Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

AWSD Reactive Burn Model for High Explosive LX-14

Journal Article · · Propellants, Explosives, Pyrotechnics
DOI:https://doi.org/10.1002/prep.12027· OSTI ID:2514503
The results of an Arrhenius–Wescott–Stewart–Davis (AWSD) reactive flow calibration for the HMX-based high explosive LX-14 are presented. The parameters in the AWSD model are calibrated to experimental thermodynamic and gas gun data and to computational results from thermochemical calculations. There is no experimental rate stick data available for LX-14; therefore, scaled experimental results from other PBX-based high explosives are used in the calibration to fill this gap in data. Strong agreement is observed between the calibrated AWSD model and experimental data for LX-14, including validation data that were not used in the calibration procedure. The developed model more accurately describes experimental shock-to-detonation results compared to several other reactive flow models for LX-14 from the literature. The presented results illustrate that the AWSD model is capable of quantitatively describing the reactive burn of LX-14.
Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE; USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
89233218CNA000001
OSTI ID:
2514503
Alternate ID(s):
OSTI ID: 2514506
OSTI ID: 2520121
Report Number(s):
LA-UR--24-30251
Journal Information:
Propellants, Explosives, Pyrotechnics, Journal Name: Propellants, Explosives, Pyrotechnics Journal Issue: 4 Vol. 50; ISSN 0721-3115
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

References (29)

Complete Equations of State for Cyclotetramethylene Tetranitramine journal March 2021
Calibration and uncertainty quantification for Davis Equation of State models for the High Explosive PBX 9501 products journal January 2024
High-order shock-fitted detonation propagation in high explosives journal March 2017
Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics journal June 2012
On Beyond the Standard Model for high Explosives: Challenges & Obstacles to Surmount
  • Menikoff, Ralph; Elert, Mark; Furnish, Michael D.
  • SHOCK COMPRESSION OF CONDENSED MATTER 2009: Proceedings of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings https://doi.org/10.1063/1.3295100
conference January 2009
Overdriven‐detonation and sound‐speed measurements in PBX‐9501 and the ‘‘thermodynamic’’ Chapman–Jouguet pressure journal December 1996
Non-equilibrium reaction rates in air flows behind shock waves. State-to-state and three-temperature description conference January 2016
Shock temperature dependent rate law for plastic bonded explosives journal April 2018
Measurement and reactive burn modeling of the shock to detonation transition for the HMX based explosive LX-14 conference January 2018
Shock initiation experiments with ignition and growth modeling on the HMX-based explosive LX-14 conference January 2018
Gas gun experiments and numerical simulations on the HMX based explosive PBX 9501 in the overdriven regime conference January 2018
Polysulfone shock compressed above the decomposition threshold: Velocimetry and modeling of two-wave structures journal March 2020
Magpie: A new thermochemical code
  • Ticknor, C.; Andrews, S. A.; Leiding, J. A.
  • SHOCK COMPRESSION OF CONDENSED MATTER - 2019: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings https://doi.org/10.1063/12.0000785
conference January 2020
AWSD calibration for the HMX based explosive PBX 9501
  • Aslam, Tariq D.; Price, Matthew A.; Ticknor, Christopher
  • SHOCK COMPRESSION OF CONDENSED MATTER - 2019: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings https://doi.org/10.1063/12.0000891
conference January 2020
Plate-impact experiments on the HMX-based explosive PBX 9404 conference January 2020
A burn model for trinitrotoluene (TNT) conference January 2023
A CREST reactive burn model for LX-14 conference January 2023
Eyring equation and fluctuation–dissipation far away from equilibrium journal December 2020
A reactive flow model for the 3,3′-diamino-4,4′-azoxyfurazan based plastic bonded explosive (PBX 9701) journal December 2021
Shock initiation of low density polymer bonded explosive LX-14: A study of two morphologies journal April 2022
Electron transfer across a thermal gradient journal July 2016
Activated kinetics in a nonequilibrium thermal bath journal August 2016
Ignition and growth modeling of shock initiation using embedded particle velocity gauges in the plastic bonded explosive LX-14 journal September 2020
Detonation waves in PBX 9501 journal December 2006
Lagrangian Descriptors of Thermalized Transition States on Time-Varying Energy Surfaces journal September 2015
Estimating Physics Models and Quantifying Their Uncertainty Using Optimization With a Bayesian Objective Function journal March 2019
Nonequilibrium Zeldovich-von Neumann-Doring theory and reactive flow modeling of detonation journal February 2007
LASL Explosive Property Data book December 1980
Plane impact response of PBX 9501 and its components below 2 GPa report April 1998

Similar Records

AWSD reactive flow model for PBX 9404
Journal Article · Sun Apr 06 20:00:00 EDT 2025 · Journal of Applied Physics · OSTI ID:2549476