Paired electrocatalysis in 5-hydroxymethylfurfural valorization

Qu, Dalong; He, Shuijian; Chen, Lianhua; Ye, Yifan; Ge, Qingmei; Cong, Hang; Jiang, Nan; Ha, Yang

doi:10.3389/fchem.2022.1055865

Paired electrocatalysis in 5-hydroxymethylfurfural valorization

Journal Article · Fri Oct 21 00:00:00 EDT 2022 · Frontiers in Chemistry

DOI:https://doi.org/10.3389/fchem.2022.1055865· OSTI ID:2470892

Qu, Dalong ^[1]; He, Shuijian ^[2]; Chen, Lianhua ^[1]; Ye, Yifan ^[3]; Ge, Qingmei ^[1]; Cong, Hang ^[1]; Jiang, Nan ^[1]; Ha, Yang ^[4]

Guizhou University, Guiyang (China)
Nanjing Forestry University (China)
University of Science and Technology of China, Hefei (China)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

5-Hydroxymethylfurfural (HMF) has aroused considerable interest over the past years as an important biomass-derived platform molecule, yielding various value-added products. The conventional HMF conversion requires noble metal catalysts and harsh operating conditions. On the other hand, the electrocatalytic conversion of HMF has been considered as an environmentally benign alternative. However, its practical application is limited by low overall energy efficiency and incomplete conversion. Paired electrolysis and highly efficient electrocatalysts are two viable strategies to address these limitations. Herein, an overview of coupled electrocatalytic HMF hydrogenation or hydrogen evolution reaction (HER) with HMF oxidation as well as the associated electrocatalysts are reviewed and discussed. In this mini-review, a brief introduction of electrocatalytic HMF upgrading is given, followed by the recent advances and challenges of paired electrolysis with an emphasis on the integration HMF electrohydrogenation with HMF electrooxidation. Finally, a perspective for a future sustainable biomass upgrading community based on electrocatalysis is proposed.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2470892

Journal Information:: Frontiers in Chemistry, Journal Name: Frontiers in Chemistry Vol. 10; ISSN 2296-2646

Publisher:: Frontiers Research FoundationCopyright Statement

Country of Publication:: United States

Language:: English

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The Impact of 5-Hydroxymethylfurfural (HMF)-Metal Interactions on the Electrochemical Reduction Pathways of HMF on Various Metal Electrodes

Journal Article · Tue Aug 10 00:00:00 EDT 2021 · ChemSusChem · OSTI ID:1976314

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
5-hydroxymethylfurfural
Chemistry
biomass valorization
electrocatalytic hydrogenation
electrocatalytic oxidation
paired electrocatalysis

Paired electrocatalysis in 5-hydroxymethylfurfural valorization

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