Hydroformylation in the presence of a rhodium catalyst promoted by sodium alcoholate
Journal Article
·
· Petroleum Chemistry
OSTI ID:249891
- and others
The effect of additive NaOR (R = CH{sub 3}, C{sub 2}H{sub 5}, C{sub 4}H{sub 9}) on the rate and selectivity of hydroformylation of allyl alcohol and propene in the presence of unmodified and modified triphenylphosphine rhodium catalysts has been shown. The dependence of the indices of hydroformylation on the ratios Na/Rh and PPh{sub 3}/Rh and the nature of R and also the results of an IR spectral study of the catalytic complex indicate that the active Rh catalyst contains an OR group. 14 refs., 5 figs.
- OSTI ID:
- 249891
- Journal Information:
- Petroleum Chemistry, Journal Name: Petroleum Chemistry Journal Issue: 5 Vol. 32; ISSN PHEME4
- Country of Publication:
- United States
- Language:
- English
Similar Records
Hydroformylation of allyl alcohol in the presence of modified rhodium catalysts
Gas phase hydroformylation of propylene and allyl alcohol with immobilized rhodium complexes
Study of hydroformylation of formaldehyde in the presence of rhodium catalysts by in situ IR spectroscopy and the kinetic technique
Journal Article
·
Thu Dec 30 23:00:00 EST 1993
· Petroleum Chemistry
·
OSTI ID:249902
Gas phase hydroformylation of propylene and allyl alcohol with immobilized rhodium complexes
Technical Report
·
Mon Dec 31 23:00:00 EST 1979
·
OSTI ID:5783521
Study of hydroformylation of formaldehyde in the presence of rhodium catalysts by in situ IR spectroscopy and the kinetic technique
Journal Article
·
Thu Jun 01 00:00:00 EDT 1995
· Russian Chemical Bulletin
·
OSTI ID:161904