Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Advancing high-temperature electrostatic energy storage via linker engineering of metal–organic frameworks in polymer nanocomposites

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/D4EE04085F· OSTI ID:2478739
 [1];  [2];  [3];  [4];  [5];  [6];  [4];  [5];  [2];  [2];  [7];  [2];  [8];  [4];  [9];  [2];  [2];  [5];  [4];  [2] more »;  [3] « less
  1. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA, The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an, Shaanxi 710049, P. R. China
  2. The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
  3. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA, The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
  4. State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an, Shaanxi 710049, P. R. China
  5. School of Polymer Science and Engineering, Center for Optoelectronic Materials and Devices, The University of Southern Mississippi, Hattiesburg, MS 39406, USA
  6. School of Polymer Science and Engineering, Center for Optoelectronic Materials and Devices, The University of Southern Mississippi, Hattiesburg, MS 39406, USA, Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
  7. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA, Department of Chemistry and the Hong Kong Branch of the Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science and Technology, Hong Kong 999077, P. R. China
  8. The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA, Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, USA
  9. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

Linker engineering of the UiO-66-based metal–organic framework series reveals its untapped potential as nanofillers for boosting the heat-resistant electrostatic energy storage performance of polyetherimide at 200 °C.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-05CH11231; SC0022050
OSTI ID:
2478739
Journal Information:
Energy & Environmental Science, Journal Name: Energy & Environmental Science Journal Issue: 2 Vol. 18; ISSN EESNBY; ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (66)

Review of Polymer‐Based Nanodielectric Exploration and Film Scale‐Up for Advanced Capacitors journal April 2019
Sub‐Nanowires Boost Superior Capacitive Energy Storage Performance of Polymer Composites at High Temperatures journal January 2023
Interfacial Engineering Using Covalent Organic Frameworks in Polymer Composites for High‐Temperature Electrostatic Energy Storage journal January 2024
Mechanical Properties in Metal-Organic Frameworks: Emerging Opportunities and Challenges for Device Functionality and Technological Applications journal November 2017
Suppressing the Loss of Polymer‐Based Dielectrics for High Power Energy Storage journal November 2022
Scalable Ultrathin All‐Organic Polymer Dielectric Films for High‐Temperature Capacitive Energy Storage journal October 2022
Tailoring Poly(Styrene‐co‐maleic anhydride) Networks for All‐Polymer Dielectrics Exhibiting Ultrahigh Energy Density and Charge–Discharge Efficiency at Elevated Temperatures journal November 2022
Scalable Polyimide‐Organosilicate Hybrid Films for High‐Temperature Capacitive Energy Storage journal March 2023
Quantum Size Effect to Induce Colossal High‐Temperature Energy Storage Density and Efficiency in Polymer/Inorganic Cluster Composites journal June 2023
Polyimides Physically Crosslinked by Aromatic Molecules Exhibit Ultrahigh Energy Density at 200 °C journal July 2023
Spiral‐Structured Dielectric Polymers Exhibiting Ultrahigh Energy Density and Charge–Discharge Efficiency at High Temperatures journal October 2023
Aromatic‐Free Polymers Based All‐Organic Dielectrics with Breakdown Self‐Healing for High‐Temperature Capacitive Energy Storage journal October 2023
γ‐Ray Irradiation Significantly Enhances Capacitive Energy Storage Performance of Polymer Dielectric Films journal February 2024
Engineering the Dielectric Constants of Polymers: From Molecular to Mesoscopic Scales journal December 2023
Advances in Polymer Dielectrics with High Energy Storage Performance by Designing Electric Charge Trap Structures journal December 2023
Chain‐Like Semiconductive Fillers for Dielectric Enhancement and Loss Reduction of Polymer Composites journal March 2024
Multilaminate Energy Storage Films from Entropy‐Driven Self‐Assembled Supramolecular Nanocomposites journal May 2024
Pendant Group Functionalization of Cyclic Olefin for High Temperature and High‐Density Energy Storage journal June 2024
Atomic‐Level Matching Metal‐Ion Organic Hybrid Interface to Enhance Energy Storage of Polymer‐Based Composite Dielectrics journal May 2024
Tuning Nanofillers in In Situ Prepared Polyimide Nanocomposites for High‐Temperature Capacitive Energy Storage journal March 2020
High‐Temperature High‐Energy‐Density Dielectric Polymer Nanocomposites Utilizing Inorganic Core–Shell Nanostructured Nanofillers journal June 2021
Molecular Trap Engineering Enables Superior High‐Temperature Capacitive Energy Storage Performance in All‐Organic Composite at 200 °C journal February 2023
Scalable High‐Permittivity Polyimide Copolymer with Ultrahigh High‐Temperature Capacitive Performance Enabled by Molecular Engineering journal December 2023
25 Years of Reticular Chemistry journal July 2021
In Situ Growth of Three‐Dimensional MXene/Metal–Organic Framework Composites for High‐Performance Supercapacitors journal January 2022
Anisotropic Semicrystalline Homopolymer Dielectrics for High‐Temperature Capacitive Energy Storage journal May 2024
Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals journal May 2011
Multiwfn: A multifunctional wavefunction analyzer journal December 2011
Excellent Stability in Polyetherimide/SiO2 Nanocomposites with Ultrahigh Energy Density and Discharge Efficiency at High Temperature journal June 2022
Improved Capacitive Energy Storage Nanocomposites at High Temperature Utilizing Ultralow Loading of Bimetallic MOF journal March 2023
Design strategies for dielectric metal–organic frameworks and their applications in microelectronic devices journal March 2024
Metal-organic Framework/Polyimide composite with enhanced breakdown strength for flexible capacitor journal February 2022
Interface-modulated nanocomposites based on polypropylene for high-temperature energy storage journal June 2020
High-performing polysulfate dielectrics for electrostatic energy storage under harsh conditions journal January 2023
High-temperature polymers with record-high breakdown strength enabled by rationally designed chain-packing behavior in blends journal July 2021
Rational design of all-organic flexible high-temperature polymer dielectrics journal September 2022
Mechanism insights and design strategies for metal-organic framework-based alkaline hydrogen evolution reaction electrocatalysts journal November 2024
Recent progress in polymer dielectric energy storage: From film fabrication and modification to capacitor performance and application journal December 2023
Polymer dielectrics for high-temperature energy storage: Constructing carrier traps journal December 2023
Recent Progress and Future Prospects on All-Organic Polymer Dielectrics for Energy Storage Capacitors journal December 2021
A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-66-Type MOFs journal April 2015
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
Polymer-Grafted Nanoparticles with Variable Grafting Densities for High Energy Density Polymeric Nanocomposite Dielectric Capacitors journal April 2023
Flexible high-temperature dielectric materials from polymer nanocomposites journal July 2015
Polymer/molecular semiconductor all-organic composites for high-temperature dielectric energy storage journal August 2020
Designing tailored combinations of structural units in polymer dielectrics for high-temperature capacitive energy storage journal April 2023
AI-assisted discovery of high-temperature dielectrics for energy storage journal July 2024
Roll-to-roll fabricated polymer composites filled with subnanosheets exhibiting high energy density and cyclic stability at 200 °C journal January 2024
Polymer nanocomposite dielectrics for capacitive energy storage journal January 2024
Asymmetric pore windows in MOF membranes for natural gas valorization journal June 2022
Ladderphane copolymers for high-temperature capacitive energy storage journal March 2023
Selective liquid-phase molecular sieving via thin metal–organic framework membranes with topological defects journal July 2024
Polymeric insulating materials characteristics for high-voltage applications journal July 2024
Metal–Organic Frameworks (MOFs) journal January 2014
Catalysis and photocatalysis by metal organic frameworks journal January 2018
Interface design for high energy density polymer nanocomposites journal January 2019
Dielectric polymers for high-temperature capacitive energy storage journal January 2021
Flexible polyolefin dielectric by strategic design of organic modules for harsh condition electrification journal January 2022
High-temperature polyimide dielectric materials for energy storage: theory, design, preparation and properties journal January 2022
Multilayer nanocomposites with ultralow loadings of nanofillers exhibiting superb capacitive energy storage performance journal January 2023
Surface ion-activated polymer composite dielectrics for superior high-temperature capacitive energy storage journal January 2024
Depressing relaxation and conduction loss of polar polymer materials by inserting bulky charge traps for superior energy storage performance in high-pulse energy storage capacitor applications journal January 2023
Thermally activated dynamic bonding network for enhancing high-temperature energy storage performance of PEI-based dielectrics journal January 2023
Flexible cyclic-olefin with enhanced dipolar relaxation for harsh condition electrification journal November 2021
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
High-Temperature Dielectric Materials for Electrical Energy Storage journal July 2018

Similar Records

Linker Contribution toward Stability of Metal–Organic Frameworks under Ionizing Radiation
Journal Article · Sun Nov 14 19:00:00 EST 2021 · Chemistry of Materials · OSTI ID:1832116

Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-66
Journal Article · Sat Apr 25 20:00:00 EDT 2020 · Journal of the American Chemical Society · OSTI ID:1623393

Related Subjects