Photoinduced electron transfer reactions through dendrimer architecture
Journal Article
·
· Journal of the American Chemical Society
- Univ. of Tokyo (Japan)
Herein we report the first photoreactive dendritic metalloporphyrin having noncovalently assembled electron-acceptor molecules on the exterior surface and describe a long-range photoinduced electron transfer through dendrimer architecture. Here, water-soluble dendritic zinc porphyrins with two different numbers of generations ([KO{sub 2}C]{sub 2(n+1)}LnPZn, n = 2, 4) were newly synthesized. In conclusion the long-range photoinduced electron transfer through an aryl ether dendrimer framework was demonstrated for a water-soluble dendritic zinc porphyrin bearing noncovalently assembled electron-acceptor molecules on the exterior surface. 14 refs., 2 figs., 1 tab.
- OSTI ID:
- 249704
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 16 Vol. 118; ISSN JACSAT; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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