Zero-strain high entropy spinel oxide (FeNiCuCrMn)3O4@rGO as high-performance anode for sodium ion battery

Xiao, Bin; Liu, Xiaoyang; Xie, Zelin; Zheng, Duyu; Zha, Juxing; Qi, Jiqiu; Wei, Fuxiang; Meng, Qingkun; Xue, Xiaolan; Zhao, Danyang; Li, Yongzhi; Yin, Qing; Ma, Lu; Ge, Mingyuan; Xiao, Xianghui; Sui, Yanwei; Chen, Si; Zheng, Junchao

doi:10.1016/j.cej.2024.158269

Zero-strain high entropy spinel oxide (FeNiCuCrMn)₃O₄@rGO as high-performance anode for sodium ion battery

Journal Article · Wed Dec 04 00:00:00 UTC 2024 · Chemical Engineering Journal

DOI:https://doi.org/10.1016/j.cej.2024.158269· OSTI ID:2569476

Xiao, Bin ^[1]; Liu, Xiaoyang ^[2]; Xie, Zelin ^[1]; Zheng, Duyu ^[1]; Zha, Juxing ^[1]; Qi, Jiqiu ^[1]; Wei, Fuxiang ^[1]; Meng, Qingkun ^[1]; Xue, Xiaolan ^[1]; Zhao, Danyang ^[1]; Li, Yongzhi ^[1]; Yin, Qing ^[1]; Ma, Lu ^[3]; Ge, Mingyuan ^[3]; ^[3]; Sui, Yanwei ^[1]; Chen, Si ^[2]; ^[4]

China Univ. of Mining and Technology, Xuzhou, Jiangsu (China)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Central South University, Changsha (China)

High entropy spinel oxides (HEOs), as a new type of anode material with at least five transition metal elements and high theoretical specific capacity, have enormous promise in sodium ion batteries (SIBs). However, the influence of different transition metal elements on the structure and electrochemical performances of HEOs is not clear. Here, in this study, the addition of Mn to HEO can increase the surface oxygen vacancy (O_v) concentration, shorten the band gap, and enhance the electrochemical performance of (FeNiCuCrMn)₃O₄@rGO. XPS results show (FeNiCuCrMn)3O4@rGO has the highest surface O_v concentration. Ab initio calculations demonstrate that the indirect band gap of (FeNiCuCrMn)3O4@rGO is 0.068 eV. In situ X-ray diffraction and synchrotron X-ray absorption spectroscopy reveal that (FeNiCuCrMn)₃O₄@rGO exhibits a zero-strain characteristic with an inconsequential unit cell volume change of 0.2 %. Specifically, (FeNiCuCrMn)₃O₄@rGO as anode materials for SIBs show good cyclic stability (with a capacity retention of 84 % at 500 mA g⁻¹ after 3000 cycles). Overall, this work provides a new direction for optimizing transition metal elements in HEOs.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: SC0012704

OSTI ID:: 2569476

Alternate ID(s):: OSTI ID: 2480372
OSTI ID: 2574351

Report Number(s):: BNL--228290-2025-JAAM

Journal Information:: Chemical Engineering Journal, Journal Name: Chemical Engineering Journal Vol. 503; ISSN 1385-8947

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Zero-strain high entropy spinel oxide (FeNiCuCrMn)3O4@rGO as high-performance anode for sodium ion battery

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Zero-strain high entropy spinel oxide (FeNiCuCrMn)₃O₄@rGO as high-performance anode for sodium ion battery