MoS2-Decorated Graphene@porous Carbon Nanofiber Anodes via Centrifugal Spinning

Abdolrazzaghian, Elham; Zhu, Jiadeng; Kim, Juran; Yanilmaz, Meltem

doi:10.3390/nano12142505

MoS₂-Decorated Graphene@porous Carbon Nanofiber Anodes via Centrifugal Spinning

Journal Article · Thu Jul 21 00:00:00 EDT 2022 · Nanomaterials

DOI:https://doi.org/10.3390/nano12142505· OSTI ID:2471447

^[1]; Zhu, Jiadeng ^[2]; Kim, Juran ^[3]; ^[1]

Istanbul Technical University (Turkey)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Korea Institute of Industrial Technology (KITECH), Ansan (Korea, Republic of)

Sodium-ion batteries (SIBs) are promising alternatives to lithium-ion batteries as green energy storage devices because of their similar working principles and the abundance of low-cost sodium resources. Nanostructured carbon materials are attracting great interest as high-performance anodes for SIBs. Herein, a simple and fast technique to prepare carbon nanofibers (CNFs) is presented, and the effects of carbonization conditions on the morphology and electrochemical properties of CNF anodes in Li- and Na-ion batteries are investigated. Porous CNFs containing graphene were fabricated via centrifugal spinning, and MoS₂ were decorated on graphene-included porous CNFs via hydrothermal synthesis. The effect of MoS₂ on the morphology and the electrode performance was examined in detail. The results showed that the combination of centrifugal spinning, hydrothermal synthesis, and heat treatment is an efficient way to fabricate high-performance electrodes for rechargeable batteries. Furthermore, CNFs fabricated at a carbonization temperature of 800 °C delivered the highest capacity, and the addition of MoS₂ improved the reversible capacity up to 860 mAh/g and 455 mAh/g for Li- and Na-ion batteries, respectively. A specific capacity of over 380 mAh/g was observed even at a high current density of 1 A/g. Centrifugal spinning and hydrothermal synthesis allowed for the fabrication of high-performance electrodes for sodium ion batteries.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2471447

Journal Information:: Nanomaterials, Journal Name: Nanomaterials Journal Issue: 14 Vol. 12; ISSN 2079-4991

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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MoS2-Decorated Graphene@porous Carbon Nanofiber Anodes via Centrifugal Spinning

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MoS₂-Decorated Graphene@porous Carbon Nanofiber Anodes via Centrifugal Spinning