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Uranyl Naphthylsalophen and Pyrasal Complexes: Oxo Ligands Acting as Hydrogen Bond Acceptors in the Solid State

Journal Article · · Inorganic Chemistry
 [1];  [2];  [3];  [3];  [3];  [4];  [3]
  1. Texas Tech Univ., Lubbock, TX (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
  2. Texas Tech Univ., Lubbock, TX (United States); Auburn Univ., AL (United States); Univ. of Alabama, Tuscaloosa, AL (United States)
  3. Texas Tech Univ., Lubbock, TX (United States)
  4. Texas Tech Univ., Lubbock, TX (United States); Univ. of Texas, Austin, TX (United States)
+ Show Author Affiliations
Uranium is most stable when it is exposed to oxygen or water in its +6 oxidation state as the uranyl (UO22+) ion. This ion is subsequently particularly stable and very resistant to functionalization due to the inverse trans effect. Uranyl oxo ligands are typically not considered good hydrogen bond acceptors due to their weak Lewis basicity; however, the ligands bound in the equatorial plane greatly affect the strength of the oxo ligands’ hydrogen bonding. Here, in this work, new naphthylsalophen and pyrasal complexes of uranium were synthesized and crystallized for characterization in the solid state. The bond lengths and angles of the uranyl ion and the ligand conformation are compared. In the solid state, one of the pyrasal complexes showed a hydrogen bond directly from a water molecule to the uranyl oxo ligand, which resulted in an asymmetric lengthening of the U–Oyl bonds from 1.789 to 1.862 Å and 1.784 to 1.844 Å.
Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)
Grant/Contract Number:
89233218CNA000001; SC0019177
OSTI ID:
2500876
Report Number(s):
LA-UR--24-26692
Journal Information:
Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 1 Vol. 64; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (42)

Single-Electron Uranyl Reduction by a Rare-Earth Cation journal December 2010
In Situ Generation of Organic Peroxide to Create a Nanotubular Uranyl Peroxide Phosphate journal November 2019
Isolation and Reactivity of Uranyl Superoxide journal June 2021
New Reactivity of the Uranyl(VI) Ion journal November 2012
[UO 2 Cl 2 (phen) 2 ], a Simple Uranium(VI) Compound with a Significantly Bent Uranyl Unit (phen=1,10-phenanthroline) journal September 2017
Covalency in Actinide Compounds journal January 2021
Unprecedented Catalytic Behavior of Uranyl(VI) Compounds in Chemical Reactions journal November 2020
Electropreparation of Poly(benzophenone-4) Film Modified Electrode and Its Electrocatalytic Behavior Towards Dopamine, Ascorbic Acid and Nitrite journal December 2006
Electrochemical, ESR and quantum chemical study of 1‐substituted naphthalenes and their radical anions journal December 2007
Stereognostic coordination chemistry 4 the design and synthesis of a selective uranyl ion complexant journal December 1995
Electrochemical reduction of Schiff base ligands H2salen and H2salophen journal January 1997
The first example of coexistence of the ketoamino–enolimino forms of diamine Schiff base naphthaldimine parts: the crystal and molecular structure of N,N′-bis(1-naphthaldimine)-o-phenylenediamine chloroform (1/1) solvate at 200 K journal October 2001
Oxo ligand functionalization in the uranyl ion (UO22+) journal February 2010
Structural and spectroscopic characterization of thorium pyrasal complexes journal August 2023
Oxidation of dimethylsulfoxide in the presence of uranyl salts journal October 2023
Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [U VI O 2 ] 2+ journal August 2019
Investigations of the Cobalt Hexamine Uranyl Carbonate System: Understanding the Influence of Charge and Hydrogen Bonding on the Modification of Vibrational Modes in Uranyl Compounds journal September 2022
Synthesis, Characterization, and Density Functional Theory Investigation of the Solid-State [UO2Cl4(H2O)]2– Complex journal August 2023
Cerium(IV) Pyrasal Complexes: A pH-Dependent 8- to 10-Coordinate Cerium Chelate Switch journal October 2023
Structural, Spectroscopic, and Computational Analysis of Halogen- and Hydrogen-Bonding Effects within a Series of Uranyl Fluorides with 4-Halopyridinium journal January 2024
A Spectroscopic and Computational Evaluation of Uranyl Oxo Engagement with Transition Metal Cations journal June 2024
How to Bend the Uranyl Cation via Crystal Engineering journal February 2018
Bonding Interactions in Uranyl α-Diimine Complexes: A Spectroscopic and Electrochemical Study of the Impacts of Ligand Electronics and Extended Conjugation journal November 2019
Reaction of the Uranyl(VI) Ion (UO 2 2+ ) with a Triamidoamine Ligand:  Preparation and Structural Characterization of a Mixed-Valent Uranium(V/VI) Oxo−Imido Dimer journal October 2001
Uranyl Complexation by a Schiff-Base, Polypyrrolic Macrocycle journal December 2004
Role of the Uranyl Oxo Group as a Hydrogen Bond Acceptor journal March 2011
Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning journal June 2012
Ring-Opening Polymerization of Epoxides Catalyzed by Uranyl Complexes: An Experimental and Theoretical Study of the Reaction Mechanism journal August 2012
Uranium–Ligand Multiple Bonding in Uranyl Analogues, [L═U═L] n + , and the Inverse Trans Influence journal December 2012
Mixed-Valence Uranium(V,VI) and Uranyl Oxyhydroxides Synthesized under High-Temperature, High-Pressure Hydrothermal Conditions: Na 5 [U 5 O 16 (OH) 2 ] and Na 5 [U 5 O 17 (OH)] journal August 2013
Sterically Congested Uranyl Complexes with Seven-Coordination of the UO 2 Unit: the Peculiar Ligation Mode of Nitrate in [UO 2 (NO 3 ) 2 (Rbtp)] Complexes † journal August 2008
Exploring the Effects of Reduction or Lewis Acid Coordination on the UO Bond of the Uranyl Moiety journal April 2009
Electrochemical reduction of pyrazine in aqueous media journal October 1972
Reduction and selective oxo group silylation of the uranyl dication journal January 2008
The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes journal February 2017
Multielectron redox chemistry of lanthanide Schiff-base complexes journal January 2012
Understanding the origins of O yl –U–O yl bending in the uranyl (UO 2 2+ ) ion journal January 2018
Solid-state structural elucidation and electrochemical analysis of uranyl naphthylsalophen journal January 2018
A novel symmetric pyrazine (pyz)-bridged uranyl dimer [UO2Cl3(H2O)(Pyz)0.5]22−: synthesis, structure and computational analysis journal January 2022
Uranyl N2O2-Schiff base complex as co-catalyst in ethanol electro-oxidation: synthesis, crystallographic, spectroscopic, electrochemical, and DFT characterization, and catalytic investigation journal January 2023
Electrochemical Studies on [UO 2 (DMF) 5 ](CIO 4 ) 2 , UO 2 (acac) 2 DMF, and UO 2 (salen)DMF (DMF= N , N -dimethylformamide, acac=acetylacetonate, salen= N , N′-disalicylideneethylenediaminate) Complexes in DMF journal February 2002
The Supramolecular Attitude of Metal–Salophen and Metal–Salen Complexes journal April 2018

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
cations
ligands
noncovalent interactions
redox reactions
solvents