Self‐Standing Chiral Covalent Organic Framework Thin Films with Full‐Color Tunable Guest‐Induced Circularly Polarized Luminescence

Tang, Xihao; Zhang, Kai; Xue, Ruxiao; Zheng, Yuexin; Chen, Simin; Zheng, Shengrun; Fan, Jun; Zhang, Yuwei; Ye, Weiping; Zhang, Weiguang; Cai, Songliang; Liu, Yi

doi:10.1002/ange.202413171

Self‐Standing Chiral Covalent Organic Framework Thin Films with Full‐Color Tunable Guest‐Induced Circularly Polarized Luminescence

Journal Article · Thu Oct 24 00:00:00 EDT 2024 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.202413171· OSTI ID:2475002

Tang, Xihao ^[1]; Zhang, Kai ^[1]; Xue, Ruxiao; Zheng, Yuexin ^[1]; Chen, Simin ^[1]; Zheng, Shengrun ^[2]; Fan, Jun ^[2]; Zhang, Yuwei ^[1]; Ye, Weiping ^[1]; Zhang, Weiguang ^[2]; ^[2]; ^[3]

GDMPA Key Laboratory for Process Control and Quality Evaluation of Chiral Pharmaceuticals Guangzhou Key Laboratory of Analytical Chemistry for Biomedicine School of Chemistry South China Normal University 510006 Guangzhou P. R. China
GDMPA Key Laboratory for Process Control and Quality Evaluation of Chiral Pharmaceuticals Guangzhou Key Laboratory of Analytical Chemistry for Biomedicine School of Chemistry South China Normal University 510006 Guangzhou P. R. China, SCNU Qingyuan Institute of Science and Technology Innovation Co., Ltd. 511517 Qingyuan P. R. China
The Molecular Foundry Lawrence Berkeley National Laboratory 94720 Berkeley California United States

Abstract

Exploring self‐standing chiral covalent organic framework (COF) thin films with controllable circularly polarized luminescence (CPL) is of paramount significance but remains a challenging task. Herein, we demonstrate the first example of self‐standing chiral COF films employing a polymerization‐dispersion‐filtration strategy. Pristine, low‐quality chiral COF films were produced by interfacial polymerization and then re‐dispersed into COF colloidal solutions. Via vacuum assisted assembly, these COF colloids were densely stacked and assembled into self‐standing, pure chiral COF films ( L‐ / D‐ CCOF‐F) that were transparent, smooth, crack‐free and highly crystalline. These films were tunable in thicknesses, areas, and roughness, along with strong diffuse reflectance circular dichroism (DRCD) and cyan CPL signals, showing an intrinsic luminescence asymmetric factor ( g _lum ) of ~4.3×10 ⁻³ . Furthermore, these COF films served as host adsorbents to load various achiral organic dye guests through adsorption. The effective chiral transfer and energy transfer between CCOF‐F and achiral fluorescent dyes endowed the dyes with strong chirality and tunable DRCD, resulting in intense, full‐color‐tunable solid‐state CPL. Notably, the ordered arrangement of dye guest molecules within the preferentially oriented chiral pores of CCOF‐F contributed to an amplified | g _lum | factor of up to 7.2×10 ⁻² , which is state‐of‐the‐art for COF‐based CPL materials. This work provides new insights into the design and fabrication of self‐standing chiral COF films, demonstrating their great potential for chiroptical applications.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-05CH11231

OSTI ID:: 2475002

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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