Research Organization:: University of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: US National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-05CH11231; SC0019397

OSTI ID:: 2516691

Alternate ID(s):: OSTI ID: 1980852

Journal Information:: Annual Review of Physical Chemistry, Journal Name: Annual Review of Physical Chemistry Journal Issue: 1 Vol. 73; ISSN 0066-426X

Publisher:: Annual ReviewsCopyright Statement

Country of Publication:: United States

Language:: English

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Effect of strong coupling on photodegradation of the semiconducting polymer P3HT Peters, Vanessa N.; Faruk, Md Omar; Asane, Joshua Optica, Vol. 6, Issue 3 https://doi.org/10.1364/OPTICA.6.000318	journal	January 2019
Quantum theory of surface-enhanced resonant Raman scattering (SERRS) of molecules in strongly coupled plasmon–exciton systems Neuman, Tomáš; Aizpurua, Javier; Esteban, Ruben Nanophotonics, Vol. 9, Issue 2 https://doi.org/10.1515/nanoph-2019-0336	journal	February 2020
Ground state chemistry under vibrational strong coupling: dependence of thermodynamic parameters on the Rabi splitting energy Thomas, Anoop; Jayachandran, Anjali; Lethuillier-Karl, Lucas Nanophotonics, Vol. 9, Issue 2 https://doi.org/10.1515/nanoph-2019-0340	journal	February 2020
Macroscopic QED for quantum nanophotonics: emitter-centered modes as a minimal basis for multiemitter problems Feist, Johannes; Fernández-Domínguez, Antonio I.; García-Vidal, Francisco J. Nanophotonics, Vol. 10, Issue 1 https://doi.org/10.1515/nanoph-2020-0451	journal	October 2020
Vacuum-Field Catalysis: Accelerated Reactions by Vibrational Ultra Strong Coupling Hiura, Hidefumi; Shalabney, Atef https://doi.org/10.26434/chemrxiv.7234721.v5	preprint	May 2021

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
chemical dynamics
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optical cavities
plasmonic cavities
strong coupling

Molecular Polaritonics: Chemical Dynamics Under Strong Light–Matter Coupling

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