Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Finding a needle in a haystack: quantitative HERFD-XRF imaging and HERFD-XANES characterization of trace platinum in gold solidi from the Late Roman and Byzantine Empires

Journal Article · · Journal of Analytical Atomic Spectrometry
DOI:https://doi.org/10.1039/D4JA00281D· OSTI ID:2478732
 [1];  [2];  [3];  [4];  [5];  [6]
  1. Western University, Department of Earth Sciences, London, ON, Canada, Western University, Soochow-Western Centre for Synchrotron Radiation Research, London, ON, Canada, Western University, Department of Anthropology, London, ON, Canada, LISA CAN Analytical Solutions Inc., Saskatoon, SK, Canada
  2. Advanced Photon Source, Lemont, IL, USA
  3. Canadian Light Source Inc., Saskatoon, SK, Canada
  4. University of Ottawa, Department of Classics and Religious Studies, Ottawa, ON, Canada
  5. Queen's University, Department of Geography and Planning, Kingston, ON, Canada
  6. Western University, Department of Earth Sciences, London, ON, Canada, Western University, Soochow-Western Centre for Synchrotron Radiation Research, London, ON, Canada

Application of HERFD to SR-XRF imaging and XANES enables precise quantification of trace Pt in Late Roman and Byzantine gold solidi, revolutionizing our understanding of minting practices, economic shifts, and the emergence of new gold sources.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
2478732
Journal Information:
Journal of Analytical Atomic Spectrometry, Journal Name: Journal of Analytical Atomic Spectrometry; ISSN JASPE2; ISSN 0267-9477
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (58)

Analysis of the Hoard of Beçin using X‐ray‐based techniques journal July 2012
Precious Metals and Provenance Enquiries using LA-ICP-MS journal August 1999
Chemical Mapping of Ancient Artifacts and Fossils with X-Ray Spectroscopy book May 2020
Fingerprints in Gold book January 2009
Unlocking the secrets of gold antiquities journal March 1988
LA-ICP-MS analysis of platinum-group elements and other elements of interest in ancient gold journal July 2004
Cultural heritage and archaeology materials studied by synchrotron spectroscopy and imaging journal November 2011
Mechanical analysis of coin striking: Application to the study of byzantine gold solidi minted in constantinople and carthage journal November 1984
The study of the characterisation and provenance of coins and other metalwork using XRF, PIXE and Activation Analysis book January 2000
Electronic structures of supported Pt and PtSn nanoparticles in the presence of adsorbates and during CO oxidation☆ journal February 2011
Spectroscopic investigation of historical uranium glasses journal January 2023
Electronic structure effects in catalysis probed by X-ray and electron spectroscopy journal October 2013
Gold traces to trace gold journal September 2004
Early Cambodian gold and silver from Prohear: composition, trace elements and gilding journal September 2012
Platinum group placer minerals in ancient gold artifacts – Geochemistry and osmium isotopes of inclusions in Early Bronze Age gold from Ur/Mesopotamia journal April 2016
Double Dispersive X-Ray Fluorescence (D 2 XRF) based on an Energy Dispersive pnCCD detector for the detection of platinum in gold journal March 2016
Fingerprinting ancient gold by measuring Pt with spatially resolved high energy Sy-XRF
  • Guerra, M. F.; Calligaro, T.; Radtke, M.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 240, Issue 1-2 https://doi.org/10.1016/j.nimb.2005.06.150
journal October 2005
Analysis of trace elements in gold alloys by SR-XRF at high energy at the BAMline journal May 2008
Multivariate statistical analysis of trace element compositions of native gold from orogenic gold deposits: Implication for mineral exploration journal April 2021
Development and trends in synchrotron studies of ancient and historical materials journal October 2012
Non-destructive analysis and testing of museum objects: An overview of 5 years of research journal December 2005
Synchrotron-based techniques for studying the environmental health effects of heavy metals: Current status and future perspectives journal January 2020
Introduction to XAFS book January 2010
Is Energy Resolution Still an Important Specification in EDS? journal July 2013
Damages Induced by Synchrotron Radiation-Based X-ray Microanalysis in Chrome Yellow Paints and Related Cr-Compounds: Assessment, Quantification, and Mitigation Strategies journal September 2020
In Situ / Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy journal September 2020
High Energy Resolution Fluorescence Detection of the Pt L 3,2 -Edge Whitelines of Pt-Based Bimetallic Systems: Implications for the Pt 5d 5/2,3/2 Density of States journal January 2021
High Energy Resolution X-ray Absorption Spectroscopy of Environmentally Relevant Lead(II) Compounds journal October 2009
In situ X-ray spectroscopies beyond conventional X-ray absorption spectroscopy on deciphering dynamic configuration of electrocatalysts journal October 2023
In situ X-ray probing reveals fingerprints of surface platinum oxide journal January 2011
HERFD-XAS and valence-to-core-XES: new tools to push the limits in research with hard X-rays? journal January 2014
The non-destructive determination of Pt in ancient Roman gold coins by XRF spectrometry journal January 2014
Rapid, quantitative, and non-destructive SR-WD-XRF mapping of trace platinum in Byzantine Roman Empire gold coins journal January 2018
Electronic structure of alumina-supported monometallic Pt and bimetallic PtSn catalysts under hydrogen and carbon monoxide environment journal January 2010
Further metallurgical analyses on silver coins of Trajan (AD 98–117) journal January 2011
Studies on archaeological gold items found in Romanian territory using X-Ray-based analytical spectrometry journal January 2012
A new μ-high energy resolution fluorescence detection microprobe imaging spectrometer at the Stanford Synchrotron Radiation Lightsource beamline 6-2 journal August 2022
New Opportunities Offered by the ESRF to the Cultural and Natural Heritage Communities journal September 2022
Archaeometallurgy using synchrotron radiation: a review journal February 2012
Gold cultural heritage objects: a review of studies of provenance and manufacturing technologies journal July 2003
X-ray spectroscopic and first-principles investigation of lead tungstate under pressure journal August 2021
Range-extended EXAFS at the L edge of rare earths using high-energy-resolution fluorescence detection: A study of La in LaOCl journal July 2005
Chemical State of Complex Uranium Oxides journal December 2013
XAFS at the Pacific Northwest Consortium-Collaborative Access Team undulator beamline journal March 2001
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
Quantitative performance measurements of bent crystal Laue analyzers for X-ray fluorescence spectroscopy journal March 2012
A bent Laue analyzer for fluorescence EXAFS detection journal May 1999
Improved precision in As speciation analysis with HERFD-XANES at the AsK-edge: the case of As speciation in mine waste journal August 2022
High-resolution X-ray imaging based on curved Bragg mirrors: first results journal February 2003
Operando High Energy Resolution Fluorescence Detected (HERFD) X-Ray Absorption Spectroscopic Study of Toyota Mirai Gen.1 Catalysts journal October 2022
Non-Destructive and Non-Invasive Approaches for the Identification of Hydroxy Lead–Calcium Phosphate Solid Solutions ((PbxCa1−x)5(PO4)3OH) in Cultural Heritage Materials journal April 2024
13. Physicochemical approaches to gold and silver work, an overview: Searching for technologies, tracing routes, attempting to preserve book February 2020
High-Energy Resolution Fluorescence Detected X-Ray Absorption Spectroscopy: A Powerful New Structural Tool in Environmental Biogeochemistry Sciences journal November 2017
Gold speciation in hydrothermal fluids revealed by in situ high energy resolution X-ray absorption spectroscopy journal March 2022
A novel non-destructive workflow for examining germanium and co-substituents in ZnS journal January 2023
Exploring Platinum Speciation with X-ray Absorption Spectroscopy under High-Energy Resolution Fluorescence Detection Mode journal December 2022
Thracian golden wreath from Kabyle, Bulgaria: chemical composition journal January 2015
An arsenic-driven pump for invisible gold in hydrothermal systems journal April 2021

Similar Records

Rapid, quantitative, and non-destructive SR-WD-XRF mapping of trace platinum in Byzantine Roman Empire gold coins
Journal Article · Sun Dec 31 23:00:00 EST 2017 · Journal of Analytical Atomic Spectrometry · OSTI ID:1479036

Rapid, quantitative, and non-destructive SR-WD-XRF mapping of trace platinum in Byzantine Roman Empire gold coins
Journal Article · Sun Dec 31 19:00:00 EST 2017 · Journal of Analytical Atomic Spectrometry · OSTI ID:1467929

Improved precision in As speciation analysis with HERFD-XANES at the As K -edge: the case of As speciation in mine waste
Journal Article · Wed Aug 10 20:00:00 EDT 2022 · Journal of Synchrotron Radiation (Online) · OSTI ID:1881046

Related Subjects