Highly Stable Subnanometric PtIn Clusters for the Selective Dehydrogenation of Alkanes

Li, Chengeng; Meyer, Randall J.; Yacob, Sara; Gomez, Elaine; Lopez‐Haro, Miguel; Calvino, Jose J.; Moliner, Manuel; Serna, Pedro; Corma, Avelino

doi:10.1002/cssc.202401284

Highly Stable Subnanometric PtIn Clusters for the Selective Dehydrogenation of Alkanes

Journal Article · Wed Oct 23 00:00:00 EDT 2024 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.202401284· OSTI ID:2473399

Li, Chengeng ^[1]; Meyer, Randall J. ^[2]; Yacob, Sara ^[2]; Gomez, Elaine ^[2]; Lopez‐Haro, Miguel ^[3]; Calvino, Jose J. ^[3]; Moliner, Manuel ^[1]; Serna, Pedro ^[4]; Corma, Avelino ^[1]

Instituto de Tecnología Química Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas Avenida de los Naranjos s/n 46022 València Spain
ExxonMobilTechnology and Engineering Company Annandale, New Jersey 08801 United States
Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica Facultad de Ciencias Universidad de Cádiz 11003 Cádiz Spain
Instituto de Tecnología Química Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas Avenida de los Naranjos s/n 46022 València Spain, ExxonMobilTechnology and Engineering Company Annandale, New Jersey 08801 United States

Abstract

Subnanometric PtIn clusters have been synthesized within pure silica MFI zeolites by post‐synthetic incorporation of In to Pt@K‐MFI. The optimized PtIn@K‐MFI catalyst outcompetes state‐of‐the‐art PtSn formulations in ethane and propane dehydrogenations, avoiding the need of large excess of Pt promoters and harsh reductive conditions.

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Sponsoring Organization:: USDOE

OSTI ID:: 2473399

Alternate ID(s):: OSTI ID: 2473400

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 2 Vol. 18; ISSN 1864-5631

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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