Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Aldol condensation of mixed oxygenates on TiO 2

Journal Article · · Catalysis Science and Technology
DOI:https://doi.org/10.1039/D3CY01798B· OSTI ID:2480384

Kinetic studies of aldol condensation of mixtures on TiO 2 reveal strong suppression of acetone self-condensation in the presence of acetaldehyde.

Sponsoring Organization:
USDOE
Grant/Contract Number:
EE0008921
OSTI ID:
2480384
Alternate ID(s):
OSTI ID: 2315058
OSTI ID: 2338111
Journal Information:
Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 7 Vol. 14; ISSN CSTAGD; ISSN 2044-4753
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (49)

Aqueous Phase Aldol Condensation of Formaldehyde and Acetone on Anatase TiO 2 (101) Surface: A Theoretical Investigation journal December 2019
Transient Studies of 2-Propanol Photocatalytic Oxidation on Titania journal December 1995
Mechanistic Considerations in Acid-Catalyzed Cracking of Olefins journal January 1996
Infrared Study of Pyridine Adsorbed on Unpromoted and Promoted Sulfated Zirconia journal April 1999
Acetone and Acetaldehyde Oligomerization on TiO2 Surfaces journal July 1999
Selectivity and mechanism shifts in the reactions of acetaldehyde on oxidized and reduced TiO2(001) surfaces journal January 1996
Aldol Condensation of Cyclopentanone with Valeraldehyde Over Metal Oxides journal February 2019
The production of methyl vinyl ketone by the vapor-phase aldol condensation between formaldehyde and acetone journal July 1987
Thermal desorption of gases journal July 1962
Secondary reactions of the base-catalyzed aldol condensation of acetone journal October 1991
Acetone Conversion and Deactivation of Zeolites book January 1989
Vapor phase aldol condensation of acetaldehyde on metal oxide catalysts journal November 1997
Catalytic hydrodeoxygenation journal June 2000
In situ FTIR spectra of pyridine adsorbed on SiO2–Al2O3, TiO2, ZrO2 and CeO2: general considerations for the identification of acid sites on surfaces of finely divided metal oxides journal October 2001
The effect of water on the acidity of TiO2 and sulfated titania journal April 2006
Aldol condensation of furfural and acetone over MgAl layered double hydroxides and mixed oxides journal March 2014
The role of renewable energy in the global energy transformation journal April 2019
IR spectral evidence of aldol condensation: Acetaldehyde adsorption over TiO2 surface journal December 2008
Vapor phase butanal self-condensation over unsupported and supported alkaline earth metal oxides journal February 2012
Condensation and esterification reactions of alkanals, alkanones, and alkanols on TiO2: Elementary steps, site requirements, and synergistic effects of bifunctional strategies journal August 2016
Elementary steps in acetone condensation reactions catalyzed by aluminosilicates with diverse void structures journal February 2017
Aldol condensation among acetaldehyde and ethanol reactants on TiO2: Experimental evidence for the kinetically relevant nucleophilic attack of enolates journal May 2018
Oxide-catalyzed self- and cross-condensation of cycloketones. Kinetically relevant steps that determine product distribution journal November 2020
Study of acetaldehyde condensation chemistry over magnesia and zirconia supported on silica journal December 2010
Acetaldehyde adsorption and condensation on anatase TiO2: Influence of acetaldehyde dimerization journal January 2014
Probing Acid–Base Properties of Anatase TiO 2 Nanoparticles with Dominant {001} and {101} Facets Using Methanol Chemisorption and Surface Reactions journal February 2021
Substituent Effects and Molecular Descriptors of Reactivity in Condensation and Esterification Reactions of Oxygenates on Acid–Base Pairs at TiO 2 and ZrO 2 Surfaces journal September 2016
Adsorption Mechanisms of Typical Carbonyl-Containing Volatile Organic Compounds on Anatase TiO2 (001) Surface: A DFT Investigation journal June 2017
Coupling of Acetaldehyde to Crotonaldehyde on CeO 2– x (111): Bifunctional Mechanism and Role of Oxygen Vacancies journal October 2018
Elucidating the Mechanism of Ambient-Temperature Aldol Condensation of Acetaldehyde on Ceria journal June 2021
Aldol Condensation of Acetaldehyde over Titania, Hydroxyapatite, and Magnesia journal April 2016
TiO 2 -Catalyzed n -Valeraldehyde Self-Condensation Reaction Mechanism and Kinetics journal June 2017
Growing the Bioeconomy through Catalysis: A Review of Recent Advancements in the Production of Fuels and Chemicals from Syngas-Derived Oxygenates journal April 2019
Quantitative Lewis/Brönsted Ratios Using DRIFTS journal November 2003
Kinetics, Selectivity, and Deactivation in the Aldol Condensation of Acetaldehyde on Anatase Titanium Dioxide journal January 2011
Catalytic Cracking of Linear Paraffins:  Effects of Chain Length journal January 1997
Entropy-Driven High Reactivity of Formaldehyde in Nucleophilic Attack by Enolates on Oxide Surfaces journal January 2018
Elucidation of Active Sites in Aldol Condensation of Acetone over Single-Facet Dominant Anatase TiO 2 (101) and (001) Catalysts journal December 2020
Surface Acidity and Properties of TiO 2 /SiO 2 Catalysts Prepared by Atomic Layer Deposition: UV−visible Diffuse Reflectance, DRIFTS, and Visible Raman Spectroscopy Studies journal June 2009
Photocatalytic Dehydrogenation of 2-Propanol on TiO2(110) journal September 1998
Molecular Mechanisms of Aldehyde Toxicity: A Chemical Perspective journal June 2014
Aldol condensation of acetaldehyde to form high molecular weight compounds on TiO2 journal January 1999
Catalytic routes for the conversion of biomass into liquid hydrocarbon transportation fuels journal January 2011
Recent advances in heterogeneous catalysts for bio-oil upgrading via “ex situ catalytic fast pyrolysis”: catalyst development through the study of model compounds journal January 2014
The role of synergic interaction in transition state formation for the aldol reaction on a metal oxide catalyst: a DFT investigation journal January 2015
Catalytic conversion of biomass to biofuels journal January 2010
Toward net-zero sustainable aviation fuel with wet waste–derived volatile fatty acids journal March 2021
2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy report July 2016
Ex Situ Catalytic Fast Pyrolysis of Lignocellulosic Biomass to Hydrocarbon Fuels: 2019 State of Technology and Future Research report March 2020

Similar Records

Aldol Condensation of Mixed Oxygenates on TiO2
Journal Article · Thu Feb 15 23:00:00 EST 2024 · Catalysis Science and Technology · OSTI ID:2338111

Consequences of Intrapore Liquids on Reactivity, Selectivity, and Stability for Aldol Condensation Reactions on Anatase TiO 2 Catalysts
Journal Article · Tue May 03 20:00:00 EDT 2022 · ChemCatChem · OSTI ID:1866299

Related Subjects