Pressure induced Invar effect in Fe55⁢Ni45: An experimental study with nuclear resonant scattering

Guzman, P.; Lohaus, S. H.; Bernal-Choban, C. M.; Fultz, B.; Zhao, J. Y.; Shen, G.; Hu, M. Y.; Alp, E. E.; Lavina, B.

doi:10.1103/physrevb.110.144419

Pressure induced Invar effect in Fe₅₅⁢Ni₄₅: An experimental study with nuclear resonant scattering

Journal Article · Fri Oct 11 04:00:00 EDT 2024 · Physical Review. B

DOI:https://doi.org/10.1103/physrevb.110.144419· OSTI ID:2499472

^[1]; ^[1]; ^[1]; ^[1]; Zhao, J. Y. ^[2]; Shen, G. ^[2]; ^[2]; Alp, E. E. ^[2]; ^[3]

California Institute of Technology (CalTech), Pasadena, CA (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Univ. of Chicago, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Pressure-dependent synchrotron x-ray diffraction (XRD), nuclear resonant inelastic x-ray scattering (NRIXS), and nuclear forward scattering (NFS) measurements were made on ⁵⁷Fe₅₅Ni₄₅. XRD measurements were at 298 and 392 K at pressures up to 20 GPa, confirming a pressure-induced Invar effect between 7 and 13 GPa. A decrease of the ⁵⁷Fe magnetic moment was found in NFS measurements under pressure, showing an increase in magnetic entropy. The ⁵⁷Fe phonon density of states (DOS) was obtained from NRIXS measurements. The low thermal expansion in the high-pressure Invar region originates from a competition between the thermal expansion from spins and phonons as calculated from Maxwell relations. Finally, the longitudinal phonon modes changed their pressure dependence near the Curie transition, which is evidence for a spin-phonon interaction.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2499472

Alternate ID(s):: OSTI ID: 2474055

Journal Information:: Physical Review. B, Journal Name: Physical Review. B Journal Issue: 14 Vol. 110; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Pressure induced Invar effect in Fe55⁢Ni45: An experimental study with nuclear resonant scattering

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Pressure induced Invar effect in Fe₅₅⁢Ni₄₅: An experimental study with nuclear resonant scattering