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Insight of Synthesis of Single Crystal Ni-Rich LiNi1-x-yCoxMnyO2 Cathodes

Journal Article · · Advanced Energy Materials
 [1];  [2];  [3];  [1];  [4];  [4];  [5];  [1];  [4]
  1. Hainan University, Haikou (China)
  2. Tsinghua Univ., Beijing (China); China University of Mining and Technology, Beijing (China)
  3. China University of Mining and Technology, Beijing (China)
  4. Tsinghua Univ., Beijing (China)
  5. Argonne National Laboratory (ANL), Argonne, IL (United States)
+ Show Author Affiliations
Single-crystal Ni-rich LiNi1-x-yCoxMnyO2 (NCM) cathodes have garnered widespread attention in the lithium-ion battery community due to their unique advantages in mechanical performance and their ability to minimize interfacial electrochemical side reactions. The synthesis of single-crystal materials with monodisperse and appropriate size, minimal lattice defects, and highly ordered structures is the key for high-performance batteries. However, achieving this goal poses challenges due to the lack of in-depth understanding regarding specific experimental parameters and the solid reaction mechanism during the synthesis process. Further, in this review, the aim is to provide an in-depth analysis of the critical process parameters involved in the synthesis and their impact on crystal morphology, structure, and electrochemical performance. Consequently, the first section focuses on the effect of the precursor morphology, lithium salt, atmosphere, and sintering procedure. In the second section, the study delves into an in-depth discussion of the solid reaction and crystal growth mechanism. Lastly, it is concluded by highlighting the prospects and challenges associated with the synthesis and application of single-crystal Ni-rich NCM cathodes.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
National Natural Science Foundation of China; USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
2498365
Journal Information:
Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 11 Vol. 14; ISSN 1614-6832
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

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Construction of Planar Gliding Restriction Buffer and Kinetic Self-Accelerator Stabilizing Single-Crystalline LiNi0.9Co0.05Mn0.05O2 Cathode journal February 2023
In Situ Multitechnical Investigation into Capacity Fading of High-Voltage LiNi 0.5 Co 0.2 Mn 0.3 O 2 journal December 2016
Nasicon-Type Surface Functional Modification in Core–Shell LiNi 0.5 Mn 0.3 Co 0.2 O 2 @NaTi 2 (PO 4 ) 3 Cathode Enhances Its High-Voltage Cycling Stability and Rate Capacity toward Li-Ion Batteries journal January 2018
Ab Initio Study on Surface Segregation and Anisotropy of Ni-Rich LiNi 1–2 y Co y Mn y O 2 (NCM) ( y ≤ 0.1) Cathodes journal February 2018
Compound-Hierarchical-Sphere LiNi0.5Co0.2Mn0.3O2: Synthesis, Structure, and Electrochemical Characterization journal August 2018
Constructing a Protective Pillaring Layer by Incorporating Gradient Mn4+ to Stabilize the Surface/Interfacial Structure of LiNi0.815Co0.15Al0.035O2 Cathode journal July 2018
New Chemical Insights into the Beneficial Role of Al 2 O 3 Cathode Coatings in Lithium-ion Cells journal March 2019
An Empirical Model for the Design of Batteries with High Energy Density journal February 2020
Capacity Fading Mechanisms in Ni-Rich Single-Crystal NCM Cathodes journal July 2021
Structural Stability of Single-Crystalline Ni-Rich Layered Cathode upon Delithiation journal August 2022
Morphology-Dependent Battery Performance of Ni-Rich Layered Cathodes: Single-Crystal versus Refined Polycrystal journal August 2022
Long-Lasting Ni-Rich NCMA Cathodes via Simultaneous Microstructural Refinement and Surface Modification journal February 2023
High-Capacity Oxide Cathode beyond 300 mAh/g journal June 2023
New Organic Complex for Lithium Layered Oxide Modification: Ultrathin Coating, High-Voltage, and Safety Performances journal February 2019
Conformal PEDOT Coating Enables Ultra-High-Voltage and High-Temperature Operation for Single-Crystal Ni-Rich Cathodes journal September 2022
The Role of Intragranular Nanopores in Capacity Fade of Nickel-Rich Layered Li(Ni 1– x – y Co x Mn y )O 2 Cathode Materials journal August 2019
Performance and Stability Improvement of Layered NCM Lithium-Ion Batteries at High Voltage by a Microporous Al 2 O 3 Sol–Gel Coating journal August 2019
Comparative Studies of Polycrystal and Single-Crystal LiNi0.6Co0.2Mn0.2O2 in Terms of Physical and Electrochemical Performance journal August 2021
Single-Crystal Ni-Rich Layered LiNi0.9Mn0.1O2 Enables Superior Performance of Co-Free Cathodes for Lithium-Ion Batteries journal April 2022
Structural Changes and Thermal Stability of Charged LiNi x Mn y Co z O 2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy journal December 2014
Kinetic Origin of Planar Gliding in Single-Crystalline Ni-Rich Cathodes journal June 2022
Residual Lithium Carbonate Predominantly Accounts for First Cycle CO 2 and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides journal November 2017
Collapse of LiNi 1– x – y Co x Mn y O 2 Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries journal March 2019
A New Type of Protective Surface Layer for High-Capacity Ni-Based Cathode Materials: Nanoscaled Surface Pillaring Layer journal February 2013
Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries journal January 2017
Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries journal January 2016
A reflection on lithium-ion battery cathode chemistry journal March 2020
Surface regulation enables high stability of single-crystal lithium-ion cathodes at high voltage journal June 2020
Thermal runaway of Lithium-ion batteries employing LiN(SO2F)2-based concentrated electrolytes journal October 2020
Hierarchical nickel valence gradient stabilizes high-nickel content layered cathode materials journal April 2021
Surface enrichment and diffusion enabling gradient-doping and coating of Ni-rich cathode toward Li-ion batteries journal July 2021
Enabling high energy lithium metal batteries via single-crystal Ni-rich cathode material co-doping strategy journal April 2022
In situ multiscale probing of the synthesis of a Ni-rich layered oxide cathode reveals reaction heterogeneity driven by competing kinetic pathways journal April 2022
High-nickel layered oxide cathodes for lithium-based automotive batteries journal January 2020
Strain-retardant coherent perovskite phase stabilized Ni-rich cathode journal November 2022
Fast charging of energy-dense lithium-ion batteries journal October 2022
Na-doped Ni-rich LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode material with both high rate capability and high tap density for lithium ion batteries journal January 2014
Infiltrative coating of LiNi 0.5 Co 0.2 Mn 0.3 O 2 microspheres with layer-structured LiTiO 2 : towards superior cycling performances for Li-ion batteries journal January 2014
A hydrolysis-hydrothermal route for the synthesis of ultrathin LiAlO 2 -inlaid LiNi 0.5 Co 0.2 Mn 0.3 O 2 as a high-performance cathode material for lithium ion batteries journal January 2015
Improving the electrochemical properties of LiNi 0.5 Co 0.2 Mn 0.3 O 2 at 4.6 V cutoff potential by surface coating with Li 2 TiO 3 for lithium-ion batteries journal January 2015
Enhanced high-rate capability and high voltage cycleability of Li2TiO3-coated LiNi0.5Co0.2Mn0.3O2 cathode materials journal January 2016
Molybdate flux growth of idiomorphic Li(Ni 1/3 Co 1/3 Mn 1/3 )O 2 single crystals and characterization of their capabilities as cathode materials for lithium-ion batteries journal January 2016
Synthesis and characterization of Al-substituted LiNi0.5Co0.2Mn0.3O2 cathode materials by a modified co-precipitation method journal January 2017
Improved conductivity and electrochemical properties of LiNi0.5Co0.2Mn0.3O2 materials via yttrium doping journal January 2018
Single-crystal based studies for correlating the properties and high-voltage performance of Li[Ni x Mn y Co 1−x−y ]O 2 cathodes journal January 2019
Overall structural modification of a layered Ni-rich cathode for enhanced cycling stability and rate capability at high voltage journal January 2019
Suppressing detrimental phase transitions via tungsten doping of LiNiO 2 cathode for next-generation lithium-ion batteries journal January 2019
Cation ordered Ni-rich layered cathode for ultra-long battery life journal January 2021
Restraining the polarization increase of Ni-rich and low-Co cathodes upon cycling by Al-doping journal January 2020
Preparation and electrochemical investigation of single-crystal LiNi0.6Co0.2Mn0.2O2 for high-performance lithium-ion batteries journal January 2022
Titanium and fluorine synergetic modification improves the electrochemical performance of Li(Ni0.8Co0.1Mn0.1)O2 journal January 2021
Which of the nickel-rich NCM and NCA is structurally superior as a cathode material for lithium-ion batteries? journal January 2021
Revisiting the role of Zr doping in Ni-rich layered cathodes for lithium-ion batteries journal January 2021
Ni crossover catalysis: truth of hydrogen evolution in Ni-rich cathode-based lithium-ion batteries journal January 2023
Nano-TiO2 coated single-crystal LiNi0.65Co0.15Mn0.2O2 for lithium-ion batteries with a stable structure and excellent cycling performance at a high cut-off voltage journal January 2022
Improving LiNiO2 cathode performance through particle design and optimization journal January 2022
General flux-free synthesis of single crystal Ni-rich layered cathodes by employing a Li-containing spinel transition phase for lithium-ion batteries journal January 2022
Cathode regeneration and upcycling of spent LIBs: toward sustainability journal January 2023
Coarsening in Sintering: Grain Shape Distribution, Grain Size Distribution, and Grain Growth Kinetics in Solid-Pore Systems journal November 2010
Advanced single-crystal layered Ni-rich cathode materials for next-generation high-energy-density and long-life Li-ion batteries journal July 2022
Microstructural Evolution During Sintering with Control of the Interface Structure journal July 2009
Solid-State Conversion of Single Crystals: The Principle and the State-of-the-Art journal January 2015
Strategies and practices for suppressing abnormal grain growth during liquid phase sintering journal September 2018
Electrical Energy Storage and Intercalation Chemistry journal June 1976
Reversible planar gliding and microcracking in a single-crystalline Ni-rich cathode journal December 2020
Microstructural Observations of “Single Crystal” Positive Electrode Materials Before and After Long Term Cycling by Cross-section Scanning Electron Microscopy journal January 2020
Superior Electrochemical and Kinetics Performance of LiNi0.8Co0.15Al0.05O2 Cathode by Neodymium Synergistic Modifying for Lithium Ion Batteries journal January 2020
Synthesis of Single Crystal LiNi 0.92 Co 0.06 Mn 0.01 Al 0.01 O 2 Cathode Materials with Superior Electrochemical Performance for Lithium Ion Batteries journal August 2020
Cobalt-Free Core-Shell Structure with High Specific Capacity and Long Cycle Life as an Alternative to Li[Ni0.8Mn0.1Co0.1]O2 journal January 2020
SrCO3 Assisted Synthesis of Disk-Like Micron-Sized Monocrystalline LiNi0.5Co0.2Mn0.3O2 with Preferred (104) Plane and Its Enhanced Cycle Performance journal October 2020
Temperature-Swing Synthesis of Large-Size Single-Crystal LiNi 0.6 Mn 0.2 Co 0.2 O 2 Cathode Materials journal January 2021
Superior Electrochemical Properties of Ni-Rich LiNi0.85Co0.05Mn0.10O2 Cathode with the Stable Polypyrrole Coating and Boron Doping for Li-Ion Batteries journal March 2021
Synthesis of Co-Free Ni-Rich Single Crystal Positive Electrode Materials for Lithium Ion Batteries: Part I. Two-Step Lithiation Method for Al- or Mg-Doped LiNiO2 journal April 2021
Transition Metal Oxides and Li2CO3 as Precursors for the Synthesis of Ni-Rich Single-Crystalline NCM for Sustainable Lithium-Ion Battery Production journal July 2022
Synthesis of Single Crystal LiNi 0.5 Mn 0.3 Co 0.2 O 2 for Lithium Ion Batteries journal January 2017
Synthesis of Single Crystal LiNi 0.88 Co 0.09 Al 0.03 O 2  with a Two-Step Lithiation Method journal January 2019
Synthesis of Single Crystal LiNi 0.6 Mn 0.2 Co 0.2 O 2 with Enhanced Electrochemical Performance for Lithium Ion Batteries journal January 2018
A Wide Range of Testing Results on an Excellent Lithium-Ion Cell Chemistry to be used as Benchmarks for New Battery Technologies journal January 2019
Investigating the Effects of Magnesium Doping in Various Ni-Rich Positive Electrode Materials for Lithium Ion Batteries journal January 2019
Current status of solid-state single crystal growth journal January 2020
Reversing planar gliding, microcracking enhances performance of single-crystalline Ni-rich cathode journal July 2021
Process design for calcination of nickel-based cathode materials by in situ characterization and multiscale modeling journal August 2022
Mixed control of boundary migration and the principle of microstructural evolution journal January 2016
Synthesis and Manipulation of Single-Crystalline Lithium Nickel Manganese Cobalt Oxide Cathodes: A Review of Growth Mechanism journal September 2020
Lithium-Ion Battery Storage for the Grid—A Review of Stationary Battery Storage System Design Tailored for Applications in Modern Power Grids journal December 2017
Boundary Structure-Dependent Grain Growth Behavior in Polycrystals: Model and Principle journal March 2013

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Related Subjects

25 ENERGY STORAGE
Mechanism
Ni-rich layered cathodes
Single-crystal
Solid reaction
Synthesis