Reentrant polar phase induced by the ferroionic coupling in B⁢i1−𝑥⁢S⁢m𝑥⁢Fe⁢O3 nanoparticles

Morozovska, Anna N.; Eliseev, Eugene A.; Fesych, Igor V.; Zagorodniy, Yuriy O.; Pylypchuk, Oleksandr S.; Leonenko, Evgenii V.; Rallev, Maxim V.; Yaremkevych, Andrii D.; Yurchenko, Lesya P.; Demchenko, Lesya; Kalinin, Sergei V.; Fesenko, Olena M.

doi:10.1103/physrevb.110.224110

Reentrant polar phase induced by the ferroionic coupling in B⁢i_1−𝑥⁢S⁢m_𝑥⁢Fe⁢O₃ nanoparticles

Journal Article · Mon Dec 23 00:00:00 EST 2024 · Physical Review. B

DOI:https://doi.org/10.1103/physrevb.110.224110· OSTI ID:2483741

^[1]; ^[1]; Fesych, Igor V. ^[2]; ^[1]; Pylypchuk, Oleksandr S. ^[1]; ^[1]; ^[1]; Yaremkevych, Andrii D. ^[1]; ^[1]; Demchenko, Lesya ^[3]; ^[4]; Fesenko, Olena M. ^[1]

National Academy of Sciences of Ukraine, Kyiv (Ukraine)
Taras Shevchenko National University of Kyiv (Ukraine)
Stockholm Univ. (Sweden); National Technical University of Ukraine, Kyiv (Ukraine)
Univ. of Tennessee, Knoxville, TN (United States)

Using the model of four sublattices, the Landau-Ginzburg-Devonshire-Kittel phenomenological approach and the Stephenson-Highland ionic adsorption model for the description of coupled polar and antipolar long-range orders in ferroics, we analytically calculated the phase diagrams and polar properties of B⁢i_1−𝑥⁢S⁢m_𝑥⁢Fe⁢O₃ nanoparticles covered by surface ions with dependence on their size, surface ions density, samarium content 𝑥 , and temperature. The size effects and ferroionic coupling govern the appearance and stability conditions of the long-range ordered ferroelectric, reentrant ferrielectric, and antiferroelectric phases in B⁢i_1−𝑥⁢S⁢m_𝑥⁢Fe⁢O₃ nanoparticles. Calculated phase diagrams are in qualitative agreement with the x-ray diffraction phase analysis, electron paramagnetic resonance, infrared spectroscopy, and electrophysical measurements of B⁢i_1−𝑥⁢S⁢m_𝑥⁢Fe⁢O₃ nanopowders sintered by the solution combustion method. The combined theoretical-experimental approach allows us to explain the influence of the ferroionic coupling and size effects in B⁢i_1−𝑥⁢S⁢m_𝑥⁢Fe⁢O₃ nanoparticles on their polar properties.

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Research Organization:: Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Organization:: National Research Foundation of Ukraine; USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0021118

OSTI ID:: 2483741

Alternate ID(s):: OSTI ID: 3003207

Journal Information:: Physical Review. B, Journal Name: Physical Review. B Journal Issue: 22 Vol. 110; ISSN 2469-9950; ISSN 2469-9969

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Reentrant polar phase induced by the ferroionic coupling in B⁢i1−𝑥⁢S⁢m𝑥⁢Fe⁢O3 nanoparticles

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Reentrant polar phase induced by the ferroionic coupling in B⁢i_1−𝑥⁢S⁢m_𝑥⁢Fe⁢O₃ nanoparticles