Selenium interaction with iron minerals: Quantitative comparison of sorption and coprecipitation impacts on mobility

Balboni, Enrica; Han, Sol-chan; Zavarin, Mavrik

doi:10.1016/j.apgeochem.2024.106194

Selenium interaction with iron minerals: Quantitative comparison of sorption and coprecipitation impacts on mobility

Journal Article · Thu Oct 10 00:00:00 EDT 2024 · Applied Geochemistry

DOI:https://doi.org/10.1016/j.apgeochem.2024.106194· OSTI ID:2478208

^[1]; Han, Sol-chan ^[2]; Zavarin, Mavrik ^[1]

Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Given the significance of selenium (Se) as a micronutrient, the radioactive nature of some of its isotopes, and its affinity to iron (Fe) minerals, extensive research has been conducted on the sorption mechanisms between Se and these minerals. Here, in this study, we employ sorption data sourced from the L-SCIE database and coprecipitation data from available literature to achieve the following objectives: i) establish coherence between adsorption and coprecipitation processes, ii) quantitatively evaluate the importance of these processes in nuclear waste repository science, and iii) propose a forward-looking approach for integrating coprecipitation into reactive transport models. Our findings indicate that a correlation between Se adsorption and coprecipitation can be established using the λ formalism. The comparable log(λ_Se(IV)/λ_Se(VI)) ratios derived from adsorption and coprecipitation experiments suggest that these processes can be quantitatively compared and evaluated using our numerical approach. Across all iron oxide phases examined, coprecipitation leads to significantly greater immobilization of Se compared to adsorption. Specifically, for hydrous ferric oxide, hematite, and goethite, coprecipitation is predicted to result in 100–1000 times more Se immobilization compared to adsorption, irrespective of the Se oxidation state (Se(IV) or Se(VI)); notably stronger immobilization potential via coprecipitation was observed for magnetite. The modeling approach and quantitative analysis presented herein clearly highlight the importance of including coprecipitation processes when simulating Se (and other elements) transport, particularly under conditions where mineral compositions are transient or evolving with time. Neglecting coprecipitation in models is likely to lead to significant overestimates of migration.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Nuclear Energy (NE), Office of Spent Fuel and Waste Disposition. Office of Spent Fuel and Waste Science and Technology

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 2478208

Report Number(s):: LLNL--JRNL-861948; 1093207

Journal Information:: Applied Geochemistry, Journal Name: Applied Geochemistry Vol. 175; ISSN 0883-2927

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (94)

Comparison of Selenate and Sulfate Adsorption on Goethite Rietra, René P. J. J.; Hiemstra, Tjisse; van Riemsdijk, Willem H. Journal of Colloid and Interface Science, Vol. 240, Issue 2 https://doi.org/10.1006/jcis.2001.7650	journal	August 2001
X-ray diffraction and Fourier transform-infrared analysis of the rust formed by corrosion of steel in aqueous solutions Musić, S.; Gotić, M.; Popović, S. Journal of Materials Science, Vol. 28, Issue 21 https://doi.org/10.1007/BF00365176	journal	November 1993
Characterization of corrosion products in the permeable reactive barriers Roh, Y.; Lee, S. Y.; Elless, M. P. Environmental Geology, Vol. 40, Issue 1-2 https://doi.org/10.1007/s002540000178	journal	December 2000
Selenium uptake onto natural pyrite Curti, Enzo; Aimoz, Laure; Kitamura, Akira Journal of Radioanalytical and Nuclear Chemistry, Vol. 295, Issue 3 https://doi.org/10.1007/s10967-012-1966-9	journal	July 2012
Selenium environmental cycling and bioavailability: a structural chemist point of view Fernández-Martínez, Alejandro; Charlet, Laurent Reviews in Environmental Science and Bio/Technology, Vol. 8, Issue 1 https://doi.org/10.1007/s11157-009-9145-3	journal	February 2009
Comparison of adsorption characteristics of Se(IV) and Se(VI) onto hematite: effects of reaction time, initial concentration, pH, and ionic strength Jang, Mijeong; Pak, Seyoung; Kim, Myoung-Jin Environmental Earth Sciences, Vol. 74, Issue 2 https://doi.org/10.1007/s12665-015-4103-6	journal	February 2015
Adsorption of selenium by amorphous iron oxyhydroxide and manganese dioxide Balistrieri, Laurie S.; Chao, T. T. Geochimica et Cosmochimica Acta, Vol. 54, Issue 3 https://doi.org/10.1016/0016-7037(90)90369-V	journal	March 1990
Surface ionization and complexation at the oxide/water interface. 3. Adsorption of anions Davis, James A.; Leckie, James O. Journal of Colloid and Interface Science, Vol. 74, Issue 1 https://doi.org/10.1016/0021-9797(80)90168-X	journal	March 1980
Modeling ionic strength effects on anion adsorption at hydrous oxide/solution interfaces Hayes, Kim F.; Papelis, Charalambos; Leckie, James O. Journal of Colloid and Interface Science, Vol. 125, Issue 2 https://doi.org/10.1016/0021-9797(88)90039-2	journal	October 1988
A critical review of thermodynamic data for selenium species at 25°C Séby, F.; Potin-Gautier, M.; Giffaut, E. Chemical Geology, Vol. 171, Issue 3-4 https://doi.org/10.1016/S0009-2541(00)00246-1	journal	January 2001
Coprecipitation of Uranium(VI) with Calcite: XAFS, micro-XAS, and luminescence characterization Reeder, Richard J.; Nugent, Melissa; Tait, C. Drew Geochimica et Cosmochimica Acta, Vol. 65, Issue 20 https://doi.org/10.1016/S0016-7037(01)00647-0	journal	October 2001
Secondary mineralization pathways induced by dissimilatory iron reduction of ferrihydrite under advective flow Hansel, Colleen M.; Benner, Shawn G.; Neiss, Jim Geochimica et Cosmochimica Acta, Vol. 67, Issue 16 https://doi.org/10.1016/S0016-7037(03)00276-X	journal	August 2003
79Se: geochemical and crystallo-chemical retardation mechanisms Chen, Fanrong; C. Burns, Peter; Ewing, Rodney C. Journal of Nuclear Materials, Vol. 275, Issue 1 https://doi.org/10.1016/S0022-3115(99)00105-1	journal	October 1999
Module-oriented modeling of reactive transport with HYTEC van der Lee, Jan; De Windt, Laurent; Lagneau, Vincent Computers & Geosciences, Vol. 29, Issue 3 https://doi.org/10.1016/S0098-3004(03)00004-9	journal	April 2003
Geochemical changes during biodegradation of petroleum hydrocarbons: field investigations and biogeochemical modelling Prommer, H.; Davis, G. B.; Barry, D. A. Organic Geochemistry, Vol. 30, Issue 6 https://doi.org/10.1016/S0146-6380(99)00027-3	journal	June 1999
Simulation of reactive processes related to biodegradation in aquifers Schäfer, Dirk; Schäfer, Wolfgang; Kinzelbach, Wolfgang Journal of Contaminant Hydrology, Vol. 31, Issue 1-2 https://doi.org/10.1016/S0169-7722(97)00060-0	journal	May 1998
Towards an understanding of the sorption of U(VI) and Se(IV) on sodium bentonite Boult, K. A.; Cowper, M. M.; Heath, T. G. Journal of Contaminant Hydrology, Vol. 35, Issue 1-3 https://doi.org/10.1016/S0169-7722(98)00122-3	journal	December 1998
Sorption of selenium anionic species on apatites and iron oxides from aqueous solutions Duc, Myriam; Lefevre, Gregory; Fedoroff, Michel Journal of Environmental Radioactivity, Vol. 70, Issue 1-2 https://doi.org/10.1016/S0265-931X(03)00125-5	journal	January 2003
Coprecipitation of radionuclides with calcite: estimation of partition coefficients based on a review of laboratory investigations and geochemical data Curti, Enzo Applied Geochemistry, Vol. 14, Issue 4 https://doi.org/10.1016/S0883-2927(98)00065-1	journal	June 1999
Modeling reactive transport in non-ideal aqueous–solid solution system Shao, Haibing; Dmytrieva, Svitlana V.; Kolditz, Olaf Applied Geochemistry, Vol. 24, Issue 7 https://doi.org/10.1016/j.apgeochem.2009.04.001	journal	July 2009
A chemistry-informed hybrid machine learning approach to predict metal adsorption onto mineral surfaces Chang, Elliot; Zavarin, Mavrik; Beverly, Linda Applied Geochemistry, Vol. 155 https://doi.org/10.1016/j.apgeochem.2023.105731	journal	August 2023
Preparation of radiochemically pure 79Se and highly precise determination of its half-life Jörg, Gerhard; Bühnemann, Rolf; Hollas, Simon Applied Radiation and Isotopes, Vol. 68, Issue 12 https://doi.org/10.1016/j.apradiso.2010.05.006	journal	December 2010
Sorption of selenium(IV) and selenium(VI) onto magnetite Martínez, M.; Giménez, J.; de Pablo, J. Applied Surface Science, Vol. 252, Issue 10 https://doi.org/10.1016/j.apsusc.2005.05.067	journal	March 2006
Fate of adsorbed arsenate during phase transformation of ferrihydrite in the presence of gypsum and alkaline conditions Das, Soumya; Essilfie-Dughan, Joseph; Hendry, M. Jim Chemical Geology, Vol. 411 https://doi.org/10.1016/j.chemgeo.2015.06.031	journal	September 2015
Competition between selenium (IV) and silicic acid on the hematite surface Jordan, Norbert; Marmier, Nicolas; Lomenech, Claire Chemosphere, Vol. 75, Issue 1 https://doi.org/10.1016/j.chemosphere.2008.11.018	journal	March 2009
Smart Kd-values, their uncertainties and sensitivities - Applying a new approach for realistic distribution coefficients in geochemical modeling of complex systems Stockmann, M.; Schikora, J.; Becker, D. -A. Chemosphere, Vol. 187 https://doi.org/10.1016/j.chemosphere.2017.08.115	journal	November 2017
Corrosion of carbon steel under sequential aerobic–anaerobic environmental conditions El Hajj, H.; Abdelouas, A.; El Mendili, Y. Corrosion Science, Vol. 76 https://doi.org/10.1016/j.corsci.2013.07.017	journal	November 2013
Reactive transport modeling: An essential tool and a new research approach for the Earth sciences Steefel, C.; Depaolo, D.; Lichtner, P. Earth and Planetary Science Letters, Vol. 240, Issue 3-4 https://doi.org/10.1016/j.epsl.2005.09.017	journal	December 2005
Selenite retention by nanocrystalline magnetite: Role of adsorption, reduction and dissolution/co-precipitation processes Missana, T.; Alonso, U.; Scheinost, A. C. Geochimica et Cosmochimica Acta, Vol. 73, Issue 20 https://doi.org/10.1016/j.gca.2009.07.005	journal	October 2009
Adsorption mechanism of selenium(VI) onto maghemite Jordan, N.; Ritter, A.; Foerstendorf, H. Geochimica et Cosmochimica Acta, Vol. 103 https://doi.org/10.1016/j.gca.2012.09.048	journal	February 2013
Incorporation of Np(V) and U(VI) in carbonate and sulfate minerals crystallized from aqueous solution Balboni, Enrica; Morrison, Jessica M.; Wang, Zheming Geochimica et Cosmochimica Acta, Vol. 151 https://doi.org/10.1016/j.gca.2014.10.027	journal	February 2015
Uptake mechanisms of selenium oxyanions during the ferrihydrite-hematite recrystallization Börsig, Nicolas; Scheinost, Andreas C.; Shaw, Samuel Geochimica et Cosmochimica Acta, Vol. 206 https://doi.org/10.1016/j.gca.2017.03.004	journal	June 2017
Reactive transport model of silicification at the Mount Isa copper deposit, Australia Kühn, Michael; Gessner, Klaus Journal of Geochemical Exploration, Vol. 89, Issue 1-3 https://doi.org/10.1016/j.gexplo.2005.11.076	journal	April 2006
Sorption of selenite ions on hematite Duc, M.; Lefèvre, G.; Fédoroff, M. Journal of Colloid and Interface Science, Vol. 298, Issue 2 https://doi.org/10.1016/j.jcis.2006.01.029	journal	June 2006
Sorption of selenium(IV) onto magnetite in the presence of silicic acid Jordan, Norbert; Lomenech, Claire; Marmier, Nicolas Journal of Colloid and Interface Science, Vol. 329, Issue 1 https://doi.org/10.1016/j.jcis.2008.09.052	journal	January 2009
Experimental study and modelling of selenite sorption onto illite and smectite clays Missana, T.; Alonso, U.; García-Gutiérrez, M. Journal of Colloid and Interface Science, Vol. 334, Issue 2 https://doi.org/10.1016/j.jcis.2009.02.059	journal	June 2009
Sorption of selenium(IV) and selenium(VI) onto synthetic pyrite (FeS2): Spectroscopic and microscopic analyses Han, Dong Suk; Batchelor, Bill; Abdel-Wahab, Ahmed Journal of Colloid and Interface Science, Vol. 368, Issue 1 https://doi.org/10.1016/j.jcis.2011.10.065	journal	February 2012
Preferential adsorption of selenium oxyanions onto {1 1 0} and {0 1 2} nano-hematite facets Lounsbury, Amanda W.; Wang, Ranran; Plata, Desiree L. Journal of Colloid and Interface Science, Vol. 537 https://doi.org/10.1016/j.jcis.2018.11.018	journal	March 2019
Mobile fission and activation products in nuclear waste disposal Grambow, Bernd Journal of Contaminant Hydrology, Vol. 102, Issue 3-4 https://doi.org/10.1016/j.jconhyd.2008.10.006	journal	December 2008
Formation of a ternary neptunyl(V) biscarbonato inner-sphere sorption complex inhibits calcite growth rate Heberling, Frank; Scheinost, Andreas C.; Bosbach, Dirk Journal of Contaminant Hydrology, Vol. 124, Issue 1-4 https://doi.org/10.1016/j.jconhyd.2011.02.002	journal	June 2011
Structure of selenium incorporated in pyrite and mackinawite as determined by XAFS analyses Diener, A.; Neumann, T.; Kramar, U. Journal of Contaminant Hydrology, Vol. 133 https://doi.org/10.1016/j.jconhyd.2012.03.003	journal	May 2012
Effects of pH and anions on the sorption of selenium ions onto magnetite Kim, Seung Soo; Min, Je Ho; Lee, Jae Kwang Journal of Environmental Radioactivity, Vol. 104 https://doi.org/10.1016/j.jenvrad.2011.09.013	journal	February 2012
Sorption of selenium(IV) and selenium(VI) onto natural iron oxides: Goethite and hematite Rovira, Miquel; Giménez, Javier; Martínez, María Journal of Hazardous Materials, Vol. 150, Issue 2 https://doi.org/10.1016/j.jhazmat.2007.04.098	journal	January 2008
Sorption kinetic study of selenite and selenate onto a high and low pressure aged iron oxide nanomaterial Gonzalez, Christina M.; Hernandez, Jeffrey; Peralta-Videa, Jose R. Journal of Hazardous Materials, Vol. 211-212 https://doi.org/10.1016/j.jhazmat.2011.08.023	journal	April 2012
The role of counter ions in nano-hematite synthesis: Implications for surface area and selenium adsorption capacity Lounsbury, Amanda W.; Yamani, Jamila S.; Johnston, Chad P. Journal of Hazardous Materials, Vol. 310 https://doi.org/10.1016/j.jhazmat.2016.01.078	journal	June 2016
Corrosion issues in nuclear waste disposal Féron, Damien; Crusset, Didier; Gras, Jean-Marie Journal of Nuclear Materials, Vol. 379, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2008.06.023	journal	September 2008
The essential toxin: The changing perception of selenium in environmental sciences Lenz, Markus; Lens, Piet N. L. Science of The Total Environment, Vol. 407, Issue 12 https://doi.org/10.1016/j.scitotenv.2008.07.056	journal	June 2009
ES&T in the 21st Century: A Data-Driven Analysis of Research Topics, Interconnections, And Trends in the Past 20 Years Zhu, Jun-Jie; Dressel, Willow; Pacion, Kelee Environmental Science & Technology, Vol. 55, Issue 6 https://doi.org/10.1021/acs.est.0c07551	journal	March 2021
Community Data Mining Approach for Surface Complexation Database Development Zavarin, Mavrik; Chang, Elliot; Wainwright, Haruko Environmental Science & Technology, Vol. 56, Issue 4 https://doi.org/10.1021/acs.est.1c07109	journal	February 2022
Numerical Modeling of Arsenic Mobility during Reductive Iron-Mineral Transformations Rawson, Joey; Prommer, Henning; Siade, Adam Environmental Science & Technology, Vol. 50, Issue 5 https://doi.org/10.1021/acs.est.5b05956	journal	February 2016
Adsorption of Selenium and Strontium on Goethite: EXAFS Study and Surface Complexation Modeling of the Ternary Systems Nie, Zhe; Finck, Nicolas; Heberling, Frank Environmental Science & Technology, Vol. 51, Issue 7 https://doi.org/10.1021/acs.est.6b06104	journal	March 2017
Mechanisms of Se(IV) Co-precipitation with Ferrihydrite at Acidic and Alkaline Conditions and Its Behavior during Aging Francisco, Paul Clarence M.; Sato, Tsutomu; Otake, Tsubasa Environmental Science & Technology, Vol. 52, Issue 8 https://doi.org/10.1021/acs.est.8b00462	journal	March 2018
Uranium(V) Incorporation Mechanisms and Stability in Fe(II)/Fe(III) (oxyhydr)Oxides Roberts, Hannah E.; Morris, Katherine; Law, Gareth T. W. Environmental Science & Technology Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acs.estlett.7b00348	journal	September 2017
Transformation of Ferrihydrite to Goethite and the Fate of Plutonium Balboni, Enrica; Smith, Kurt F.; Moreau, Liane M. ACS Earth and Space Chemistry, Vol. 4, Issue 11 https://doi.org/10.1021/acsearthspacechem.0c00195	journal	October 2020
Plutonium Co-precipitation with Calcite Balboni, Enrica; Smith, Kurt F.; Moreau, Liane M. ACS Earth and Space Chemistry, Vol. 5, Issue 12 https://doi.org/10.1021/acsearthspacechem.1c00181	journal	November 2021
Chemistry of Iron Sulfides Rickard, David; Luther, George W. Chemical Reviews, Vol. 107, Issue 2 https://doi.org/10.1021/cr0503658	journal	February 2007
Surface and bulk characteristics of binary oxide suspensions Anderson, Paul R.; Benjamin, Mark M. Environmental Science & Technology, Vol. 24, Issue 5 https://doi.org/10.1021/es00075a013	journal	May 1990
Kinetics of selenate and selenite adsorption/desorption at the goethite/water interface Zhang, Pengchu; Sparks, Donald L. Environmental Science & Technology, Vol. 24, Issue 12 https://doi.org/10.1021/es00082a010	journal	December 1990
Mechanisms of Selenate Adsorption on Iron Oxides and Hydroxides Peak, D.; Sparks, D. L. Environmental Science & Technology, Vol. 36, Issue 7 https://doi.org/10.1021/es0156643	journal	April 2002
In Situ Spectroscopic Evidence for Neptunium(V)-Carbonate Inner-Sphere and Outer-Sphere Ternary Surface Complexes on Hematite Surfaces Arai, Yuji; Moran, P. B.; Honeyman, B. D. Environmental Science & Technology, Vol. 41, Issue 11 https://doi.org/10.1021/es062468t	journal	June 2007
Neptunium(V) Coprecipitation with Calcite Heberling, Frank; Denecke, Melissa A.; Bosbach, Dirk Environmental Science & Technology, Vol. 42, Issue 2 https://doi.org/10.1021/es071790g	journal	January 2008
Technetium Incorporation into Hematite (α-Fe ₂ O ₃ ) Skomurski, Frances N.; Rosso, Kevin M.; Krupka, Kenneth M. Environmental Science & Technology, Vol. 44, Issue 15 https://doi.org/10.1021/es100069x	journal	August 2010
Environmental Selenium Research: From Microscopic Processes to Global Understanding Winkel, Lenny H. E.; Johnson, C. Annette; Lenz, Markus Environmental Science & Technology, Vol. 46, Issue 2 https://doi.org/10.1021/es203434d	journal	December 2011
Structural Incorporation of As ⁵⁺ into Hematite Bolanz, Ralph M.; Wierzbicka-Wieczorek, Maria; Čaplovičová, Mária Environmental Science & Technology, Vol. 47, Issue 16 https://doi.org/10.1021/es305182c	journal	August 2013
Selenium(IV) Uptake by Maghemite (γ-Fe ₂ O ₃ ) Jordan, Norbert; Ritter, Aline; Scheinost, Andreas C. Environmental Science & Technology, Vol. 48, Issue 3 https://doi.org/10.1021/es4045852	journal	January 2014
The Aqueous Geochemistry of Neptunium: Dynamic Control of Soluble Concentrations with Applications to Nuclear Waste Disposal Kaszuba, John P.; Runde, Wolfgang H. Environmental Science & Technology, Vol. 33, Issue 24 https://doi.org/10.1021/es990470x	journal	December 1999
Uranyl Incorporation into Calcite and Aragonite: XAFS and Luminescence Studies Reeder, Richard J.; Nugent, Melissa; Lamble, Geraldine M. Environmental Science & Technology, Vol. 34, Issue 4 https://doi.org/10.1021/es990981j	journal	February 2000
Environmental Speciation of Actinides Maher, Kate; Bargar, John R.; Brown, Gordon E. Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic301686d	journal	June 2012
Thermodynamic Modeling of the Adsorption of Radionuclides on Selected Minerals. II: Anions Wang, Peiming; Anderko, Andrzej; Turner, David R. Industrial & Engineering Chemistry Research, Vol. 40, Issue 20 https://doi.org/10.1021/ie000992h	journal	August 2001
CO-PRECIPITATION OF RADIUM AND BARIUM SULFATES ¹ Doerner, H. A.; Hoskins, Wm. M. Journal of the American Chemical Society, Vol. 47, Issue 3 https://doi.org/10.1021/ja01680a010	journal	March 1925
General Strategy for Doping Impurities (Ge, Si, Mn, Sn, Ti) in Hematite Nanocrystals Liu, Jun; Liang, Changhao; Zhang, Hemin The Journal of Physical Chemistry C, Vol. 116, Issue 8 https://doi.org/10.1021/jp2105874	journal	February 2012
Multicomponent reactive transport modeling in variably saturated porous media using a generalized formulation for kinetically controlled reactions: REACTIVE TRANSPORT MODELING IN VARIABLY SATURATED MEDIA Mayer, K. Ulrich; Frind, Emil O.; Blowes, David W. Water Resources Research, Vol. 38, Issue 9 https://doi.org/10.1029/2001WR000862	journal	September 2002
Retention and multiphase transformation of selenium oxyanions during the formation of magnetite via iron(ii) hydroxide and green rust Börsig, Nicolas; Scheinost, Andreas C.; Shaw, Samuel Dalton Transactions, Vol. 47, Issue 32 https://doi.org/10.1039/C8DT01799A	journal	January 2018
Discriminating factors affecting incorporation: comparison of the fate of Eu3+–Cm3+ in the Sr carbonate–sulfate system Holliday, Kiel; Chagneau, Aurélie; Schmidt, Moritz Dalton Transactions, Vol. 41, Issue 13 https://doi.org/10.1039/c2dt12425d	journal	January 2012
Competitive adsorption of negatively charged ligands on oxide surfaces Hingston, F. J.; Posner, A. M.; Quirk, J. P. Discussions of the Faraday Society, Vol. 52 https://doi.org/10.1039/df9715200334	journal	January 1971
Sorption behavior of hydroselenide (HSe ⁻ ) onto iron-containing minerals Iida, Yoshihisa; Yamaguchi, Tetsuji; Tanaka, Tadao Journal of Nuclear Science and Technology, Vol. 51, Issue 3 https://doi.org/10.1080/00223131.2014.864457	journal	November 2013
A comparative radiological assessment of five European biosphere systems in the context of potential contamination of well water from the hypothetical disposal of radioactive waste Olyslaegers, G.; Zeevaert, T.; Pinedo, P. Journal of Radiological Protection, Vol. 25, Issue 4 https://doi.org/10.1088/0952-4746/25/4/002	journal	December 2005
Anion Adsorption by Goethite and Gibbsite Hingston, F. J.; Posner, A. M.; Quirk, J. P. Journal of Soil Science, Vol. 23, Issue 2 https://doi.org/10.1111/j.1365-2389.1972.tb01652.x	journal	June 1972
In Situ X-ray Absorption Study of Surface Complexes: Selenium Oxyanions on agr-FeOOH Hayes, K. F.; Roe, A. L.; Brown, G. E. Science, Vol. 238, Issue 4828 https://doi.org/10.1126/science.238.4828.783	journal	November 1987
Effect of Phosphate on the Crystallization of Hematite, Goethite, and Lepidocrocite from Ferrihydrite Gálvez, Natividad Clays and Clay Minerals, Vol. 47, Issue 3 https://doi.org/10.1346/CCMN.1999.0470306	journal	January 1999
Interaction of Corroding Iron with Bentonite in the ABM1 Experiment at Äspö, Sweden: A Microscopic Approach Wersin, Paul; Jenni, Andreas; Mäder, Urs K. Clays and Clay Minerals, Vol. 63, Issue 1 https://doi.org/10.1346/CCMN.2015.0630105	journal	February 2015
Tracking Se Assimilation and Speciation through the Rice Plant – Nutrient Competition, Toxicity and Distribution Nothstein, Alexandra K.; Eiche, Elisabeth; Riemann, Michael PLOS ONE, Vol. 11, Issue 4 https://doi.org/10.1371/journal.pone.0152081	journal	April 2016
Synthesis and incorporation of selenide in pyrite and mackinawite Diener, Alexander; Neumann, Thomas Radiochimica Acta, Vol. 99, Issue 12 https://doi.org/10.1524/ract.2011.1883	journal	August 2011
The influence of temperature on selenate adsorption by goethite Kersten, Michael; Vlasova, N. ract, Vol. 101, Issue 7 https://doi.org/10.1524/ract.2013.2041	journal	April 2013
Selenate and Selenite Mobility in Overburden by Saturated Flow Ahlrichs, J. S.; Hossner, L. R. Journal of Environmental Quality, Vol. 16, Issue 2 https://doi.org/10.2134/jeq1987.00472425001600020001x	journal	April 1987
Selenium Adsorption by Goethite Balistrieri, Laurie S.; Chao, T. T. Soil Science Society of America Journal, Vol. 51, Issue 5 https://doi.org/10.2136/sssaj1987.03615995005100050009x	journal	September 1987
Selenate and Selenite Sorption on Iron Oxides An Infrared and Electrophoretic Study Su, Chunming; Suarez, Donald L. Soil Science Society of America Journal, Vol. 64, Issue 1 https://doi.org/10.2136/sssaj2000.641101x	journal	January 2000
Aggregate‐Scale Heterogeneity in Iron (Hydr)oxide Reductive Transformations Tufano, Katharine J.; Benner, Shawn G.; Mayer, Klaus U. Vadose Zone Journal, Vol. 8, Issue 4 https://doi.org/10.2136/vzj2008.0090	journal	November 2009
The kinetics and mechanisms of goethite and hematite crystallization under alkaline conditions, and in the presence of phosphate Shaw, S. American Mineralogist, Vol. 90, Issue 11-12 https://doi.org/10.2138/am.2005.1757	journal	November 2005
A process-oriented approach to computing multi-field problems in porous media Kolditz, Olaf; Bauer, Sebastian Journal of Hydroinformatics, Vol. 6, Issue 3 https://doi.org/10.2166/hydro.2004.0017	journal	July 2004
Modeling multiphase non-isothermal fluid flow and reactive geochemical transport in variably saturated fractured rocks: 1. Methodology Xu, T. American Journal of Science, Vol. 301, Issue 1 https://doi.org/10.2475/ajs.301.1.16	journal	January 2001
U(VI), Np(V), Eu(III) sorption on goethite: A wide-ranging multiradionuclide dataset and uncertainty-aware parametrization of surface complexation models Romanchuk, Anna Yu.; Svitelman, Valentina S.; Blinov, Peter D. Frontiers in Nuclear Engineering, Vol. 1 https://doi.org/10.3389/fnuen.2022.969171	journal	August 2022
Selenium Cycling Across Soil-Plant-Atmosphere Interfaces: A Critical Review Winkel, Lenny; Vriens, Bas; Jones, Gerrad Nutrients, Vol. 7, Issue 6 https://doi.org/10.3390/nu7064199	journal	May 2015
Sorption Mechanisms of Chemicals in Soils Strawn, Daniel G. Soil Systems, Vol. 5, Issue 1 https://doi.org/10.3390/soilsystems5010013	journal	February 2021

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